Structural Requirements of Synthetic Anionophores for Inorganic Phosphate and Phosphate Esters DOI Creative Commons
Aarón Torres‐Huerta, Karolis Norvaiša, Alessio Cataldo

и другие.

ChemistryEurope, Год журнала: 2025, Номер unknown

Опубликована: Фев. 3, 2025

Abstract The transmembrane transport of anions is a promising application synthetic anion receptors. Numerous anionophores have been developed for chloride over the past decades. Despite biological relevance phosphate and esters, very few reports on their by systems exist. Here we report systematic study diphenyl phosphate, phenyl inorganic five different anionophores. these phosphates into liposomes was monitored fluorescence spectroscopy, 31 P NMR an ion selective electrode. results experiments showed that readily transported most ionophores. more challenging but can be enhanced better shielding group. Inorganic to this achieved using macrocyclic anionophore with eight preorganised H‐bond donors. These pave way development as well esters.

Язык: Английский

Structural Requirements of Synthetic Anionophores for Inorganic Phosphate and Phosphate Esters DOI Creative Commons
Aarón Torres‐Huerta, Karolis Norvaiša, Alessio Cataldo

и другие.

ChemistryEurope, Год журнала: 2025, Номер unknown

Опубликована: Фев. 3, 2025

Abstract The transmembrane transport of anions is a promising application synthetic anion receptors. Numerous anionophores have been developed for chloride over the past decades. Despite biological relevance phosphate and esters, very few reports on their by systems exist. Here we report systematic study diphenyl phosphate, phenyl inorganic five different anionophores. these phosphates into liposomes was monitored fluorescence spectroscopy, 31 P NMR an ion selective electrode. results experiments showed that readily transported most ionophores. more challenging but can be enhanced better shielding group. Inorganic to this achieved using macrocyclic anionophore with eight preorganised H‐bond donors. These pave way development as well esters.

Язык: Английский

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