Materials, Год журнала: 2025, Номер 18(5), С. 1131 - 1131
Опубликована: Март 2, 2025
HKUST-1 (HKUST = Hong Kong University of Science and Technology) is one the most recognized metal-organic frameworks (MOFs) based on copper trimesate, extensively studied for a variety applications, such as gas storage, separation, adsorption, electrocatalysis, drug delivery, sensor photodegradation, etc. In this work, we introduce novel nanofused HKUST-1, referred to N-CuBTC (BTC trimesate), which has been synthesized with hydrothermal method at room temperature (typical synthesis from 80~120 °C). The resulting features an irregular particle morphology, numerous crystals clustering together edges that have fused, creating hierarchical pore structure. contrast traditional micro-sized octahedral (named M-CuBTC), displays unique clumped where are seamlessly integrated into cohesive This innovative formation significantly enhances mass transfer capabilities porosity accessibility. Consequently, demonstrates markedly improved catalytic performance in cyanosilylation aldehydes.
Язык: Английский