Recent applications of organic cages in sensing and separation processes in solution DOI Creative Commons
Sonia La Cognata, Valeria Amendola

Chemical Communications, Год журнала: 2023, Номер 59(92), С. 13668 - 13678

Опубликована: Янв. 1, 2023

Cages at work: structural tunability results in tailored properties, which makes these systems suitable for countless applications sensing and separation processes, both solution the solid state.

Язык: Английский

Dynamic Timing Control over Multicolor Molecular Emission by Temporal Chemical Locking DOI

Zezhou Zong,

Qi Zhang, Shuhai Qiu

и другие.

Angewandte Chemie International Edition, Год журнала: 2022, Номер 61(13)

Опубликована: Янв. 24, 2022

Dynamic control over molecular emission, especially in a time-dependent manner, holds great promise for the development of smart luminescent materials. Here we report series dynamic multicolor fluorescent systems based on time-encoded locking and unlocking individual vibrational emissive units. The intramolecular cyclization reaction driven by adding chemical fuel acts as lock to decrease conformational freedom units, thus varying fluorescence wavelength, while resulting chemically locked state can be automatically unlocked hydrolysis with water molecules. system fuels multiple times. emission wavelength lifetime states readily controlled elaborating structures, indicating this strategy robust versatile way modulate multi-color manner.

Язык: Английский

Процитировано

62

Instantaneous High‐Resolution Visual Imaging of Latent Fingerprints in Water Using Color‐Tunable AIE Pincer Complexes DOI
Lixin Duan, Qingshu Zheng, Tao Tu

и другие.

Advanced Materials, Год журнала: 2022, Номер 34(35)

Опубликована: Июнь 30, 2022

Instant visualization of latent fingerprints is developed by using a series water-soluble terpyridine zinc complexes as aggregation-induced emission probes in pure water, under UV light or ambient sunlight. By simply soaking, spraying with an aqueous solution the probe, bright yellow fluorescence images high contrast and resolution are readily on various surfaces including tinfoil, glass, paper, steel, leather, ceramic tile. Remarkably, can be visualized within seconds details whorl sweat pores. The color tuned from blue to orange modifying pincer ligands, allowing direct imaging These inexpensive, water-resistant, color-tunable provide practical approach for recording analysis, security protection, well criminal investigation different scenarios.

Язык: Английский

Процитировано

53

Recent advances in aggregation-induced emission (AIE)-based chemosensors for the detection of organic small molecules DOI
Ming Hui Chua, Bryan Yat Kit Hui, Kang Le Osmund Chin

и другие.

Materials Chemistry Frontiers, Год журнала: 2023, Номер 7(22), С. 5561 - 5660

Опубликована: Янв. 1, 2023

This review provides an overview of the progress in development AIE-based organic small molecule probes for detecting biologically important molecules, drug volatile compounds, and explosives over past five years.

Язык: Английский

Процитировано

39

Tetralactam macrocycle based indicator displacement assay for colorimetric and fluorometric dual-mode detection of urinary uric acid DOI
Huan Yao,

Shi-Yao Li,

Hong Zhang

и другие.

Chemical Communications, Год журнала: 2023, Номер 59(36), С. 5411 - 5414

Опубликована: Янв. 1, 2023

An indicator displacement assay for colorimetric and fluorometric dual-mode detection of urinary uric acid (UA) was constructed using a water-soluble naphthalene-based tetralactam macrocycle the phenoxazine dye, resorufin (RF). The visual UA levels volunteers successfully realized modified paper assays, which could be used home monitoring UA.

Язык: Английский

Процитировано

27

When near-infrared fluorescence meets supramolecular coordination complexes: Challenges and opportunities of metallacycles/metallacages in precision biomedicine DOI
Yuling Xu,

You Dou,

Qian Li

и другие.

Coordination Chemistry Reviews, Год журнала: 2023, Номер 493, С. 215320 - 215320

Опубликована: Июль 7, 2023

Язык: Английский

Процитировано

23

Supramolecular Fluorescence Biosensing Based on Macrocycles DOI Creative Commons

Jia‐Hong Tian,

Haiqi Xu,

Xin‐Yue Hu

и другие.

Supramolecular Materials, Год журнала: 2024, Номер 3, С. 100063 - 100063

Опубликована: Янв. 21, 2024

Fluorescence sensing converts chemical events into measurable readings by utilizing fluorescence signals for the qualitative or quantitative detection of specific analytes. Supramolecular chemistry, reliant upon non-covalent interactions, has emerged as a potent paradigm applications, garnering significant scholarly attention. The adoption supramolecular chemistry within realm offers several advantages, including easy construction, rapid response, dynamic reversibility, and compatibility with pattern recognition. Notably, molecular recognition stands pivotal facet sensing. Among integral constituents an array macrocyclic compounds boasts remarkable properties, apt diverse guest molecules, finds extensive utility in This review highlights contributions fluorescent sensors rooted crown ethers, cyclodextrins, calixarenes, cucurbiturils, other macrocycles single sensing, differential bioimaging. versatility these extends to media, encompassing aqueous environments, buffer solutions, biofluid matrices. Additionally, this provides insights future endeavors forthcoming research directions field imaging.

Язык: Английский

Процитировано

8

Optical tuning of polymer functionalized zinc oxide quantum dots as a selective probe for the detection of antibiotics DOI Creative Commons
Awadhesh Kumar Verma,

G.B.V.S. Lakshmi,

Tarun Kumar Dhiman

и другие.

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Янв. 10, 2025

Excess consumption of antibiotics leads to antibiotic resistance that hinders the control and cure microbial diseases. Therefore, it is crucial monitor levels in environment. In this proposed research work, an optical nano-sensor was devised can sense ultra-low concentration antibiotics, samples like tap water using fluorescent zinc oxide quantum dots (ZnO QDs) based nano-sensor. For this, different polymers (polyvinylalcohol–PVA polyvinylpyrrolidine–PVP) capped florescent ZnO QDs were synthesized a modified sol–gel technique. These used as probes presence antibiotics. The characterizations performed UV–visible absorption fluorescence spectroscopic methods while structural characteristics analyzed by Raman spectroscopy X-ray diffraction spectroscopy. formation confirmed Fourier transform infrared (FTIR). Charge on obtained with help ZETA potential. Here ten checked, Ciprofloxacin Moxifloxacin have shown excellent sensing specificity PVA-ZnO PVP-ZnO LOD 1.4 nM 0.8 nM, sensitivity 36.17 units/mM 19.33 respectively. This study also inferred tuning properties towards be achieved capping polymers.

Язык: Английский

Процитировано

1

A Novel Rhodamine Functionalized Schiff Base Type Ratiometric Fluorescent Chemosensor for the Sensing of Hg2+ Ions; Experimental and Theoretical Approach DOI

Sushree Suman Dash,

Patitapaban Mohanty, Pravin Kumar Kar

и другие.

Journal of Fluorescence, Год журнала: 2025, Номер unknown

Опубликована: Янв. 30, 2025

Язык: Английский

Процитировано

1

Encoding Supramolecular Chiral Self‐Assembly with Photo‐Controlled Circularly Polarized Luminescence by Overcrowded Alkene‐Based Bis‐PBI Modulators DOI

Zhao‐Tao Shi,

Qian Wang,

Jinhao Yi

и другие.

Angewandte Chemie International Edition, Год журнала: 2022, Номер 61(39)

Опубликована: Авг. 4, 2022

Developing photoresponsive circularly polarized luminescence (CPL) materials is an essential step for biosensing and biomedical applications. However, fabricating CPL assemblies rooted in the chirality amplification transmission of molecular building blocks, which simultaneously show photo-controllable signals, remains challenging. Herein, a block containing overcrowded-alkene core bis-PBI (MPBI) was designed. Importantly, enantiopure MPBI can self-assemble into well-organized nanofibers via π-π stacking interactions enable intrinsic chirality, providing opposite signals. The photoisomerization induced transformation from to discrete nanospheres, accompanied by gradually decreased signal. results demonstrated development assembly chiral MPBI, provides alternatively facile strategy fabricate CPL-active would offer opportunities future

Язык: Английский

Процитировано

34

Dynamic Covalent Bond Cross‐Linked Luminescent Silicone Elastomer with Self‐Healing and Recyclable Properties DOI
Ning Wang, Lei Feng, Xing‐Dong Xu

и другие.

Macromolecular Rapid Communications, Год журнала: 2022, Номер 43(7)

Опубликована: Фев. 3, 2022

Two aldehyde-modified tetraphenylene derivatives with different functionality are synthesized and exhibit fluorescence properties. By incorporating into polydimethylsiloxane (PDMS) networks, two elastomers prepared through dynamic covalent cross-linking. The show excellent properties, mechanical thermal stability as well self-healing recycle At the same time, properties of influenced by molecular weight PDMS. process takes place quickly recycling can be carried out solution processing hot pressing. It shows similar tensile between pristine healed samples.

Язык: Английский

Процитировано

33