A crystalline Sm(III)-containing antimonotungstate with efficient catalytic activity in three-component reaction for isoindolinones synthesis

Rare Metals, Год журнала: 2025, Номер unknown

Опубликована: Март 7, 2025

Язык: Английский

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Selective Oxidation of Tertiary Alcohols to Ketones via Synergistic Catalysis of (NH₄)₂Ce(NO₃)₆ and Trifluoroacetic Acid With Oxygen

cMat., Год журнала: 2025, Номер 2(1)

Опубликована: Март 1, 2025

ABSTRACT Tertiary alcohols are generally considered difficult to oxidize. However, in this work, it was found that catalyzed by (NH 4 ) 2 Ce(NO 3 6 (CAN) and the presence of catalytic trifluoroacetic acid (TFA), selective oxidative C‐C bond cleavage tertiary could be achieved using O flow produce carbonyl compounds. The benefits method include use simple inexpensive catalysts, as well environmentally friendly nature process. This research significantly broadens scope alcohol oxidation chemistry. Since reactions involving have potential applications key unit reaction certain industrial processes, finding holds significant promise for organic chemical engineering.

Язык: Английский

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An efficient improvement for photocatalytic hydrogen peroxide production: Sulfur vacancies in CaIn2S4

Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137614 - 137614

Опубликована: Апрель 1, 2025

Язык: Английский

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Nanomaterials for Advanced Photocatalytic Plastic Conversion

Molecules, Год журнала: 2023, Номер 28(18), С. 6502 - 6502

Опубликована: Сен. 7, 2023

As the disposal of waste plastic emerges as a societal problem, photocatalytic conversion is attracting significant attention. Ultimately, for sustainable future, development an eco-friendly technology essential breaking away from current use environment. Compared to conventional methods, photocatalysis can be more environmentally friendly option reprocessing because it uses sunlight energy source under ambient temperature and pressure. In addition this, plastics upcycled (i.e., converted into useful chemicals or fuels) enhance their original value via methods. Among various strategies improving efficiency method, nanomaterials have played pivotal role in suppressing charge recombination. Hence, recent years, attempts been made introduce nanomaterials/nanostructures on basis advances material-based studies using simple photocatalysts. line with this trend, present review examines that recently developed discusses direction future development.

Язык: Английский

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Iron-nickel alloy particles with N-doped carbon “armor” as a highly selective and long-lasting catalyst for the synthesis of N-benzylaniline molecules

Nano Research, Год журнала: 2023, Номер 17(4), С. 2308 - 2319

Опубликована: Сен. 8, 2023

Язык: Английский

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Photocatalyzed Synthesis of a Schiff Base via C–N Bond Formation: Benzyl Alcohol as Sustainable Surrogates of Aryl Aldehydes

The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(17), С. 12576 - 12582

Опубликована: Авг. 22, 2024

The advancement of photocatalytic techniques has enabled green chemical synthesis through visible-light-mediated photochemical oxidation under mild conditions. A novel approach visible-light conditions was facilitated by eosin-Y for the reaction between substituted benzyl alcohols and anilines, resulting in diverse Schiff bases. This innovative method is emphasized its environmentally friendly nature, lack metal catalysts, cost-effectiveness, nontoxic characteristics.

Язык: Английский

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An unexpected approach to enhance specific surface area and mesopore amount of polyaniline by Zn doping

Rare Metals, Год журнала: 2024, Номер 43(9), С. 4585 - 4594

Опубликована: Май 25, 2024

Язык: Английский

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Se/ZrO₂-Catalyzed Oxidative Polymerization of Aniline

Chinese Journal of Organic Chemistry, Год журнала: 2024, Номер 44(11), С. 3392 - 3392

Опубликована: Янв. 1, 2024

Язык: Английский

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Polyaniline-Supported Tungsten-Catalyzed α-H Alkylation Reaction of Ketone with Alcohol

Organic Letters, Год журнала: 2023, Номер 25(43), С. 7928 - 7932

Опубликована: Окт. 23, 2023

α-H alkylation of carbonyls is a significant reaction in the pharmaceutical industry because it can directly form C–C bond an environmentally benign manner. Thus, developing novel catalyst for this hot and practical topic catalysis, organic synthesis, materials science. In paper, we found that polyaniline-supported tungsten could catalyze ketone with alcohol generating water as only byproduct. Polyaniline support key promoting catalytic activity tungsten, which relatively cheaper than traditionally employed noble metals. The occurred under mild conditions wide substrate scope. initial concentration was enhanced to 1 mol/L, while speed accelerated reduce time 6 h; these improvements significantly enhance production capacity. advantages make synthesis industrial purposes.

Язык: Английский

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Fabrication of a PCN/BiOBr 2D hybrid with improved photocatalytic performance of 2,4-dichorophenol degradation

RSC Advances, Год журнала: 2024, Номер 14(2), С. 1150 - 1155

Опубликована: Янв. 1, 2024

A 2D-structured PCN/BiOBr composite is constructed which exhibits improved photocatalytic 2,4-DCP degradation performance and enhanced charge separation property. S-type mechanism suggested to explain the promoted separation.

Язык: Английский

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