Packed-bed pyrolysis of some leguminosae PODS – exothermicity magnitude and products DOI Creative Commons
Carmen Branca, Colomba Di Blasi

Fuel, Год журнала: 2024, Номер 375, С. 132667 - 132667

Опубликована: Авг. 2, 2024

Packed bed pyrolysis is carried out for a heating temperature of 575 K pellets made by ten Leguminosae pods (peas, broad beans, cranberry and cannellini peanuts, broom, tamarind, silver wattle, acacia, carob). Except some tree (carob, acacia), remarkable exothermicity displayed with overshoots approximately between 50–130 K. Based on thermogravimetric curves, it can be stated that high alkali contents (low peak rate temperatures) promote exothermic decomposition. Instead, negative factors are low molecular weight carbohydrates to the detriment cellulose rates). The yields charred solid in range 36-62 wt%. Carbon dioxide most abundant gaseous product, followed smaller carbon monoxide. liquids mainly consist acetic acid, hydroxy propanone, methyl alcohol, furfural, furfuryl alcohol and, cases, toluene. In general, characteristics quantitatively similar belonging same botanical family, few exceptions caused peculiar chemical compositions such as case carob pods.

Язык: Английский

Catalytic solid derived from residual bean husk biomass applied to sustainable biodiesel production: preparation, characterization, and regeneration study DOI Creative Commons

Izadora de Araújo Sobrinho,

Thaíssa Saraiva Ribeiro,

A. Silva

и другие.

RSC Advances, Год журнала: 2025, Номер 15(9), С. 7050 - 7068

Опубликована: Янв. 1, 2025

This study investigates the use of bean husks as a precursor for synthesis an efficient and regenerable catalyst, with aim offering economical sustainable alternative biodiesel production. Residual shell biomass (RBBH) was calcined at different temperatures (350-500 °C) times (1-4 h) to determine optimum conditions. The catalyst obtained characterized by various methods, such X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Energy Dispersive (EDS) Thermogravimetric Analysis (TG/DTG). results showed that contains metal oxides carbonates active sites. In addition, influence reaction conditions evaluated in ranges temperature (60-120 °C), time (0.5-2.5 h), MeOH : oil molar ratio (12 1-28 1) concentration (2-10% weight). maximum ester content (97.6%) achieved 120 °C, 2 h, 20 1 8% catalyst. After partial deactivation solid it regenerated KOH, yielding biodiesels over 75% three consecutive cycles, demonstrating its efficiency potential continuous use.

Язык: Английский

Процитировано

1

A review on the conversion of plant husk-based biomass into biochar DOI
Kingsley O. Iwuozor, Ebuka Chizitere Emenike, Babatunde Femi Bakare

и другие.

Biofuels, Год журнала: 2024, Номер 15(10), С. 1331 - 1345

Опубликована: Июль 8, 2024

This study sheds light on the synthesis, properties, and application of plant husk-derived biomass into biochar through thermochemical conversion processes. Gasification, pyrolysis, hydrothermal carbonization, torrefaction are processes that have been used in this regard. Investigation production variables revealed temperature, carbonization duration, heating rate significantly influence yield characteristics husk-based biochar, including surface area porosity, with temperature exerting most notable impact. It was observed gave rise to a relatively higher than other processes, which may be due low temperatures usually utilized. The properties typically exhibit carbon content exceeding 45% its total weight. has applied as catalyst, for soil amendment, environmental remediation, water treatment. identification research gaps shows need further exploration intricacies well consequences socio-environmental factors, technical scalability, economic feasibility.

Язык: Английский

Процитировано

7

Removal of phenol from wastewater using Luffa cylindrica fibers in a packed bed column: Optimization, isotherm and kinetic studies DOI Creative Commons
Samuel Ogunniyi, Ebuka Chizitere Emenike, Kingsley O. Iwuozor

и другие.

Heliyon, Год журнала: 2024, Номер 10(4), С. e26443 - e26443

Опубликована: Фев. 1, 2024

This research entails a comparison of the effectiveness unmodified

Язык: Английский

Процитировано

6

Modification of activated carbon for enhanced treatment of per‐ and polyfluoroalkyl substances: A focused review DOI
Chika J. Okorie,

Toluwalase Ojeyemi,

Abel Egbemhenghe

и другие.

Remediation Journal, Год журнала: 2024, Номер 34(2)

Опубликована: Фев. 1, 2024

Abstract In response to the growing concern over contamination of water sources by per‐ and polyfluoroalkyl substances (PFAS), use activated carbon (AC) for PFAS removal has garnered significant attention. However, efficient with conventional AC poses challenges due limited surface area delayed absorption kinetics. This focused review provides a concise overview latest advancements in modification AC, promising strategy enhancing adsorption. Chemical physical modifications, including deposition metal/metal oxide nanoparticles, polymer‐based coatings, surfactants, advanced oxidation processes, were explored, offering insights into their mechanisms effectiveness. The thorough analysis these modified materials valuable resource developing sustainable strategies address pressing issue sources.

Язык: Английский

Процитировано

4

Investigating the Tribological Behavior of Bioinspired Surfaces in Agro-waste and Alumina Reinforced AA6063 Matrix Composites DOI Creative Commons
Ben Festus,

Peter Apata Olubambi

Vacuum, Год журнала: 2024, Номер unknown, С. 113687 - 113687

Опубликована: Сен. 1, 2024

Язык: Английский

Процитировано

3

Investigating the mechanical performance of innovative bean pod ash particulates reinforced in AA6063 alloy for construction and building applications DOI Creative Commons
Ben Festus,

Peter Apata Olubambi

MRS Advances, Год журнала: 2025, Номер unknown

Опубликована: Янв. 30, 2025

Язык: Английский

Процитировано

0

Another way to valorize by-products: Coffee Silver Skin for removing the antibiotic Norfloxacin from water DOI
Jennifer Gubitosa,

Domenico Cignolo,

Vito Rizzi

и другие.

Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 116285 - 116285

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Antibiotics in water: Bean pods as adsorbent for removing and recovering ciprofloxacin DOI Creative Commons
Jennifer Gubitosa,

Domenico Cignolo,

Vito Rizzi

и другие.

Environmental Chemistry and Ecotoxicology, Год журнала: 2025, Номер unknown

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Seasonal variation and human health risk assessment of potentially toxic elements in pharmaceutical effluents around Ilorin metropolis, Nigeria DOI
Hussein K. Okoro, Muyiwa Michael Orosun,

Oriade F Anuoluwa

и другие.

Environmental Monitoring and Assessment, Год журнала: 2024, Номер 196(8)

Опубликована: Авг. 1, 2024

Язык: Английский

Процитировано

1

Packed-bed pyrolysis of some leguminosae PODS – exothermicity magnitude and products DOI Creative Commons
Carmen Branca, Colomba Di Blasi

Fuel, Год журнала: 2024, Номер 375, С. 132667 - 132667

Опубликована: Авг. 2, 2024

Packed bed pyrolysis is carried out for a heating temperature of 575 K pellets made by ten Leguminosae pods (peas, broad beans, cranberry and cannellini peanuts, broom, tamarind, silver wattle, acacia, carob). Except some tree (carob, acacia), remarkable exothermicity displayed with overshoots approximately between 50–130 K. Based on thermogravimetric curves, it can be stated that high alkali contents (low peak rate temperatures) promote exothermic decomposition. Instead, negative factors are low molecular weight carbohydrates to the detriment cellulose rates). The yields charred solid in range 36-62 wt%. Carbon dioxide most abundant gaseous product, followed smaller carbon monoxide. liquids mainly consist acetic acid, hydroxy propanone, methyl alcohol, furfural, furfuryl alcohol and, cases, toluene. In general, characteristics quantitatively similar belonging same botanical family, few exceptions caused peculiar chemical compositions such as case carob pods.

Язык: Английский

Процитировано

0