Journal of Alloys and Compounds, Год журнала: 2023, Номер 976, С. 173371 - 173371
Опубликована: Дек. 29, 2023
Язык: Английский
Journal of Alloys and Compounds, Год журнала: 2023, Номер 976, С. 173371 - 173371
Опубликована: Дек. 29, 2023
Язык: Английский
Separation and Purification Technology, Год журнала: 2023, Номер 324, С. 124577 - 124577
Опубликована: Июль 11, 2023
Язык: Английский
Процитировано
69Coordination Chemistry Reviews, Год журнала: 2024, Номер 505, С. 215695 - 215695
Опубликована: Фев. 1, 2024
Язык: Английский
Процитировано
47Desalination, Год журнала: 2024, Номер 574, С. 117278 - 117278
Опубликована: Янв. 2, 2024
Язык: Английский
Процитировано
32Chemical Engineering Journal, Год журнала: 2024, Номер 487, С. 150437 - 150437
Опубликована: Март 16, 2024
Язык: Английский
Процитировано
31Chemical Engineering Journal, Год журнала: 2024, Номер 496, С. 153808 - 153808
Опубликована: Июль 6, 2024
Язык: Английский
Процитировано
31Advanced Functional Materials, Год журнала: 2024, Номер 34(44)
Опубликована: Июнь 4, 2024
Abstract Prussian blue analogues (PBAs) are a class of promising materials for capacitive deionization. However, the kinetic mismatch between their slow ion storage rate and demand from short‐time desalination severely limits performance. Here, group structure‐tuneable Ni‐Mn PBAs have been developed by combination strategy surface‐protected chemical etching Ostwald ripening to study kinetics. Treating them as demos, characterizations investigations, e.g., in situ XRD three‐electrode system, dynamic impedance, finite element simulation, DFT calculations etc., reveal that diffusion caused severe agglomeration nanoparticles unsuitable lattice parameter controls final behavior. Therefore, correspondingly optimized sample (HC‐t) possessing microscale hollow structure, nanoscale shell thickness, expanded lattice, displays fast kinetics with ratio surface‐controlled current high 82% at scan 20 mV s −1 . Consequently, it delivers an impressive capacity 120.8 mg g (2.06 mmol Na + ) average 0.25 (0.004 1.2 V, competitive those reported literature. Moreover, elucidation structure‐performance correlation provides valuable insights development design next‐generation deionization (CDI).
Язык: Английский
Процитировано
20Advanced Functional Materials, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 12, 2024
Abstract Hybrid capacitive deionization (HCDI) emerges as a burgeoning electrochemical desalination technology due to the utilization of profitable pseudocapacitive reactions. Although tunable organic compounds are potential faradaic electrode materials, their insufficient active sites and high water‐solubility restrict practical HCDI applications. Herein, polymer (PNDS) is proposed with diverse redox‐active for deionization. The pronounced molecular aromaticity strong π‐electron delocalization not only endow PNDS framework rigidity, but refine its electronic structure bolster redox activity electron affinity. As an material, demonstrates substantial capacitance 390 F g −1 sustains long‐term stability at 96.3% after 5000 cycles, surpassing reported Na + ‐capturing electrodes. In‐operando monitoring techniques theoretical calculations reveal efficient capture C═N C═O within during repeated electrosorption processes. conceptual demonstration, high‐performance device equipped exhibits impressive salt removal capacity (66.4 mg ), rapid rate (2.2 min ) stable regeneration property. More importantly, integrated system engineered rapidly repeatedly treat saltwater resources human consumption agricultural irrigation, highlighting promising prospects high‐efficiency
Язык: Английский
Процитировано
18Materials Horizons, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
A pseudo-capacitive organic material with multiple active sites and rigid skeleton structure is proposed, which can be applied in electrochemical desalination system efficient, fast durable electroadsorption performance.
Язык: Английский
Процитировано
3Separation and Purification Technology, Год журнала: 2023, Номер 329, С. 125155 - 125155
Опубликована: Сен. 22, 2023
Язык: Английский
Процитировано
32Separation and Purification Technology, Год журнала: 2024, Номер 348, С. 127804 - 127804
Опубликована: Май 3, 2024
Язык: Английский
Процитировано
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