pH-responsive drug carriers MIL-125(Ti)-NH2 and MIL-125(Ti) for delivering colorectal cancer therapeutics 5-fluorouracil
Journal of Porous Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 1, 2025
Язык: Английский
Multifunctional sorafenib-loaded MXene for enhanced cancer therapy: In vitro and in vivo study based on chemotherapy/photothermal therapy approach
International Journal of Pharmaceutics,
Год журнала:
2025,
Номер
unknown, С. 125492 - 125492
Опубликована: Март 1, 2025
Язык: Английский
Enrichment of Trace Selenium in Water Based on Metal−Organic Framework Materials and Reversed−Phase Ultra−High−Performance Liquid Chromatography−Diode Array Determination
Separations,
Год журнала:
2025,
Номер
12(3), С. 62 - 62
Опубликована: Март 9, 2025
A
method
for
the
determination
of
trace
selenium
in
water
enriched
by
metal–organic−framework
material
(MIL−125−NH2)
and
reversed−phase
ultra−high−performance
liquid
chromatography−diode
array
detection
(UPLC−DAD)
was
established.
The
MIL−125−NH2
material,
synthesized
microwave
method,
characterized
SEM,
XRD,
FT−IR.
added
to
sample
enrich
selenium,
desorbed
with
dilute
HCl,
then
derivative
reaction
0.1
mol·L−1
4−nitro−o−phenylenediamine
performed
produce
piaselenole.
After
extraction
cyclohexane,
retention
time
spectrogram
were
qualitatively
detected
a
detector,
peak
area
quantitatively
detected.
pH,
time,
amount
extractant,
other
conditions
derivation
enrichment
optimized
experiment,
methodology
verified
under
conditions.
results
showed
that
linear
correlation
coefficient
R2
0.9998,
limit
0.13
μg·L−1
without
close
ICP−MS
after
10−fold
0.013
μg·L−1,
RSD
0.7~2.7%,
recovery
87.8~102.1%,
range
2~1000
μg·L−1.
Therefore,
can
be
applied
tap
water,
river
mountain
spring
packaged
drinking
industrial
sewage.
Язык: Английский
Enhancing Methanol/Water Activation for Photothermal Hydrogen Production: Modulation of Cu-pyridine Sites in UiO-67 Metal-Organic Frameworks
Applied Catalysis B Environment and Energy,
Год журнала:
2025,
Номер
unknown, С. 125376 - 125376
Опубликована: Апрель 1, 2025
Язык: Английский
A flexible electrochemical sensor based on paper cellulose fibers network loaded with Mn3O4-UiO-67 for Ultrasensitive detection of methylmercury (MeHg)
Microchemical Journal,
Год журнала:
2025,
Номер
unknown, С. 113778 - 113778
Опубликована: Апрель 1, 2025
Язык: Английский
Advances in Green Synthesis and Photo-/Electrocatalytic Applications of Zirconium-Based MOFs: A Review
Organics,
Год журнала:
2025,
Номер
6(2), С. 22 - 22
Опубликована: Май 9, 2025
Metal–organic
frameworks
(MOFs),
particularly
zirconium-based
(Zr-MOFs),
have
gained
significant
attention
in
recent
years
due
to
their
unique
structural
and
functional
properties.
This
review
focuses
on
eco-friendly
synthetic
methods
for
producing
Zr-MOFs,
addressing
the
environmental
impacts
costs
associated
with
conventional
synthesis,
which
often
relies
hazardous
reagents
harsh
conditions.
We
explore
various
green
synthesis
strategies,
including
selection
of
raw
materials
(such
as
using
zirconium
acetate),
organic
ligands
(recycling
waste
ligand
synthesis),
(solvothermal,
microwave-assisted,
ultrasound-assisted,
electrochemical,
mechanochemical
approaches).
Additionally,
application
Zr-MOFs
photocatalysis
electrocatalysis
is
examined,
highlighting
potential
purification
energy
conversion.
Despite
progress
made
laboratory
settings,
challenges
remain
achieving
cost-effectiveness,
material
stability,
scalability
industrial
applications.
Future
research
should
concentrate
enhancing
efficiency,
optimizing
catalytic
properties,
investigating
structure–property
relationships,
expanding
applications
novel
reactions,
thus
ensuring
can
contribute
sustainable
development
chemical
science
technology.
Язык: Английский
Transition metal supported UiO-67 materials and their applications in catalysis
Frontiers in Chemistry,
Год журнала:
2025,
Номер
13
Опубликована: Май 30, 2025
Metal-organic
frameworks
(MOFs)
have
emerged
as
promising
platforms
for
heterogeneous
catalysis
due
to
their
tunable
structures
and
high
specific
surface
areas.
Results
indicate
that
modified
composite
MOFs
not
only
exhibit
superior
water
stability
but
also
demonstrate
broader
applicability
in
catalysis,
such
Fenton-like
oxidation,
Morita-Baylis-Hillman
reactions,
ethylene
dimerization,
various
photoelectrochemical
processes.
Among
them,
UiO-67,
a
zirconium-based
MOF,
has
attracted
extensive
attention
its
exceptional
chemical
stability,
catalytic
activity,
well-defined
microporous
structure.
This
review
introduces
composites
formed
by
different
types
of
single
multi-metal
loadings
on
UiO-67
demonstrated
performance.
It
emphasizes
the
structure-performance
relationships
these
composites,
highlighting
how
metal
loading
spatial
distribution
influence
reactivity
stability.
The
current
application
status
existing
challenges
series
materials
derivatives
are
systematically
reviewed.
By
integrating
experimental
results
mechanistic
insights,
this
work
underscores
transformative
potential
meeting
demands
sustainable
catalysis.
Язык: Английский