A Novel Polyoxovanadate-Based Metal-Organic Framework as an Efficient Electrocatalyst for Oxygen Evolution DOI
Ning Li,

Siyu Du,

Xueyi Wang

и другие.

Опубликована: Янв. 1, 2024

Язык: Английский

Mechanochemically Driven C–C Bond Formation via Cu-Complex-Functionalized Polyoxoniobate under Solvent-Free Conditions DOI

Weina Cai,

Hongrui Tian,

Zouguang Han

и другие.

Crystal Growth & Design, Год журнала: 2025, Номер 25(5), С. 1636 - 1643

Опубликована: Фев. 19, 2025

Developing a mechanochemical, solvent-free approach for forming C–C bonds in place of traditional solvent-based synthesis is significant green chemistry. Herein, novel Cu-complex-functionalized polyoxoniobate-based hybrid material [Cu(tpy)2]{[Cu(tpy)(H2O)]2[Nb10O28]}·5.5H2O (1, tpy = 2,2′:6′,2″-terpyridine) successfully synthesized and thoroughly characterized. 1 displays excellent thermal solvent stability highly mechanical force tolerant. Catalytic studies reveal that can catalyze the Knoevenagel condensations series aromatic aldehydes with malononitrile to build bond compounds under mechanochemical ball milling conditions. The catalytic system conducted no additional heating, lower oscillating frequency, without solvent. remarkable performance catalyst be attributed two factors: one sufficient contact between reagents facilitated by force, as well preactivated it; other synergistic effect Lewis acid–base sites (Cu2+ [Nb10O28]6–) within catalyst. exhibits outstanding recyclability applied gram-scale reactions. To best our knowledge, this work represents first example mechanochemically driven organic transformation using polyoxometalate-based

Язык: Английский

Процитировано

0
In Situ Synthesis of MIL-101 on Carboxyl-Functionalized SBA-16: Preparation and Catalytic Performance in the Knoevenagel Condensation Reaction under Mild Conditions DOI

Chunlai Liu,

Na Wang,

Zelin Meng

и другие.

Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 116267 - 116267

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Enhanced catalytic performance for CO2 cycloaddition and Knoevenagel condensation reactions via stable Eu3+ modified Mn-MOF DOI

Meng-Qiang Deng,

Zhen Xu,

Ya‐Yu Zhao

и другие.

Surfaces and Interfaces, Год журнала: 2024, Номер 52, С. 104864 - 104864

Опубликована: Июль 26, 2024

Язык: Английский

Процитировано

2
Rational fabrication of two polyoxovanadate-based frameworks for efficient detoxifying mustard gas simulant DOI
Ning Li,

Si-Yu Du,

Xueyi Wang

и другие.

Journal of Molecular Structure, Год журнала: 2024, Номер unknown, С. 140276 - 140276

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

1
Scalable synthesis of a new {P2Mo18O62}-modified CuI/CuII-based metal–organic complex for multi-center synergistic catalysis of benzyl alcohol to benzoic acid DOI
Xiaoyan Zhang, Na Xu, Xiaohui Liu

и другие.

Molecular Catalysis, Год журнала: 2024, Номер 568, С. 114478 - 114478

Опубликована: Авг. 30, 2024

Язык: Английский

Процитировано

0
A Novel Polyoxovanadate-Based Metal-Organic Framework as an Efficient Electrocatalyst for Oxygen Evolution DOI
Ning Li,

Siyu Du,

Xueyi Wang

и другие.

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0