Polymers,
Год журнала:
2022,
Номер
14(4), С. 684 - 684
Опубликована: Фев. 11, 2022
A
new
method
for
the
recycling
of
a
polyester
tire
cord
under
action
oligoethylene
terephthalates,
bis(2-hydroxyethyl)
terephthalate
and
ethylene
glycol
has
been
proposed.
The
involves
simultaneous
homogeneous
glycolysis
polyethylene
devulcanization
crumb
rubber.
Polyester
glycolysates
were
characterized
by
FTIR
spectroscopy
gel
permeation
chromatography
(GPC).
process
was
investigated
swelling-based
methods.
rate
proposed
in
melt
phase
proved
to
be
higher
than
one
heterogeneous
glycolysis.
assumption
more
efficient
presence
softener
also
confirmed.
degree
46.07%,
apparent
swelling
167.4%,
constant
0.0902
min-1
achieved.
results
indicate
that
made
it
possible
carry
out
deeply
known
with
various
agents,
but
further
research
is
needed
industrial
implementation.
Materials & Design,
Год журнала:
2023,
Номер
237, С. 112558 - 112558
Опубликована: Дек. 13, 2023
Mishandling
of
waste
plastics
and
biomasses
is
a
major
global
concern.
Every
year,
around
380
million
tons
plastic
are
produced,
with
only
9%
being
recycled,
leading
to
widespread
pollution.
Similarly,
biomass
generation
from
agricultural
forestry
sectors
accounts
for
140
billion
metric
tons,
in
addition
2.01
municipal
solid
waste.
This
review
paper
addresses
the
gap
regarding
integration
3D
printing,
upcycling
recycled
plastics,
utilization
sustainable
composites.
printed
parts
have
shown
comparable
mechanical
properties
compared
virgin
materials,
which
been
further
improved
by
biomass-derived
fillers.
The
acknowledges
that
different
printing
parameters
substantial
influence
on
strength,
ductility,
crystallinity,
dimensional
accuracy
parts.
Therefore,
optimizing
these
becomes
crucial
achieving
performance.
Moreover,
incorporating
reinforcing
agents,
stabilizers,
chain
extenders,
compatibilizers,
surface
modifiers
recycling
presents
an
excellent
opportunity
enhance
properties,
thermal
stability,
adhesion,
stability.
Additionally,
identifies
research
gaps
proposes
machine
learning
artificial
intelligence
enhanced
process
control
material
development,
expanding
possibilities
this
field.
Polymer Engineering and Science,
Год журнала:
2024,
Номер
64(4), С. 1555 - 1570
Опубликована: Янв. 19, 2024
Abstract
The
high
volume
of
plastic
waste
and
the
extremely
low
recycling
rate
have
created
a
serious
challenge
worldwide.
Local
distributed
additive
manufacturing
(DRAM)
offers
solution
by
economically
incentivizing
local
recycling.
One
DRAM
technology
capable
processing
large
quantities
is
fused
granular
fabrication,
where
solid
shredded
can
be
reused
directly
as
3D
printing
feedstock.
This
study
presents
an
experimental
assessment
multi‐material
printability
using
two
most
common
thermoplastics
in
beverage
industry,
polyethylene
terephthalate
(PET)
high‐density
(HDPE),
feasibility
mixing
PET
HDPE
to
used
feedstock
material
for
large‐scale
3‐D
printing.
After
collection,
shredding,
cleaning,
characterization
optimization
parameters
were
performed.
Results
showed
object
from
rPET/rHDPE
flakes,
reducing
production
costs
up
88%.
Highlights
Study:
PET‐HDPE.
Large‐scale
particle‐based
technically
possible.
Direct
Biomimetics,
Год журнала:
2025,
Номер
10(1), С. 46 - 46
Опубликована: Янв. 13, 2025
Wood
plastic
composites
(WPCs)
offer
a
means
to
reduce
the
carbon
footprint
by
incorporating
natural
fibers
enhance
mechanical
properties.
However,
there
is
limited
information
on
properties
of
these
materials
under
hostile
conditions.
This
study
evaluated
polypropylene
(PP),
polystyrene
(PS),
and
polylactic
acid
(PLA)
processed
via
extrusion
injection
molding.
Tests
were
conducted
tensile
flexural
strength
modulus,
heat
deflection
temperature
(HDT),
creep
analysis
varying
relative
humidity
conditions
(10%
90%)
water
immersion,
followed
freeze—thaw
cycles.
The
addition
generally
improved
but
increased
absorption.
HDT
dependent
crystallinity
composites.
PLA
PS
demonstrated
superior
overall
performance,
except
for
their
impact
properties,
where
PP
was
slightly
better
than
PLA.
Journal of Thermoplastic Composite Materials,
Год журнала:
2022,
Номер
36(7), С. 3094 - 3132
Опубликована: Май 22, 2022
Fused
deposition
modeling
(FDM)
is
one
of
the
leading
emerging
technologies
Industry
4.0,
which
has
been
employed
to
develop
sustainable
engineering
products,
customized
implants
and
sophisticated
biomedical
devices.
However,
mechanical
strength
durability
3D
printed
parts
still
lower
than
its
conventional
counterparts,
restrict
widespread
use.
In
this
regard,
use
short
fibres
(i.e.
natural
or
artificial)
advanced
nanomaterials
reinforce
existing
polymer
matrix
drastically
increased
improve
load
bearing
capacity
FDM
parts.
Hence,
article
aims
provide
a
systematic
review
on
thermoplastic
composite
structure
prepared
through
technology
summarizes
current
knowledge
about
various
additives
overall
quality
Moreover,
common
defects
associated
with
structures
methods
required
are
discussed
in
article.
Cleaner Materials,
Год журнала:
2023,
Номер
9, С. 100207 - 100207
Опубликована: Сен. 1, 2023
3D
printing
process
has
gained
significant
attention
because
of
its
ability
to
manufacture
complicated
geometries.
The
also
a
lot
potential
for
reducing
plastic
waste.
In
recent
years,
the
use
carbon
fiber
become
increasingly
popular
as
reinforcement
material
3D-printed
objects.
combination
waste
and
create
high-strength
lightweight
structures
various
applications.
This
presented
paper
reviews
advancements
in
using
waste,
focusing
specifically
on
fused
deposition
modeling
(FDM)
selective
laser
sintering
(SLS)
methods
composites.
study
highlights
important
role
materials
process,
especially
regarding
difficulties
producing
non-recyclable
plastics.
composite
processes
industries
that
utilize
these
technologies.
One
key
aspects
article
is
exploration
impact
environment
through
recycling
shall
be
helpful
demonstration
turning
into
durable,
functional
objects
while
minimizing
environmental
impact.
Polymers,
Год журнала:
2023,
Номер
15(4), С. 845 - 845
Опубликована: Фев. 8, 2023
The
energy
efficiency
of
material
extrusion
additive
manufacturing
has
a
significant
impact
on
the
economics
and
environmental
footprint
process.
Control
parameters
that
ensure
3D-printed
functional
products
premium
quality
mechanical
strength
are
an
established
market-driven
requirement.
To
accomplish
multiple
objectives
is
challenging,
especially
for
multi-purpose
industrial
polymers,
such
as
Poly[methyl
methacrylate].
current
paper
explores
contribution
six
generic
control
factors
(infill
density,
raster
deposition
angle,
nozzle
temperature,
print
speed,
layer
thickness,
bed
temperature)
to
performance
methacrylate]
over
its
performance.
A
five-level
L25
Taguchi
orthogonal
array
was
composed,
with
five
replicas,
involving
135
experiments.
3D
printing
time
electrical
consumption
were
documented
stopwatch
approach.
tensile
strength,
modulus,
toughness
experimentally
obtained.
angle
speed
first
second
most
influential
strength.
Layer
thickness
corresponding
ones
consumption.
Quadratic
regression
model
equations
each
response
metric
compiled
validated.
Thus,
best
compromise
between
achievable,
tool
creates
value
engineering
applications.
Materials,
Год журнала:
2024,
Номер
17(5), С. 1083 - 1083
Опубликована: Фев. 27, 2024
The
polymer
foil
industry
is
one
of
the
leading
producers
plastic
waste.
development
new
recycling
methods
for
packaging
products
biggest
demands
in
today’s
engineering.
subject
this
research
was
melt
processing
multilayered
PET-based
waste
with
PETG
copolymer.
resulting
blends
were
intended
additive
manufacturing
using
fused
deposition
modeling
(FDM)
method.
In
order
to
improve
properties
developed
materials,
compounding
procedure
conducted
addition
a
reactive
chain
extender
(CE)
and
elastomeric
copolymer
used
as
an
impact
modifier
(IM).
samples
manufactured
3D
printing
technique
and,
comparison,
traditional
injection
molding
obtained
subjected
detailed
characterization
procedure,
including
mechanical
performance
evaluation,
thermal
analysis,
rheological
measurements.
This
confirms
that
film
can
be
successfully
production
filament,
most
samples,
FDM
process
without
any
difficulties.
Unfortunately,
unmodified
are
characterized
by
brittleness,
which
makes
it
necessary
use
elastomer
presence
semicrystalline
PET
phase
improves
resistance
prepared
blends;
however,
annealing
required
purpose.
Materials Today Sustainability,
Год журнала:
2024,
Номер
26, С. 100757 - 100757
Опубликована: Март 24, 2024
Filaments
from
blends
of
post-industrial,
low-quality
recycled
poly(ethylene
terephthalate)
(RPET)
and
ethylene-butyl-acrylate-glycidyl-methacrylate
(EBA-GMA)
were
extruded
with
different
EBA-GMA
contents,
then
specimens
3D-printed
by
fused
filament
fabrication
technology.
It
has
been
demonstrated
that,
when
0–90°
layer
order
is
applied,
at
15
wt%
content
the
unnotched
impact
strength
increases
two
a
half
times
notched
nine
compared
to
samples
printed
elastomer-free
RPET.
DSC
DMA
measurements
proved
that
reactively
bonds
PET
molecules,
which
indicated
increment
rigid
amorphous
phase
glass
transition
temperature
reduction
crystallinity.
The
co-polymer
molecules
formed
in-situ
during
compounding
create
Toughening
Enhancer
Interphase
(TEI),
also
remains
after
3D
printing
effectively
enhances
strength.
strain
break
tensile
filaments
are
substantially
higher
than
due
increasing
shrinkage
resulting
increased
porosity
content.
However,
Young-modulus
values
quite
similar.
flexural
reaches
40–60%
injection
moulded
samples.
proposed
method
enables
production
parts
arbitrary
geometry
balanced
mechanical
properties
RPET,
may
substitute
acrylonitrile
butadiene
styrene.