Carbon‐based Flame Retardants for Polymers: A Bottom‐up Review

Advanced Materials, Год журнала: 2024, Номер unknown

Опубликована: Май 30, 2024

Abstract This state‐of‐the‐art review is geared toward elucidating the molecular understanding of carbon‐based flame‐retardant mechanisms for polymers via holistic characterization combining detailed analytical assessments and computational material science. The use flame retardants, which include graphite, graphene, carbon nanotubes (CNTs), dots (CDs), fullerenes, in their pure functionalized forms are initially reviewed to evaluate retardancy performance determine elevation flammability resistance on various types polymers. early transition metal carbides such as MXenes, regarded next‐generation discussed with respect superior multifunctional applications. At core this utilization cutting‐edge dynamics (MD) simulations sets a precedence an alternative bottom‐up approach fill knowledge gap through insights into thermal resisting process formation carbonaceous char intermediate chemical reactions offered by unique bonding arrangements microscopic in‐situ architectures. Combining MD experimental characterization, more targeted development well systematic synthesis framework can be realized future advanced

Язык: Английский

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Flexible and alternately layered high electrochemical active electrode based on MXene, carboxymethylcellulose, and carbon nanotube for asymmetric micro-supercapacitors

Journal of Colloid and Interface Science, Год журнала: 2023, Номер 645, С. 974 - 984

Опубликована: Май 9, 2023

Язык: Английский

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Rationally assembled sandwich structure of MXene-based phosphorous flame retardant at ultra-low loading nanosheets enabling fire-safe thermoplastic polyurethane

Applied Surface Science, Год журнала: 2023, Номер 649, С. 159111 - 159111

Опубликована: Дек. 9, 2023

Язык: Английский

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Targeted assembly of hierarchical sea-urchin inspired NiPS@LDH architecture for enhanced toughness, wear-resistance and fire-safety of epoxy composites

Chemical Engineering Journal, Год журнала: 2024, Номер 498, С. 155413 - 155413

Опубликована: Сен. 1, 2024

Язык: Английский

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Unlocking epoxy thermal management capability via hierarchical Ce-MOF@MoS2 hybrid constructed by in-situ growth method

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 678, С. 959 - 967

Опубликована: Сен. 21, 2024

Язык: Английский

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Facile alteration of the molecular structure of phosphonamide for efficient flame retardancy in TPU

Composites Communications, Год журнала: 2023, Номер 44, С. 101759 - 101759

Опубликована: Окт. 21, 2023

Язык: Английский

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Boron-Based Polyphosphazene-Functionalized Mxene Nanosheets for Polypropylene Composites with Improved Mechanical Properties and Flame Retardancy Applications

ACS Applied Nano Materials, Год журнала: 2024, Номер 7(2), С. 2021 - 2032

Опубликована: Янв. 11, 2024

Developing high-performance resins with exceptional thermal oxidation stability, flame retardancy, smoke release suppression, and mechanical properties is an important industrial challenge. However, current flame-retardant design strategies often compromise other composite material properties. Especially when using polyolefin, unsaturated polyester, noncharred materials, it usually necessary to add large amounts of fillers. In this study, a nanosynergist (Ti3C2Tx@PPD) for functionalizing Ti3C2Tx nanosheets boron-based polyphosphazene was designed adopted piperazine pyrophosphate/polypropylene (PAPP/PP) system as application example. By controlling the chemical environment cyclotriphosphazene, condensed phase characteristics were preserved, but also atypical vapor mechanism activated. The combination P/N/B elements exhibited excellent catalytic char-forming performance compared others in literature. Only 2% incorporated Ti3C2Tx@PPD reduced total heat released from by 66.3%, 71.8%, fire growth index 49.4%. incorporation inhibited deterioration composite. addition, pyrolysis path revealed under special environment. This study lays foundation functional nanomaterials that can be used various applications require resins.

Язык: Английский

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Mechanism Investigation and Safety Evaluation towards Flame-retardant Structural Thermoplastic Polyurethane Composites Inspired via Interfacial Synergy Strategy

Polymer Degradation and Stability, Год журнала: 2025, Номер unknown, С. 111355 - 111355

Опубликована: Апрель 1, 2025

Язык: Английский

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