High-Entropy layered double hydroxides Tailor Pt electron state for Promoting acidic hydrogen evolution reaction

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 684, С. 566 - 574

Опубликована: Янв. 11, 2025

Язык: Английский

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Morning Glory-Inspired Biomimetic Water Purification Device with a Dry Chimney for Efficient Solar-Thermal Desalination and Simultaneous Catalytic Degradation of Organic Pollutants

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Фев. 12, 2025

Although solar steam generation is effective in evaporating water and seawater under light irradiation, it ineffective purifying wastewater with organic pollutants. Herein, a morning glory-shaped purification device dry chimney (pistil) designed for simultaneous solar-thermal evaporation of catalytic degradation pollutants therein, which fabricated by decorating Au/CoFe2O4/carbon nanotube functional components on hydrophilic porous bamboo fabric substrate. Au CoFe2O4 are capable forming Mott–Schottky heterostructures to create stable built-in electric field promote the separation electron–hole pairs, thereby facilitating activation potassium peroxymonosulfate generate reactive oxygen species achieving high rate constant 0.222 min–1 1-sun irradiation. Crucially, bionic glory structure benefits continuous supply air creates airflow circulation, reducing humidity increasing escape saturated vapor from evaporator, 3.21 kg m–2 h–1 A total as 28.21 realized therein. The integration enables an efficient protocol

Язык: Английский

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Manipulating electron redistribution in small-sized NiCoP colloidal nanocrystals for enhanced alkaline water/seawater electrolysis

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161709 - 161709

Опубликована: Март 1, 2025

Язык: Английский

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Morphological engineering of monodispersed Co2P nanocrystals for efficient alkaline water and seawater splitting

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 691, С. 137389 - 137389

Опубликована: Март 20, 2025

Язык: Английский

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Built-in electric field construction and lattice oxygen activation for boosting alkaline electrochemical water/seawater oxidation

Chemical Engineering Journal, Год журнала: 2024, Номер 496, С. 154279 - 154279

Опубликована: Июль 25, 2024

Язык: Английский

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Hydrogen Spillover Boosted Hydrogen Evolution Electrocatalysis over Pd@CoP in Alkaline Seawater

ACS Materials Letters, Год журнала: 2024, Номер 6(9), С. 3970 - 3976

Опубликована: Июль 29, 2024

Developing efficient and stable electrocatalysts for the hydrogen evolution reaction (HER) is crucial to achieve effective electrolytic production from seawater. Hydrogen spillover enhances catalytic performance by facilitating migration of species between different sites, improving efficiency kinetics in HER. Herein, we report hydrothermal-phosphatization-immersion synthesis Pd-decorated CoP nanoneedle arrays on nickel foam (Pd@CoP/NF) as a highly active HER electrocatalyst toward alkaline seawater reduction. In situ electrochemical impedance spectroscopy kinetic isotope effects reveal Pd@CoP/NF's extensive adsorption enhanced transfer rates. seawater, such Pd@CoP/NF exhibits outstanding with low overpotential 249 mV at current density 1000 mA cm–2 long-term stability 500 h.

Язык: Английский

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Modulation of electrospun nanomaterials for boosting electrocatalytic water splitting

Journal of Electroanalytical Chemistry, Год журнала: 2025, Номер unknown, С. 118941 - 118941

Опубликована: Янв. 1, 2025

Язык: Английский

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Balancing electrophilic and nucleophilic dual sites to construct efficient Mott–Schottky oxygen electrocatalysts

Chemical Engineering Science, Год журнала: 2025, Номер unknown, С. 121249 - 121249

Опубликована: Янв. 1, 2025

Язык: Английский

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Room‐Temperature Synthesis of Amorphous Fe‐Doped Nickel Phosphate for High‐Efficiency Alkaline Seawater Oxidation

Small, Год журнала: 2025, Номер unknown

Опубликована: Фев. 2, 2025

The construction of an efficient and durable oxygen evolution reaction (OER) electrocatalyst through a simple synthesis strategy is crucial for the hydrogen produced from seawater splitting. However, achieving this goal remains great challenge. Herein, amorphous Fe-doped nickel phosphate (Fe-NixPO4) as high-performance OER electrocatalysts alkaline freshwater/seawater splitting presented using straightforward co-precipitation method at room-temperature. Experimental results reveal structural reconstruction Fe-NixPO4 into NiOOH decorated with PO4 3-. collaborative interplay between Ni2+ Fe3+, along decoration 3-, can effectively modulate electronic environment electrocatalyst. Consequently, optimized exhibits exceptional activity, requiring overpotentials 359 422 mV to generate 1000 mA cm-2 in freshwater seawater, respectively. Moreover, also displays outstanding stability 100 h seawater. This research presents viable approach fabricating efficiency electrolysis.

Язык: Английский

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Constructing NiCo-hydroxide/Ni Mott-Schottky heterostructure electrocatalyst for enhanced alkaline hydrogen evolution reaction by inducing interfacial electron redistribution

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 688, С. 1 - 10

Опубликована: Фев. 15, 2025

Язык: Английский

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