Batteries,
Год журнала:
2024,
Номер
10(12), С. 438 - 438
Опубликована: Дек. 10, 2024
Supercapacitors
are
a
kind
of
energy
storage
device
that
lie
between
traditional
capacitors
and
batteries,
characterized
by
high
power
density,
long
cycle
life,
rapid
charging
discharging
capabilities.
The
mechanism
supercapacitors
mainly
includes
electrical
double-layer
capacitance
pseudocapacitance.
In
addition
to
constructing
multi-level
pore
structures
increase
the
specific
surface
area
electrode
materials,
defect
engineering
is
essential
for
enhancing
electrochemical
active
sites
achieving
additional
extrinsic
Therefore,
developing
simple
efficient
method
essential.
Atomic
layer
deposition
(ALD)
technology
enables
precise
control
over
thin
film
thickness
at
atomic
level
through
layer-by-layer
deposition.
This
capability
allows
intentional
introduction
defects,
such
as
vacancies,
heteroatom
doping,
or
misalignment,
within
material.
ALD
process
can
regulate
defects
in
materials
without
altering
overall
structure,
thereby
optimizing
both
physical
properties
materials.
Its
self-limiting
reaction
also
ensures
doping
introduced
uniformly
across
material
surface.
uniform
distribution
particularly
profitable
electrodes
supercapacitor
applications,
it
promotes
consistent
performance
entire
electrode.
review
systematically
summarizes
latest
advancements
via
supercapacitors,
including
enhancement
conductivity
ALD,
improving
density
device.
Furthermore,
we
discuss
underlying
mechanisms,
advantages,
future
directions
this
field.
Energy & Fuels,
Год журнала:
2024,
Номер
38(21), С. 21219 - 21231
Опубликована: Окт. 17, 2024
In
recent
advancements,
bimetal
MXene
has
emerged
as
a
promising
electrocatalyst
well
catalytic
supportive
material
due
to
its
unique
properties,
including
rich
chemistry
and
potential
metal-like
conductivity.
This
study
introduces
novel
bifunctional
for
overall
water
splitting,
involving
the
synthesis
of
sea
urchin-like
CoNi2Se4
onto
Ti2NbC2Tx
using
simple
two-step
solvothermal
method.
The
developed
CoNi2Se4@Ti2NbC2Tx
is
subjected
physical
surface
topographical
investigation
X-ray
diffraction,
field-emission
scanning
electron
microscopy,
Raman
spectroscopy,
photoelectron
spectroscopy
techniques.
synergistic
effect
prepared
nanocomposite
shows
extraordinary
kinetic
metrics
both
HER
OER
processes.
It
low
overpotential
76
mV
at
10
mA
cm–2
small
Tafel
slope
78.6
dec–1
an
203
with
102.2
OER.
exhibits
lower
exchange
current
density
onset
that
highlights
enhanced
performance.
achieved
1.55
V
maintained
excellent
electrocatalytic
stability
24
h.
reveals
could
be
used
cost-effective
efficient
catalyst,
paving
way
application
in
clean
hydrogen
production
through
splitting.
Owing
better
electrochemical
behavior,
also
electrode
supercapacitor
applications,
it
specific
capacitance
about
2.05
F
2
cm–2.