A critical and comprehensive review of the current status of 17β-estradiol hormone remediation through adsorption technology

Environmental Science and Pollution Research, Год журнала: 2024, Номер 31(17), С. 24679 - 24712

Опубликована: Март 15, 2024

Язык: Английский

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Efficient adsorption of fluorescein dye from aqueous solutions by Al/Th-MOF bimetal-organic frameworks: Adsorption isotherm, kinetics, DFT computation, and optimization via Box-Behnken design

Process Safety and Environmental Protection, Год журнала: 2024, Номер 190, С. 353 - 371

Опубликована: Авг. 22, 2024

Язык: Английский

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ZnO@ activated carbon derived from wood sawdust as adsorbent for removal of methyl red and methyl orange from aqueous solutions

Scientific Reports, Год журнала: 2024, Номер 14(1)

Опубликована: Март 5, 2024

Abstract Activated carbon (AC) and ZnO@AC composite derived from wood sawdust were prepared to be utilized as adsorbents for methyl red (MR) orange (MO) anionic dyes the aqueous solutions. The maximum adsorption capacity of AC toward both was achieved in strong acidic medium (pH = 3), under stirring 60 min. kinetic studies revealed that MR MO onto fitted well with pseudo-second-order model. Furthermore, intraparticle diffusion Elovich models confirmed is controlled by external surfaces, chemisorption process. isotherm results indicated dye occurred via monolayer adsorption, estimated capacities higher than those AC. Thermodynamic analysis suggested endothermic spontaneous. mechanism MR, proposed electrostatic bonding, π–π interactions, ion exchange, while H-bonding n–π interactions minor contributors. This study reveals potential use carbon-based removal wastewater.

Язык: Английский

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Activated Carbon Derived from Rice Husk Biomass using Pyrolysis-assisted Tartaric Acid Activation for Removal of Reactive Orange 16 Dye: Adsorption Modeling using Response Surface Methodology

AUIQ complementary biological system., Год журнала: 2024, Номер 1(1), С. 89 - 95

Опубликована: Авг. 1, 2024

In the current work, rice husk (RH) biomass was pyrolyzed using tartaric acid as an activating agent to produce activated carbon (AC). For 60 min, procedure run at 700 °C and 5 L/min of nitrogen (N2) flow rate. The study used response surface methodology (RSM) a 3-level Box-Behnken design (BBD) optimize extraction efficiency (RHAC) in eliminating reactive orange 16 (RO16) dye from aqueous solution. Different process parameters, such pH (2–12), RHAC dose (0.04 – 0.14 g), time (60-240 min), were chosen part optimization method. When solution's 2, adsorbent dosage 0.09 g, contact 240 maximum amount removal (53%) achieved. This work demonstrates ability use abundant create carbon, which can be effectively remove organic dyes.

Язык: Английский

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The formation and adsorption mechanism studies of 3D hydrangea-like ZnFe-LDHs/FeOOH for the highly efficient removal of phosphate

Chemical Engineering Journal, Год журнала: 2024, Номер 482, С. 148410 - 148410

Опубликована: Янв. 5, 2024

Язык: Английский

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Molecular simulation-based insights into dye pollutant adsorption: A perspective review

Advances in Colloid and Interface Science, Год журнала: 2024, Номер 333, С. 103281 - 103281

Опубликована: Авг. 24, 2024

Growing concerns about environmental pollution have highlighted the need for efficient and sustainable methods to remove dye contamination from various ecosystems. In this context, computational such as molecular dynamics (MD), Monte Carlo (MC) simulations, quantum mechanics (QM) calculations, machine learning (ML) are powerful tools used study predict adsorption processes of dyes on adsorbents. These provide detailed insights into interactions mechanisms involved, which can be crucial designing systems. MD detailing arrangements, dyes' behaviour interaction energies with They simulate entire process, including surface diffusion, solvent layer penetration, physisorption. QM especially density functional theory (DFT), determine structures reactivity descriptors, aiding in understanding mechanisms. identify stable configurations like hydrogen bonding electrostatic forces. MC simulations equilibrium properties by sampling configurations. ML proven highly effective predicting optimizing processes. models offer significant advantages over traditional methods, higher accuracy ability handle complex datasets. optimize conditions, clarify adsorbent functionalization roles, removal efficiency under conditions. This research explores MD, MC, QM, approaches connect macroscopic phenomena. Probing these techniques provides energetics pollutants surfaces. The findings will aid developing new materials removal. review has implications remediation, offering a comprehensive at scales. Merging microscopic data observations enhances knowledge pollutant adsorption, laying groundwork efficient, technologies. Addressing growing challenges ecosystem protection, contributes cleaner, more future. • Enviro concern drives eco-friendly Computation unveils Study bridges dynamics, Carlo, mechanics. Insights inform novel adsorbents Integration shapes greener solutions.

Язык: Английский

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Photocatalytic degradation of drugs and dyes using a maching learning approach

RSC Advances, Год журнала: 2024, Номер 14(13), С. 9003 - 9019

Опубликована: Янв. 1, 2024

The waste management industry uses an increasing number of mathematical prediction models to accurately forecast the behavior organic pollutants during catalytic degradation.

Язык: Английский

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ZnO doped C: Facile synthesis, characterization and photocatalytic degradation of dyes

Scientific Reports, Год журнала: 2023, Номер 13(1)

Опубликована: Авг. 30, 2023

Abstract Carbon doped ZnO nanoparticles have been synthesized from the thermal decomposition of Zinc citrate precursor. The precursor was semi-solid paste and then subjected to calcination at 700 °C produce nanoparticles. were characterized by Fourier Transform Infrared Spectroscopy, UV–visible (UV–Vis) spectra, Transmission Electron Microscope, Field Emission Scanning Energy Dispersive Analysis X-ray (EDAX), powder diffraction (XRD), photoelectron spectroscopy (XPS). results ensured formation hexagonal 2D-ZnO with a layer thickness 25 nm. optical band gap determined found be 2.9 eV, which is lower than bulk. Photocatalytic degradation Fluorescein dye as an anionic Rhodamine B cationic evaluated via C-ZnO NPs under UV irradiation. displayed 99% after 240 min complete photocatalytic 120

Язык: Английский

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Adsorption of anionic dyes onto 1,5-Diphenylcarbazide functionalized magnetic hybrid polymer: Impact of water salinity and surfactants on adsorption isotherms

Journal of Industrial and Engineering Chemistry, Год журнала: 2023, Номер 131, С. 569 - 584

Опубликована: Ноя. 2, 2023

Язык: Английский

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A comprehensive review on adsorption of Reactive Red 120 dye using various adsorbents

Journal of Molecular Liquids, Год журнала: 2023, Номер 394, С. 123719 - 123719

Опубликована: Дек. 6, 2023

Язык: Английский

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