The Journal of Physical Chemistry C, Год журнала: 2025, Номер unknown
Опубликована: Апрель 10, 2025
Язык: Английский
Journal of Power Sources, Год журнала: 2024, Номер 621, С. 235308 - 235308
Опубликована: Авг. 23, 2024
Язык: Английский
Процитировано
4
ACS Sensors, Год журнала: 2024, Номер 9(6), С. 3357 - 3366
Опубликована: Июнь 6, 2024
The burgeoning field of continuous glucose monitoring (CGM) for diabetes management faces significant challenges, particularly in achieving precise and stable biosensor performance under changing environmental conditions such as varying concentrations O
Язык: Английский
Процитировано
3
ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown
Опубликована: Сен. 30, 2024
Preparing stable n-type flexible single-walled carbon nanotube (SWCNT)-based thermoelectric films with high (TE) performance is desirable for self-powering wearable electronics but remains a challenge. Here, the interface regulation and enhancement mechanism of ferrocene derivatives on polyethylenimine/single-walled (PEI/SWCNT) composite have been explored by doping (f-Fc-OH) into PEI/SWCNT films. The results show that introduction f-Fc-OH leads to formation "thorn" structures surfaces SWCNT bundles via hydrophilic hydrophobic interactions, generated energy-filtering effect improves properties film, f-Fc-OH-doped (f-Fc-OH/PEI/SWCNT) achieves highest room-temperature power factor 182.22 ± 8.60 μW m
Язык: Английский
Процитировано
3
Nano Energy, Год журнала: 2025, Номер unknown, С. 110720 - 110720
Опубликована: Янв. 1, 2025
Процитировано
0
ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown
Опубликована: Фев. 17, 2025
While thiol-based adsorbates have achieved significant success in surface modification and molecular electronics, their thermal storage instability has hindered long-term commercial viability. Carbene-based thin films offer a promising alternative due to enhanced stability; however, electronic properties after postfunctionalization remain be investigated. In this study, by attaching ferrocene (Fc) unit bis(diarylcarbene)-modified gold via carbodiimide coupling, the system exhibits diode behavior with current rectification ratio of ∼100. This is highly temperature-dependent, indicating that hopping dominant mechanism for rectification. Notably, demonstrated excellent electrical stability under ambient conditions over 6 months. Our work highlights potential designing carbene-based junctions through postmodification developing durable functional devices.
Язык: Английский
Процитировано
0
Journal of Materials Chemistry C, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
The Ru–polypyridyl-based resistive switching device shows non-volatile, bipolar memory and adaptive learning behavior. Ferrocenium cobaltocene reverse the bias polarity in redox-active matrices.
Язык: Английский
Процитировано
0
Dalton Transactions, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
The redox-active species of ferrocene-functionalized phenothiazine derivatives exhibit NIR absorption (700–1000 nm), and extending conjugation at the N -position reduces energy gap.
Язык: Английский
Процитировано
0
European Journal of Inorganic Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Март 11, 2025
Abstract Treatment of {Zr}( η 2 ‐Me 3 SiC≡CSiMe )(py) ({Zr}=Zr( 5 ‐C H ) ; py=C N) ( 1 with FcC(O)H (Fc=Fe( )( 4 )) a gives dimeric [{Zr}( ‐OCHFc)] ), while the reaction ketone FcC(O)Ph b produces monomeric metallaoxiran ‐OCPhFc)(Ph)] ). In contrast, compound forms [{Zr}(O=CFc ] in presence FcC(O)Fc c The structures – solid state were determined by single crystal X‐ray analysis. two ‐OCHFc) building blocks are connected to each other over oxygen bridges aldehydes being ‐coordinated. By exchanging aldehyde , is accessible σ ‐bonded phenylate ligand and bonded ‐fashion Zr(IV). within Fc C=O ketones datively zirconocene unit Zr oxidation II, demonstrating new family compounds which metallocene coordinated group metal. Further, characterized IR spectroscopy investigated matrix assisted laser desorption/ionization mass spectrometry. case its crystallisation was tracked NMR towards CH Cl high resolution
Язык: Английский
Процитировано
0
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Март 20, 2025
Abstract Despite the great potential of lead‐halide perovskite photodetectors for broadband photodetection, ion migration in perovskites and parasitic charge injection from adjacent layers remain major challenges, ultimately leading to device failure. Here, novel use an ultra‐thin layer ferrocenyl‐bis‐phenyl‐2‐carboxylate (FcPhc 2 ) is demonstrated as a hole‐blocking layer. It shown that FcPhc creates energetic barrier between electron transport layer, significantly reducing hole Ag contact. This improvement results ultralow noise spectral density 1.2 × 10 −14 A Hz −1/2 , high specific detectivity 8.1 12 Jones at −0.5 V 740 nm. In addition, effectively inhibits I − oxidation induced by injected holes reduces formed on surface, enhancing reverse bias stability. The increase stability does not compromise response speed ‐based devices operate scale 150 ns 1.3 MHz photo‐ electrical‐responses.
Язык: Английский
Процитировано
0
Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 142145 - 142145
Опубликована: Март 1, 2025
Процитировано
0