Exploring metal-organic frameworks (MOFs) in drug delivery: A concise overview of synthesis approaches, versatile applications, and current challenges

Applied Materials Today, Год журнала: 2024, Номер 41, С. 102443 - 102443

Опубликована: Сен. 21, 2024

Язык: Английский

---

Unveiling surface reactivity: the crucial role of auxiliary ligands in Gallium amidinate-based precursors for Atomic Layer Deposition

Dalton Transactions, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Two novel gallium ALD precursors, LGaMe2 and LGa(NMe2)2 with L = amidinate, were prepared. The auxiliary ligand (methyl vs . amido) dictates the growth: while halted growth after 3 cycles, enabled Ga 2 O /Ga S deposition H O/H S.

Язык: Английский

---

Synthesis of N-heterocyclic carbene‑selenium complexes modulating apoptosis and autophagy in cancer cells: Probing the interactions with biomolecules and enzymes

Bioorganic Chemistry, Год журнала: 2025, Номер 160, С. 108435 - 108435

Опубликована: Апрель 5, 2025

Язык: Английский

---

Recent Update on Catalytic Activity of N-Heterocyclic Carbene Supported on Graphene Nanosheets: A Mini Review

Journal of Organometallic Chemistry, Год журнала: 2025, Номер unknown, С. 123660 - 123660

Опубликована: Апрель 1, 2025

Язык: Английский

---

The 12-Ethynylmonocarba-closo-dodecaborate Anion: A Ligand for Metal Alkynide Complexes (M = Li, Na, Ca, Zn)

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 8, 2025

We report the first isolation of metal alkynide complexes (2a-d) incorporating lithium, sodium, calcium and zinc based on monocarborane endo/exo-dianionic framework [CB11H11-12-C≡C]2-. These are synthesized via deprotonation terminal alkynes optimized using calcium, hexamethyldisilazide bases to achieve enhanced yields crystal stability. X-ray crystallography NMR spectroscopy reveal unique coordination geometries, including a rare chair-shaped Li4C2O2 unit in 2a, multinuclear units 2b-c, hexagonal Zn3C3 2d. Subsequent nucleophilic reactions with benzophenone afford propargylic alcohols (3) high efficiency, demonstrating their utility selective synthetic routes for complex molecular assembly. This work not only highlights reactivity alkali alkaline-earth metals acetylides but also offers valuable insights into structural characteristics potential applications advanced materials catalytic systems.

Язык: Английский

---

Novel manganese tricarbonyl complexes with benzimidazole ligands: Investigation of CO-releasing, antioxidant, antibacterial, zeta potential, theoretical, and electrochemical properties

Inorganica Chimica Acta, Год журнала: 2025, Номер unknown, С. 122752 - 122752

Опубликована: Май 1, 2025

Язык: Английский

---

Ligand Structure Effects on the Stability of Cationic Zirconocene Dimethylaniline Complexes: Insights from Density Functional Theory

ACS Omega, Год журнала: 2025, Номер unknown

Опубликована: Май 23, 2025

Язык: Английский

---

Synthesis and comparative study of (NHC_F)PdCl₂Py and (NHC_F)Ni(Cp)Cl complexes: investigation of the electronic properties of NHC ligands and complex characteristics

Dalton Transactions, Год журнала: 2024, Номер 53(30), С. 12503 - 12518

Опубликована: Янв. 1, 2024

Nickel and palladium NHC complexes with fluorine substituents have been synthesized. Their electronic parameters, including σ-donation π-acceptance, were evaluated, considering the position number of substituents.

Язык: Английский

---

Design and synthesis of self-assembled Pt(II)-based macrocycle and interaction with thiocyanate ion

Inorganica Chimica Acta, Год журнала: 2024, Номер unknown, С. 122448 - 122448

Опубликована: Ноя. 1, 2024

Язык: Английский

---