BioNanoScience, Год журнала: 2025, Номер 15(2)
Опубликована: Апрель 10, 2025
Язык: Английский
Advanced Functional Materials, Год журнала: 2024, Номер unknown
Опубликована: Май 6, 2024
Abstract The proactive exploration of electrocatalytic conversion for renewable energy valorization is tremendous significance in addressing the issues fossil exhaustion, among which critical challenge electrocatalysis lies rational design efficient electrocatalysts that are rich earth. Among electrocatalysts, heterostructured materials exhibits immense potential optimization noble metals and elaboration non‐precious metal with durability. In this review, a systematic overview modern advances range reactions described, special interfacial brings additional functional effects. Subsequently, various synthesis methods characterization techniques also summarized. innovative classification heterostructures junction, crystal structure, structural morphology, properties components presented review. Finally, possible challenges outlooks future further discussed, including how to develop more sophisticated synthesis, characterization, theoretical calculation methods, will serve as guiding direction interface design. This review aims set trajectory providing meaningful inspiration references by advancing process carbon neutrality.
Язык: Английский
Процитировано
32
Journal of Cleaner Production, Год журнала: 2024, Номер 453, С. 142263 - 142263
Опубликована: Апрель 17, 2024
Язык: Английский
Процитировано
27
CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2024, Номер 59, С. 169 - 184
Опубликована: Апрель 1, 2024
Язык: Английский
Процитировано
25
Journal of Colloid and Interface Science, Год журнала: 2025, Номер 684, С. 658 - 667
Опубликована: Янв. 10, 2025
Язык: Английский
Процитировано
10
Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(35), С. 23940 - 23947
Опубликована: Янв. 1, 2024
Pt-PMo@UiO-66 (0.32 wt% Pt) shows the highest catalytic activity and selectivity to one –NO 2 hydrogenation in nitroarene due its novel structure synergism.
Язык: Английский
Процитировано
15
ChemSusChem, Год журнала: 2024, Номер unknown
Опубликована: Июль 10, 2024
Abstract The rampant exploitation of fossil fuels has led to the significant energy scarcity and environmental disruption, affecting sound momentum development progress human civilization. To build a closed‐loop anthropogenic carbon cycle, biofuels employing sustainable biomass feedstocks stands at forefront advancing neutrality, yet its widespread adoption is mainly hampered by high production costs. Montmorillonite, however, garnered considerable attention serving as an efficient heterogeneous catalyst ideal economic feasibility for biofuel production, primarily due affordability, accessibility, stability, excellent plasticity. Up now, nevertheless, it merely received finite concerns interests in various using montmorillonite‐based catalysts. There no timely comprehensive review that addresses this latest relevant progress. This fills gap providing systematically summary controllable synthesis, performance enhancement, applications related different kinds including biodiesel, biohydrogenated diesel, levulinate, γ ‐valerolactone, 5‐ethoxymethylfurfural, gaseous (CO, H 2 ), cycloalkane, montmorillonite catalysts modified forms. Particularly, critically depicts design strategies montmorillonite, illustrates reaction mechanisms, assesses their viability, realizing via valorization. Overall, may offer valuable insights into cost‐effective proposes strategic recommendations advancement future development.
Язык: Английский
Процитировано
13
Journal of Agricultural and Food Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Янв. 14, 2025
The biomass-derived furan aldehydes furfural (FF) and 5-hydroxymethylfurfural (HMF) are versatile platform chemicals used to produce various value-added through further valorization processes. Selectively reducing C═O in FF HMF molecules form furfuryl alcohol (FAL) 2,5-bis(hydroxymethyl)furan (BHMF), represents an important research field upgrading biomass-based compounds. Currently, the reduction of alcohols chemical transformation often leads unavoidable environmental issues formation potential byproducts. Biocatalysis has demonstrated expanded applications converting into a diverse array chemicals. This process exhibits significant organic synthesis biotechnology due its green sustainable properties. biocatalytic especially route for selective FAL BHMF. review discusses recent progress biosynthesis BHMF from Recently discovered enzymes whole cells as biocatalysts production summarized. In addition, chemoenzymatic cascades synthesizing biomass hydrolysate raw materials also discussed.
Язык: Английский
Процитировано
1
Buildings, Год журнала: 2024, Номер 14(8), С. 2569 - 2569
Опубликована: Авг. 20, 2024
With the advancement of human society, more construction and building materials are required to produce sustainable construction. The polymer their use in has been improved. Compared inorganic materials, offer numerous superior qualities may also be modified increase usefulness. Additionally, although bio-polymeric have effectively supplanted many conventional various relevant disciplines, applications construction, including façades so on, quite limited up now. Nowadays, most architects engineers find it challenging choose due proliferation new market availability manufacturing techniques. This emphasizes necessity adopting a unique scientific strategy for selection process assist picking suitable necessary civil application rather than following an obsolete traditional path that depends mostly on prior subjective personal experiences. review article identified critical concerns, inspired study, provided crucial insights into prospective field synthetic natural polymeric towards
Язык: Английский
Процитировано
7
ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер 12(15), С. 5991 - 6002
Опубликована: Апрель 4, 2024
Catalytic conversion of cellulosic biomass into polyols is an effective approach for upgrading. However, the involves cascade reactions which require various catalytic sites cooperation activating specific steps, resulting in low efficiency. Here, we propose a bifunctional catalyst containing acid and hydrogenation capacity polyol production with cellobiose as model compound cellulose. Phosphonic acids (PAs) either methyl (MPA) or aminomethyl (NH2MPA) tails were used to tune Pd/Al2O3 form monolayers, thereby modulating surface physiochemical properties introducing multiple sites. An increasing ratio PdO/Pd strong metal–support interaction observed after PA modification, could boost activity cellobiose. Furthermore, Pd/Al2O3-MPA exhibited excellent hydrolytic due increase Lewis good durability under hydrothermal conditions by MPA achieving 78.5% yield sorbitol at 180 °C 5 h. A plausible mechanism enhancing synergistic effect Pd support over was also proposed. This investigation provides novel strategy rationally designing hydrothermally stable catalysts utilize more way.
Язык: Английский
Процитировано
6
Catalysts, Год журнала: 2024, Номер 14(8), С. 499 - 499
Опубликована: Авг. 1, 2024
With the continuous depletion of fossil resources and deterioration global climate, it is particularly urgent to find green sustainable renewable replace non-renewable resources. Renewable biomass, which converts stores light energy into chemical through photosynthesis by plants, has received widespread attention due its simultaneous resource properties. Therefore, this article focuses on lignocellulose, an important component in fields conversion high-value-added preparation. A detailed review was conducted application catalysts biomass bio-char, bio-oil, bio-gas, high-value added chemicals their derivatives, represented 5-hydroxymethylfurfural (5-HMF) levulinic acid (LA). At same time, difficulties challenges encountered were analyzed, new ideas proposed for future development directions, so as provide pathways efficient chemicals.
Язык: Английский
Процитировано
6