Recent Progress in Transition-Metal Sulfide Catalyst Regulation for Improved Oxygen Evolution Reaction

Energy & Fuels, Год журнала: 2022, Номер 36(13), С. 6675 - 6694

Опубликована: Июнь 23, 2022

Electrochemical hydrogen production is considered the most reliable approach to transfer renewable energies chemical energy─namely, hydrogen─for storage, and intensive attention has been directed nonprecious catalyst development for water splitting reactions. Among candidates, metal sulfides have extensively explored as an emerging electrocatalyst material oxygen evolution reaction (OER) in reaction, because of their abundant active centers, good electrical conductivity, high intrinsic activity. By optimizing structure states, some advanced catalysts reported recently, which was instructive inspiring novel development. Herein, recent advances electrocatalytic performance optimization strategies transition-metal sulfide OER are reviewed systematically comprehensively. The fundamental catalytic mechanism key parameters first presented then followed by physicochemical properties sulfides, could be helpful understanding correlation between performance. Importantly, activity boosted general strategies, terms defect/vacancy effect, lattice mismatch, phase engineering, heterostructure, doping mainly discussed this work. challenges opportunities related further materials with long-term durability finally proposed. It can concluded that these regulatory largely improve increasing site exposure reducing energy barrier In addition, problems future improving presented, provides beneficial enlightenment guidance efficient low-cost electrocatalysts future. Hopefully, effort would design preparation OER.

Язык: Английский

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Sulphur-dopant induced breaking of the scaling relation on low-valence Ni sites in nickel ferrite nanocones for water oxidation with industrial-level current density

Chemical Engineering Journal, Год журнала: 2023, Номер 461, С. 141714 - 141714

Опубликована: Фев. 4, 2023

Язык: Английский

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Amorphous FeCoNi-S as efficient bifunctional electrocatalysts for overall water splitting reaction

Chinese Chemical Letters, Год журнала: 2022, Номер 34(2), С. 107241 - 107241

Опубликована: Фев. 22, 2022

Язык: Английский

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Strategies of Anode Design for Seawater Electrolysis: Recent Development and Future Perspective

Small Science, Год журнала: 2022, Номер 2(9)

Опубликована: Авг. 16, 2022

Compared with freshwater splitting, seawater electrolysis has more spaces to be explored, which is primarily attributed the additional critical catalytic challenges of competition between anodic oxygen evolution reaction (OER) and chlorine chemistry, deep corrosion, site blocking due presence chloride ions insoluble particulate in seawater. However, if direct can realized, it would revolutionize energy environmental sectors. In this review, current effective strategies are summarized, including electronic modulation, vacancies creation, amorphous porous structure design, corrosion‐resistant passive layer decoration, creating strong catalyst–support interactions. The review also provides insights for on rational design OER catalyst high selectivity, activity, corrosion resistance, chemical, mechanical durability. Beyond progress made date, a perspective fabrication high‐performance anodes proposed. Collectively, will shed light viable anode massive sustainable hydrogen fuel production from immense

Язык: Английский

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Compositional engineering of HKUST‐1/sulfidized NiMn‐LDH on functionalized MWCNTs as remarkable bifunctional electrocatalysts for water splitting

Carbon Energy, Год журнала: 2023, Номер 5(12)

Опубликована: Дек. 1, 2023

Abstract Water‐splitting reactions such as the hydrogen evolution reaction (HER) and oxygen (OER) typically require expensive noble metal‐based electrocatalysts. This has motivated researchers to develop novel, cost‐effective electrocatalytic systems. In this study, a new multicomponent nanocomposite was assembled by combining functionalized multiwalled carbon nanotubes, Cu‐based metal–organic framework (MOF) (HKUST‐1 or HK), sulfidized NiMn‐layered double hydroxide (NiMn‐S). The resulting nanocomposite, abbreviated MW/HK/NiMn‐S, features unique architecture, high porosity, numerous electroactive Cu/Ni/Mn sites, fast charge transfer, excellent structural stability, conductivity. At current density of 10 mA cm −2 , dual‐function electrocatalyst shows remarkable performance, with ultralow overpotential values 163 mV 73 (HER), well low Tafel slopes (57 75 dec −1 respectively). Additionally, its turnover frequency (4.43 s for OER; 3.96 HER) are significantly superior those standard Pt/C IrO 2 synergistic effect nanocomposite's different components is responsible enhanced performance. A functional theory study revealed that multi‐interface heterostructure contribute increased electrical conductivity decreased energy barrier, in HER/OER activity. presents novel vision designing advanced electrocatalysts performance water splitting. Various composites have been utilized water‐splitting applications. investigates use MW/HK/NiMn‐S splitting first time indicate between carbon‐based materials along layered compounds porous MOF. each component composite can be an interesting topic field

Язык: Английский

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S-vacancy-rich NiFe-S nanosheets based on a fully electrochemical strategy for large-scale and quasi-industrial OER catalysts

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 345, С. 123686 - 123686

Опубликована: Янв. 4, 2024

Язык: Английский

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A Unique Etching‐Doping Route to Fe/Mo Co‐Doped Ni Oxyhydroxide Catalyst for Enhanced Oxygen Evolution Reaction

Small, Год журнала: 2023, Номер 19(37)

Опубликована: Май 5, 2023

Fe-doped Ni (oxy)hydroxide shows intriguing activity toward oxygen evolution reaction (OER) in alkaline solution, yet it remains challenging to further boost its performance. In this work, a ferric/molybdate (Fe3+ /MoO42- ) co-doping strategy is reported promote the OER of oxyhydroxide. The reinforced Fe/Mo-doped oxyhydroxide catalyst supported by nickel foam (p-NiFeMo/NF) synthesized via unique plasma etching-electrochemical doping route, which precursor Ni(OH)2 nanosheets are first etched form defect-rich amorphous nanosheets, followed electrochemical cycling trigger simultaneously Fe3+ and phase transition. This p-NiFeMo/NF requires an overpotential only 274 mV reach 100 mA cm-2 media, exhibiting significantly enhanced compared NiFe layered double hydroxide (LDH) other analogs. Its does not fade even after 72 h uninterrupted operation. situ Raman analysis reveals that intercalation MoO42- able prevent over-oxidation NiOOH matrix from β γ phase, thus keeping at most active state.

Язык: Английский

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Simple synthesis of peanut shell-like MoCoFe-HO@CoMo-LDH for efficient alkaline oxygen evolution reaction

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 664, С. 748 - 755

Опубликована: Март 6, 2024

Язык: Английский

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Synthesis and applications of biomass-derived electrocatalysts in water electrolysis

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 60, С. 845 - 866

Опубликована: Фев. 23, 2024

Язык: Английский

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Advanced Catalyst Design Strategies and In-Situ Characterization Techniques for Enhancing Electrocatalytic Activity and Stability of Oxygen Evolution Reaction

Electrochemical Energy Reviews, Год журнала: 2024, Номер 7(1)

Опубликована: Июнь 5, 2024

Язык: Английский

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