Visible-Light-Induced Oxidation of Styrene by a Polyoxovanadate-Based Carboxylate Derivative

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 6, 2025

Revealing the design and synthesis of precisely tailored crystalline catalysts for achieving efficient photocatalytic conversion styrene into high-value-added products remains a challenging task. In this work, highly stable polyoxovanadate functionalized by dl-tartaric acid ligand H2[V4O4(H2O)6(tart)2]·H2O [1, tart = C4H2O6] was successfully synthesized conventional aqueous solution methods. The performance evaluated photosynthesis oxide employing an oxygen source as oxidant in visible light (>420 nm) conditions at room temperature with compound 1 heterogeneous catalyst. Furthermore, manifested accomplished stability reusability, maintaining high reaction activity even after three consecutive cycles. This paper not only contributes to broadening structural diversity but also sheds new on green catalytic conversion.

Язык: Английский

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MOF-808 thick crystal film grown in-situ on electrospun fiber with encapsulated Ag-PMo10V2O40 for efficient decontamination of both vesicant and nerve agent simulants

Separation and Purification Technology, Год журнала: 2025, Номер 364, С. 132368 - 132368

Опубликована: Март 5, 2025

Язык: Английский

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Efficient multi-pollutant removal: The role of Keggin polyoxometalates in polysulfone-chitosan blend membranes

International Journal of Biological Macromolecules, Год журнала: 2025, Номер 311, С. 143738 - 143738

Опубликована: Май 1, 2025

Язык: Английский

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A Meso Butterfly-Like Ce(III)-Containing Antimonotungstate with Catalytic Activity for Synthesizing Isoindolinones

Inorganic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Сен. 26, 2024

A unique meso Ce(III)-containing antimonotungstate, {Na(OAc)(H

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Controllable Synthesis and Ultrahigh Proton Conduction of a Hydrogen-Bond Network

Inorganic Chemistry, Год журнала: 2024, Номер 63(43), С. 20492 - 20500

Опубликована: Окт. 16, 2024

The functionalization of polyoxometalates with organic ligands provides a new-style strategy to accurately incorporate advanced functional moieties on their surfaces, the development which has attracted increasing research interest due potential applications. A germanium tungstate Na

Язык: Английский

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Phosphonate Lanthanide Carbonate Cages: Remarkably Aggregated Lanthanide-Oxo Cores with Removable Cation Templates

Crystal Growth & Design, Год журнала: 2025, Номер unknown

Опубликована: Фев. 24, 2025

Язык: Английский

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Enhanced Selective Oxidation of 5-Hydroxymethylfurfural with a Recyclable V34@Fe3o4/C Catalyst Enriched with Mixed-Valence Polyoxovanadate Active Centers

Опубликована: Янв. 1, 2025

Язык: Английский

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Location of dopant dictates proton-coupled electron transfer mechanism in vanadium-substituted polyoxotungstates

Chemical Science, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

An externally exposed V dopant imposes H-atom uptake at the polyoxotungstate surface and dictates proton–coupled electron transfer mechanism.

Язык: Английский

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Enhanced selective oxidation of 5-Hydroxymethylfurfural with a recyclable V34@Fe3O4/C catalyst Enriched with Mixed-valence polyoxovanadate active centers

Fuel, Год журнала: 2025, Номер 397, С. 135439 - 135439

Опубликована: Апрель 19, 2025

Язык: Английский

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Multidentate polyoxometalate modification of metal nanoparticles with tunable electronic states

Dalton Transactions, Год журнала: 2024, Номер 53(26), С. 11088 - 11093

Опубликована: Янв. 1, 2024

We present a protocol for preparing metal nanoparticles (<5 nm; Ag, Pd, Pt, and Ru) via multidentate polyoxometalate (POM) modification with enhanced stability catalytic activity. The electronic states can be modulated by POMs supports.

Язык: Английский

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