Stimuli-Triggered Dynamic Transformations in Supramolecular Polymers

Chemistry of Materials, Год журнала: 2024, Номер 36(13), С. 6347 - 6369

Опубликована: Июнь 24, 2024

Supramolecular polymers represent ordered nanostructures that are held together by highly directional noncovalent bonds and can undergo reversible self-assembly. Their nature imparts stimuli-responsive character to supramolecular polymers, making them appealing for the development of intelligent soft materials. As compared inherent responsiveness originating from connection units, incorporating additional units into monomeric structure allows customization stimuli-responsiveness polymers. Stimuli-triggered changes at molecular level amplify macroscopic effects due arrangement monomers. This review summarizes recent progress on stimuli-triggered transformations in categorizing five types: (i) depolymerization monomers, (ii) within different types (iii) post-stabilization (iv) activation dormant monomers situ polymerization, (v) transient polymerization with programmable lifetimes. Additionally, unconventional coupled equilibria complex systems is outlined. Emphasis design principles accumulated property response stimuli, aimed stimulating further research polymer field.

Язык: Английский

Nanothermometry and luminescence modulation via separated activators in core-shell-shell fluoride nanoparticles

Chinese Chemical Letters, Год журнала: 2025, Номер unknown, С. 111159 - 111159

Опубликована: Март 1, 2025

Язык: Английский

One dimensional water chain as a zipper in a new polymorph of trans [Cu(vanilin)2(H2O)2].2(H2O) crystal – A case of water induced polymorphism

Journal of Molecular Structure, Год журнала: 2024, Номер 1321, С. 139785 - 139785

Опубликована: Авг. 24, 2024

Язык: Английский