Nanoscale,
Год журнала:
2024,
Номер
16(20), С. 9791 - 9801
Опубликована: Янв. 1, 2024
Triple-atom
catalysts
exhibit
moderate
adsorption
energy
for
intermediate
species,
enabling
the
optimal
performance
of
CO
2
electrocatalytic
reduction
reaction.
Science China Materials,
Год журнала:
2024,
Номер
68(1), С. 21 - 38
Опубликована: Ноя. 8, 2024
Abstract
The
conversion
of
carbon
dioxide
(CO
2
)
to
the
reduced
chemical
compounds
offers
substantial
environmental
benefits
through
minimizing
emission
greenhouse
gas
and
fostering
sustainable
practices.
Recently,
unique
properties
metal-organic
frameworks
(MOFs)
make
them
attractive
candidates
for
electrocatalytic
CO
reduction
reaction
RR),
providing
many
opportunities
develop
efficient,
selective,
environmentally
processes
mitigating
emissions
utilizing
as
a
valuable
raw
material
synthesis
fuels
chemicals.
Here,
recent
advances
in
MOFs
efficient
catalysts
RR
are
summarized.
detailed
characteristics,
mechanisms,
practical
approaches
improving
efficiency,
selectivity,
durability
under
realistic
conditions
also
clarified.
Furthermore,
outlooks
on
prospects
MOF-based
electrocatalysts
provided.
Abstract
Electrochemical
nitrate
reduction
reaction
(NO
3
−
RR)
represents
a
promising
ammonia
(NH
)
production
approach
and
has
garnered
significant
attention
in
recent
years.
Owing
to
the
highly
tunable
electronic
structures
physicochemical
properties,
alloy
materials
have
emerged
as
efficient
catalysts
for
electrochemical
NO
RR.
This
review
systematically
examines
advancements
including
binary
alloys
multi‐metal
RR,
comprehensively
analyzing
their
structure,
catalytic
activity,
mechanisms
In
addition,
relationship
between
catalysts′
composition,
active
sites,
activity
are
described,
aiming
elucidate
underlying
principles
high
guide
rational
design
of
future
catalysts.
Finally,
this
addresses
challenges
proposes
directions
research
development.
