D-A-Type Molecules with Free Rotors for Highly Efficient Interfacial Solar-Driven Steam Generation and Thermoelectric Performance

Organic Letters, Год журнала: 2023, Номер 25(31), С. 5730 - 5734

Опубликована: Июль 20, 2023

Three "π"-shaped D-A-type thiodiazoloquinoxaline derivatives with different electronic structures and rotations have been prepared. Their particular allow these molecules to possess a broad absorption range sufficient intramolecular motions, dissipating energy through thermal deactivation pathway. Among the three materials, TPA-TQN showed best steam generation efficiency (84.52%) water-electricity cogeneration (63.95%). This study suggests that D-A configurations, free rotors, hydrophilicities make great contributions overall solar conversion performances.

Язык: Английский

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Bifunctional Calixarene-Decorated BODIPY-based Nanoporous Organic Polymers for the Efficient Photodegradation of Aqueous Organic Pollutants

ACS Applied Nano Materials, Год журнала: 2024, Номер 7(7), С. 7465 - 7473

Опубликована: Март 20, 2024

The increasingly severe wastewater pollution from an industry that contains organic dyes and phenols urges the development of sustainable removal technology. This work reports a bifunctional nanoporous polymer-based photocatalyst CABP by integrating boron-dipyrromethene (BODIPY) chain polymer calixarene monomer into network. exhibits higher photodegradation competency toward bisphenol A methylene blue (MB) than linear FBP. Noteworthily, good recyclability robustness were found, highlighting promising utility in treatment. Mechanistic investigations suggested discrepancy between (BPA) MB can be attributed to preference for generating different reactive oxygen species nature molecular interaction with photocatalyst. contribution demonstrates practical approach design efficient photocatalysts purification regeneration.

Язык: Английский

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A new eco-friendly fluorescent microcapsules for effective and selective detection of Hg(II)&Cu(II)

Journal of Photochemistry and Photobiology A Chemistry, Год журнала: 2023, Номер 448, С. 115346 - 115346

Опубликована: Ноя. 16, 2023

Язык: Английский

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Metal–Organic Frameworks for Sustainable Crop Disease Management: Current Applications, Mechanistic Insights, and Future Challenges

Journal of Agricultural and Food Chemistry, Год журнала: 2024, Номер 72(42), С. 22985 - 23007

Опубликована: Окт. 9, 2024

Efficient management of crop diseases and yield enhancement are essential for addressing the increasing food demands due to global population growth. Metal-organic frameworks (MOFs), which have rapidly evolved throughout 21st century, notable their vast surface area, porosity, adaptability, establishing them as highly effective vehicles controlled drug delivery. This review methodically categorizes common MOFs employed in disease details effectiveness against various pathogens. Additionally, by critically evaluating existing research, it outlines strategic approaches design drug-delivery explains mechanisms through enhance resistance. Finally, this paper identifies current challenges MOF research suggests directions future research. Through in-depth review, seeks enrich understanding applications offers valuable insights researchers practitioners.

Язык: Английский

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Unveiling new horizons: Exploring rhenium and iridium dipyrrinato complexes as luminescent theranostic agents for phototherapy

Coordination Chemistry Reviews, Год журнала: 2024, Номер 511, С. 215798 - 215798

Опубликована: Апрель 17, 2024

Язык: Английский

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A near-infrared-II light-response BODIPY-based conjugated microporous polymer for enhanced photocatalytic degradation of cationic dyes and H₂O₂ production

Chemical Communications, Год журнала: 2024, Номер 60(61), С. 7910 - 7913

Опубликована: Янв. 1, 2024

A hydrophilic BODIPY-based conjugated microporous polymer was synthesized for synergistic H 2 O production and photocatalytic degradation of cationic dyes.

Язык: Английский

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A novel multifunctional PEEK internal fixation plate regulated by Gentamicin/chitosan coating

Colloids and Surfaces B Biointerfaces, Год журнала: 2024, Номер 245, С. 114316 - 114316

Опубликована: Окт. 12, 2024

Язык: Английский

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A new dithieno[2,3-b]pyridine-fused BODIPY fluorescent probe for specific Cu2+ recognition

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Год журнала: 2025, Номер unknown, С. 125900 - 125900

Опубликована: Фев. 1, 2025

Язык: Английский

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Flexible Formation of Nanoparticles: Selectively Self-Assembling with Glycoclusters to Form Nano-Photosensitizers for Multipurpose Bioimaging and Photodynamic Therapy

Molecules, Год журнала: 2025, Номер 30(6), С. 1274 - 1274

Опубликована: Март 12, 2025

The smart construction of nano-photosensitizers (PSs) is significant for multipurpose applications, such as bioimaging, efficient photodynamic anti-tumor or anti-bacterial studies. This work reports a flexible self-assembling strategy the nano-PSs, in which PSs spontaneously form amorphous aggregates killing bacteria, self-assemble with tetraphenylethene (TPE) based glycoclusters (TPE-Glc4) to construct glyco-dots cell imaging and Tricyanofuran (TCF) TPE units were bridged furan thiophene moiety two (1 2) NIR fluorescence monomers, performance aggregation-induced generation reactive oxygen species (AIG-ROS) an aggregated state. Compared large (2-a), TPE-based encapsulated PS (2-Glc) that exhibit smaller more homogeneous hydrated size approximately 40 nm, well enhanced water-solubility biocompatibility. TPE-glycoclusters facilitate cellular uptake 2 into HepG2 cells, therefore enhancing signal therapy. Meanwhile, 2-a exhibits satisfied phototoxicity against Escherichia coli. highlights self-assembly nano-PSs multifunctional bioapplications.

Язык: Английский

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A Strategy for Increasing Singlet Oxygen Quantum Yield for Water‐Soluble Distyryl‐BODIPY Derivative

Applied Organometallic Chemistry, Год журнала: 2025, Номер 39(6)

Опубликована: Май 4, 2025

ABSTRACT The combined use of synergistic therapies in photodynamic therapy has recently gained significance for achieving more effective outcomes. In recent years, ultrasound‐assisted PDT applications have begun to be investigated phthalocyanine and BODIPY derivative compounds. compounds stand out with their adjustable photophysical photochemical properties, chemical purity, singlet oxygen generation capacity. Enhancing production by through the application ultrasound appears a promising avenue advancing this treatment method. context, exploring potential sonophotochemical properties is particular interest. limited SPDT increase importance investigating Therefore, new water‐soluble distyryl‐type fluorophore having phenyl ring substituted 4‐dibenzothienyl group at meso ‐position iodines as heavy atom 2‐ 6‐positions been synthesized successfully. capacities all intermediates target product were evaluated both photochemically sonophotochemically. It was noticed that quantum yield increased remarkably light excitation

Язык: Английский

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