Crystal structure of 1-(1,3-benzothiazol-2-yl)-3-(4-bromobenzoyl)thiourea DOI Creative Commons
Salif Sow,

Mariama Thiam,

Felix Odame

и другие.

Acta Crystallographica Section E Crystallographic Communications, Год журнала: 2024, Номер 80(6), С. 663 - 666

Опубликована: Май 31, 2024

The chemical reaction of 4-bromobenzoylchloride and 2-aminothiazole in the presence potassium thiocyanate yielded a white solid formulated as C 15 H 10 BrN 3 OS 2 , which consists 4-bromobenzamido 2-benzothiazolyl moieties connected by thiourea group. are trans conformtion (sometimes also called s -trans due to single bond) with respect N—C bond. dihedral angle between mean planes 4-bromophenyl units is 10.45 (11)°. moiety, —C—NH—C(=S) —NH— fragment forms 8.64 (12)° ring almost coplanar 1.94 molecular structure stabilized intramolecular N—H...O hydrogen bonds, resulting formation an S (6) ring. In crystal, pairs adjacent molecules interact via intermolecular bonds type C—H...N, C—H...S N—H...S, layers parallel ac plane.

Язык: Английский

Green synthesis and in vitro anticancer evaluation of 1,2-disubstituted benzimidazole derivatives DOI Creative Commons
Alcives Avila‐Sorrosa,

Luis Ángel Gil-Ruiz,

Marı́a Elena Vargas-Dı́az

и другие.

Results in Chemistry, Год журнала: 2025, Номер unknown, С. 102134 - 102134

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Green synthesis of benzimidazoles via the palladium catalyzed one-pot reductive coupling of nitroarylamines with nitriles DOI
Kun Zhou,

Xing Sheng,

Haibo Liu

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141747 - 141747

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Polyoxometalate on functionalized graphene sheets as a hybrid catalyst for efficient synthesis of benzimidazoles DOI Creative Commons

Soghra Hossinimotlagh,

Ali Zarnegaryan,

Zahra Dehbanipour

и другие.

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Март 6, 2025

In this work, graphene oxide (GO) nanoparticles were synthesized and subsequently modified using 3-aminopropyltrimethoxysilane (APTMS). An Anderson-type polyoxometalate [(C4H9)4N]2[CrMo6O18(OH)6] was then immobilized on the surface of nanoparticles. The obtained catalyst characterized Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray (EDS), inductively coupled plasma (ICP), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Raman spectroscopy, diffraction (XRD). catalytic performance recyclable hybrid evaluated for synthesis benzimidazole derivatives at 75 °C under solvent-based conditions. demonstrated easy separation could be successfully reused least six times with only a slight reduction in yield desired product. Leaching recovery tests, along FT-IR analysis, confirmed high stability catalytically active species heterogeneous nature catalyst.

Язык: Английский

Процитировано

0
Immobilization of CuO onto melamine functionalized magnetic nanocomposite: an efficient catalyst for the Preparation of benzimidazole compounds DOI Creative Commons

Zeinab Asdollahpour,

Robabeh Baharfar, Sakineh Asghari

и другие.

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Апрель 3, 2025

Язык: Английский

Процитировано

0
Benzimidazole-scaffold based fluorescent probes for sensing and bioimaging applications DOI
Junhyuk Kim, Satish Balasaheb Nimse

Coordination Chemistry Reviews, Год журнала: 2025, Номер 537, С. 216690 - 216690

Опубликована: Апрель 14, 2025

Язык: Английский

Процитировано

0
Heterogeneous Catalysis in the Synthesis of Nitrogen‐Containing Heterocyclics DOI

A. Rajendran,

Samika Anand,

K.R. Sunaja Devi

и другие.

ChemistrySelect, Год журнала: 2024, Номер 9(41)

Опубликована: Окт. 28, 2024

Abstract The synthesis of nitrogen‐containing heterocyclic compounds using heterogeneous catalysis is a topic significant interest in organic and chemical research. Heterogeneous offers several advantages over homogeneous catalysis, including easier separation recovery the catalyst, reduced waste generation, potentially higher stability reusability. In this review, pivotal role synthesizing explored. Various types heterocycles specific applications these drug discovery material development are discussed detail. This review discusses various examples catalysts employed heterocycles, metal oxides, supported metals, nanoparticles, zeolites, other porous materials. Emphasis placed on mechanistic insights reaction pathways facilitated by different catalysts. Additionally, recent advancements innovations field discussed, novel catalyst designs, green chemistry approaches, emerging trends catalytic aim to provide comprehensive overview impact potential important area synthesis.

Язык: Английский

Процитировано

1
Magnetic DL-methionine grafted to chitosan by EDTA linker nanomaterial: a highly efficient multifunctional organocatalyst for the synthesis of highly substituted imidazole derivatives under green conditions DOI
Mohammad Dohendou, Mohammad G. Dekamin,

Zahra Dehnamaki

и другие.

Research Square (Research Square), Год журнала: 2024, Номер unknown

Опубликована: Июль 18, 2024

Abstract In this research, a novel protocol for the synthesis of imidazole derivatives with various substitutions has been investigated in presence new and highly effective magnetic decorated DL-methionine amino acid grafted onto chitosan backbone by using EDTA linker (CS − MET@Fe3O4) under green chemistry conditions. The CS MET@Fe3O4 nanocomposite was properly characterized FTIR, EDX, XRD, FESEM, TGA VSM spectroscopic, microscopic, or analytical methods. used as efficient heterogeneous organocatalyst wide range three- four-substituted derivatives, an important pharmaceutical scaffold, through multicomponent reactioins (MCRs) strategy. multifunctional nanocatalyst exhibited high catalytic activity, selectivity, stability to promote reactions benzoin benzyl, different aldehyde ammonim acetate well aromatic aliphatic amine EtOH solvent. Key advantages present are excellent yields, use low loading renewable, bio-based biodegredable chitosan- acid-based nanomaterial, simple procedure preparation nanomaterial imoidazole derivatives. addition, catalyst's properties, including its properties appropriate surface area characteristicscontribute performance. Fuerthermore, can be up six cycles only slight decrease activity.

Язык: Английский

Процитировано

0
Functionalized Metal-Free Carbon Nanosphere Catalyst for the Selective C–N Bond Formation under Open-Air Conditions DOI Creative Commons

Kumar Krishan,

Bhattu Swapna, Ankit Kumar Chourasia

и другие.

ACS Omega, Год журнала: 2024, Номер 9(33), С. 35676 - 35685

Опубликована: Авг. 8, 2024

A versatile shape-controlled carbon nanomaterial that can efficiently catalyze the selective C-N coupling reactions under metal-free and open-air conditions was developed by applying N-doping KOH activation strategies in candle soot (ANCS). The TEM elemental mapping results showed formation of sphere-shaped particles as well uniform distribution nitrogen species framework. enhanced specific surface area carbon, whereas enriched electron-deficient nature introducing functional N-based pyrrolic/graphitic structures synergistic effect significantly improved catalytic efficiency catalyst (ANCS), giving a 96% conversion

Язык: Английский

Процитировано

0
Methionine-ethylenediaminetetraacetic acid-chitosan magnetic nanocomposite: a multifunctional organocatalyst for green heteroannulation of imidazoles DOI Creative Commons
Mohammad G. Dekamin, Mohammad Dohendou,

Danial Namaki

и другие.

Carbohydrate Polymer Technologies and Applications, Год журнала: 2024, Номер unknown, С. 100638 - 100638

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

0
Crystal structure of 1-(1,3-benzothiazol-2-yl)-3-(4-bromobenzoyl)thiourea DOI Creative Commons
Salif Sow,

Mariama Thiam,

Felix Odame

и другие.

Acta Crystallographica Section E Crystallographic Communications, Год журнала: 2024, Номер 80(6), С. 663 - 666

Опубликована: Май 31, 2024

The chemical reaction of 4-bromobenzoylchloride and 2-aminothiazole in the presence potassium thiocyanate yielded a white solid formulated as C 15 H 10 BrN 3 OS 2 , which consists 4-bromobenzamido 2-benzothiazolyl moieties connected by thiourea group. are trans conformtion (sometimes also called s -trans due to single bond) with respect N—C bond. dihedral angle between mean planes 4-bromophenyl units is 10.45 (11)°. moiety, —C—NH—C(=S) —NH— fragment forms 8.64 (12)° ring almost coplanar 1.94 molecular structure stabilized intramolecular N—H...O hydrogen bonds, resulting formation an S (6) ring. In crystal, pairs adjacent molecules interact via intermolecular bonds type C—H...N, C—H...S N—H...S, layers parallel ac plane.

Язык: Английский

Процитировано

0