Recent advance in metal-organic frameworks based catalysts for production of fine chemicals via thermal catalysis

Molecular Catalysis, Год журнала: 2025, Номер 573, С. 114811 - 114811

Опубликована: Янв. 7, 2025

Язык: Английский

---

A review on recent advancements on removal of harmful metal/metal ions using graphene oxide: Experimental and theoretical approaches

The Science of The Total Environment, Год журнала: 2022, Номер 858, С. 159672 - 159672

Опубликована: Окт. 26, 2022

Язык: Английский

---

Coordination-driven electrocatalysts as an evolving wave of enthusiasm for sustainable hydrogen production

Coordination Chemistry Reviews, Год журнала: 2023, Номер 500, С. 215496 - 215496

Опубликована: Ноя. 6, 2023

Язык: Английский

---

Cu@Cu2O/carbon for efficient desalination in capacitive deionization

Chinese Chemical Letters, Год журнала: 2023, Номер 34(12), С. 108362 - 108362

Опубликована: Март 22, 2023

Язык: Английский

---

Recent advances in the heterogeneous photochemical synthesis of C–N bonds

Green Chemistry, Год журнала: 2023, Номер 25(13), С. 5010 - 5023

Опубликована: Янв. 1, 2023

Photocatalyst has been developed as an effective tool for C–N coupling due to high selectivity, mild reaction conditions and low energy comsume.

Язык: Английский

---

A novel amine-functionalized polyoxometalate-based metal-organic framework: A reusable heterogeneous nanocomposite for selective oxidation of alcohols

Journal of Molecular Structure, Год журнала: 2024, Номер 1303, С. 137503 - 137503

Опубликована: Янв. 17, 2024

Язык: Английский

---

Emerging Doped Metal–Organic Frameworks: Recent Progress in Synthesis, Applications, and First‐Principles Calculations

Small, Год журнала: 2024, Номер 20(27)

Опубликована: Фев. 11, 2024

Abstract Metal–organic frameworks (MOFs) are crystalline porous materials with a long‐range ordered structure and excellent specific surface area have found wide range of applications in diverse fields, such as catalysis, energy storage, sensing, biomedicine. However, their poor electrical conductivity chemical stability, low capacity, weak adhesion to substrates greatly limited performance. Doping has emerged unique strategy mitigate the issues. In this review, concept, classification, characterization methods doped MOFs first introduced, recent progress synthesis MOFs, well rapid advancements first‐principles calculations based on density functional theory (DFT) unraveling mechanistic origin enhanced performance summarized. Finally, perspective is included highlight key challenges doping MOF an outlook provided future research directions.

Язык: Английский

---

State-of-the-Art and Perspectives of Nickel-Based Single-Atom Catalysts

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер unknown, С. 124590 - 124590

Опубликована: Сен. 1, 2024

Язык: Английский

---

Harnessing the hydrogen evolution reaction (HER) through the electrical mobility of an embossed Ag(i)-molecular cage and a Cu(ii)-coordination polymer

Dalton Transactions, Год журнала: 2023, Номер 52(26), С. 8850 - 8856

Опубликована: Янв. 1, 2023

A structurally characterized porous Ag(I)-molecular cage AgMOC and a Cu(II)-coordination polymer CuCP with pre-synthesized ligand 1,3-bis(((E)-2-methoxybenzylidene)amino)propan-2-ol its parental amine thiocyanate are reported to harness electrical mobility-driven hydrogen evolution activity. Porosity-induced electrically conductive emerges as better electrocatalyst Tafel slope of 104 mV per decade over Cu(II)-polymer's 128 decade. The electrochemical stability durability the designed electrocatalysts in harnessing HER activity also examined under experimental conditions.

Язык: Английский

---

Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions

Chemical Engineering Journal, Год журнала: 2024, Номер 483, С. 149271 - 149271

Опубликована: Фев. 3, 2024

The development of efficient and cost-effective catalysts from renewable sources is crucial for sustainable chemistry. Herein, we developed a bio-heterogeneous Pd-nanocatalyst (PdNc@PA) by incorporating palladium nanoparticles into biodegradable kenaf-cellulose modified with poly(amidoxime) ligands. catalyst has demonstrated remarkable stability exceptional catalytic performance in range cross-coupling including Mizoroki-Heck, Suzuki-Miyaura, Tamejiro-Hiyama reactions inactivated aryl chlorides resulting high yields the desired coupling products. Additionally, PdNc@PA was also found to be effective Michael addition producing N, S, O-alkylated products yields. Furthermore, robustness recoverability allowing it reused across successive cycles without significant loss activity. incorporation resources offers an environmentally conscious alternative traditional synthetic approaches. This research highlights potential utilizing materials as supports, which could significantly diminish environmental impact waste production. Moreover, this study demonstrates versatility proficient reusable diverse array organic reactions. These discoveries provide encouraging pathway towards economically viable suitable industrial applications.

Язык: Английский

---