Chemical Communications,
Год журнала:
2023,
Номер
59(92), С. 13668 - 13678
Опубликована: Янв. 1, 2023
Cages
at
work:
structural
tunability
results
in
tailored
properties,
which
makes
these
systems
suitable
for
countless
applications
sensing
and
separation
processes,
both
solution
the
solid
state.
Angewandte Chemie International Edition,
Год журнала:
2022,
Номер
61(13)
Опубликована: Янв. 24, 2022
Dynamic
control
over
molecular
emission,
especially
in
a
time-dependent
manner,
holds
great
promise
for
the
development
of
smart
luminescent
materials.
Here
we
report
series
dynamic
multicolor
fluorescent
systems
based
on
time-encoded
locking
and
unlocking
individual
vibrational
emissive
units.
The
intramolecular
cyclization
reaction
driven
by
adding
chemical
fuel
acts
as
lock
to
decrease
conformational
freedom
units,
thus
varying
fluorescence
wavelength,
while
resulting
chemically
locked
state
can
be
automatically
unlocked
hydrolysis
with
water
molecules.
system
fuels
multiple
times.
emission
wavelength
lifetime
states
readily
controlled
elaborating
structures,
indicating
this
strategy
robust
versatile
way
modulate
multi-color
manner.
Advanced Materials,
Год журнала:
2022,
Номер
34(35)
Опубликована: Июнь 30, 2022
Instant
visualization
of
latent
fingerprints
is
developed
by
using
a
series
water-soluble
terpyridine
zinc
complexes
as
aggregation-induced
emission
probes
in
pure
water,
under
UV
light
or
ambient
sunlight.
By
simply
soaking,
spraying
with
an
aqueous
solution
the
probe,
bright
yellow
fluorescence
images
high
contrast
and
resolution
are
readily
on
various
surfaces
including
tinfoil,
glass,
paper,
steel,
leather,
ceramic
tile.
Remarkably,
can
be
visualized
within
seconds
details
whorl
sweat
pores.
The
color
tuned
from
blue
to
orange
modifying
pincer
ligands,
allowing
direct
imaging
These
inexpensive,
water-resistant,
color-tunable
provide
practical
approach
for
recording
analysis,
security
protection,
well
criminal
investigation
different
scenarios.
Materials Chemistry Frontiers,
Год журнала:
2023,
Номер
7(22), С. 5561 - 5660
Опубликована: Янв. 1, 2023
This
review
provides
an
overview
of
the
progress
in
development
AIE-based
organic
small
molecule
probes
for
detecting
biologically
important
molecules,
drug
volatile
compounds,
and
explosives
over
past
five
years.
Chemical Communications,
Год журнала:
2023,
Номер
59(36), С. 5411 - 5414
Опубликована: Янв. 1, 2023
An
indicator
displacement
assay
for
colorimetric
and
fluorometric
dual-mode
detection
of
urinary
uric
acid
(UA)
was
constructed
using
a
water-soluble
naphthalene-based
tetralactam
macrocycle
the
phenoxazine
dye,
resorufin
(RF).
The
visual
UA
levels
volunteers
successfully
realized
modified
paper
assays,
which
could
be
used
home
monitoring
UA.
Supramolecular Materials,
Год журнала:
2024,
Номер
3, С. 100063 - 100063
Опубликована: Янв. 21, 2024
Fluorescence
sensing
converts
chemical
events
into
measurable
readings
by
utilizing
fluorescence
signals
for
the
qualitative
or
quantitative
detection
of
specific
analytes.
Supramolecular
chemistry,
reliant
upon
non-covalent
interactions,
has
emerged
as
a
potent
paradigm
applications,
garnering
significant
scholarly
attention.
The
adoption
supramolecular
chemistry
within
realm
offers
several
advantages,
including
easy
construction,
rapid
response,
dynamic
reversibility,
and
compatibility
with
pattern
recognition.
Notably,
molecular
recognition
stands
pivotal
facet
sensing.
Among
integral
constituents
an
array
macrocyclic
compounds
boasts
remarkable
properties,
apt
diverse
guest
molecules,
finds
extensive
utility
in
This
review
highlights
contributions
fluorescent
sensors
rooted
crown
ethers,
cyclodextrins,
calixarenes,
cucurbiturils,
other
macrocycles
single
sensing,
differential
bioimaging.
versatility
these
extends
to
media,
encompassing
aqueous
environments,
buffer
solutions,
biofluid
matrices.
Additionally,
this
provides
insights
future
endeavors
forthcoming
research
directions
field
imaging.
Scientific Reports,
Год журнала:
2025,
Номер
15(1)
Опубликована: Янв. 10, 2025
Excess
consumption
of
antibiotics
leads
to
antibiotic
resistance
that
hinders
the
control
and
cure
microbial
diseases.
Therefore,
it
is
crucial
monitor
levels
in
environment.
In
this
proposed
research
work,
an
optical
nano-sensor
was
devised
can
sense
ultra-low
concentration
antibiotics,
samples
like
tap
water
using
fluorescent
zinc
oxide
quantum
dots
(ZnO
QDs)
based
nano-sensor.
For
this,
different
polymers
(polyvinylalcohol–PVA
polyvinylpyrrolidine–PVP)
capped
florescent
ZnO
QDs
were
synthesized
a
modified
sol–gel
technique.
These
used
as
probes
presence
antibiotics.
The
characterizations
performed
UV–visible
absorption
fluorescence
spectroscopic
methods
while
structural
characteristics
analyzed
by
Raman
spectroscopy
X-ray
diffraction
spectroscopy.
formation
confirmed
Fourier
transform
infrared
(FTIR).
Charge
on
obtained
with
help
ZETA
potential.
Here
ten
checked,
Ciprofloxacin
Moxifloxacin
have
shown
excellent
sensing
specificity
PVA-ZnO
PVP-ZnO
LOD
1.4
nM
0.8
nM,
sensitivity
36.17
units/mM
19.33
respectively.
This
study
also
inferred
tuning
properties
towards
be
achieved
capping
polymers.
Angewandte Chemie International Edition,
Год журнала:
2022,
Номер
61(39)
Опубликована: Авг. 4, 2022
Developing
photoresponsive
circularly
polarized
luminescence
(CPL)
materials
is
an
essential
step
for
biosensing
and
biomedical
applications.
However,
fabricating
CPL
assemblies
rooted
in
the
chirality
amplification
transmission
of
molecular
building
blocks,
which
simultaneously
show
photo-controllable
signals,
remains
challenging.
Herein,
a
block
containing
overcrowded-alkene
core
bis-PBI
(MPBI)
was
designed.
Importantly,
enantiopure
MPBI
can
self-assemble
into
well-organized
nanofibers
via
π-π
stacking
interactions
enable
intrinsic
chirality,
providing
opposite
signals.
The
photoisomerization
induced
transformation
from
to
discrete
nanospheres,
accompanied
by
gradually
decreased
signal.
results
demonstrated
development
assembly
chiral
MPBI,
provides
alternatively
facile
strategy
fabricate
CPL-active
would
offer
opportunities
future
Macromolecular Rapid Communications,
Год журнала:
2022,
Номер
43(7)
Опубликована: Фев. 3, 2022
Two
aldehyde-modified
tetraphenylene
derivatives
with
different
functionality
are
synthesized
and
exhibit
fluorescence
properties.
By
incorporating
into
polydimethylsiloxane
(PDMS)
networks,
two
elastomers
prepared
through
dynamic
covalent
cross-linking.
The
show
excellent
properties,
mechanical
thermal
stability
as
well
self-healing
recycle
At
the
same
time,
properties
of
influenced
by
molecular
weight
PDMS.
process
takes
place
quickly
recycling
can
be
carried
out
solution
processing
hot
pressing.
It
shows
similar
tensile
between
pristine
healed
samples.