Suppressing cyclic deactivation of magnesium-calcium dual-functional materials via dispersed metal-carbonate interfaces for integrated CO2 capture and conversion DOI Creative Commons

Rongchang Cao,

Lei Liu, Hanzi Liu

и другие.

Carbon Capture Science & Technology, Год журнала: 2024, Номер 13, С. 100275 - 100275

Опубликована: Авг. 14, 2024

The integrated CO 2 capture and utilization employs chemical looping approach for suppressing the equilibrium limitations of traditional gas-solid catalytic reactions, enabling efficient conversion dilute into high-value fuels with minimal energy consumption. However, diminishing cyclic activity dual-functional materials poses significant challenges to their industrial application. Herein, we tailored a series magnesium-calcium materials, influence coordinated metals on performance were quantitatively investigated. Notably, Fe Ni Ce Mg 5 Ca 20 3 achieves cumulative yield 121.0 mmol/g over 15 cycles at 650°C, maximum 8.3 per cycle 99.0% selectivity, its capacity remains stable 10.6 37 adsorption/desorption cycles. Experimental results indicate that lattice phase separation is fundamental mechanism underlying decline in activity. strategic incorporation transition metal intermediates promotes formation dispersed metal-carbonate interfaces, providing surface hydrogenation sites accelerating decomposition reconstruction * within lattice. This modification mitigates adsorption/catalytic separation, boosts migration deoxygenation nanoparticle construction. findings offer valuable strategies designing highly DFMs utilization.

Язык: Английский

Data-driven analysis of property-performance correlations in dual functional materials for CO2 capture and utilization DOI
Lukas C. Buelens,

Louis Van de Voorde,

Varun Singh

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159596 - 159596

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1
Simple marble dust for integrated carbon capture and utilization with simulated flue gas containing oxygen and water DOI Creative Commons
Yuanyuan Wang, Shuzhuang Sun, Yuan Zhu

и другие.

Separation and Purification Technology, Год журнала: 2023, Номер 333, С. 125934 - 125934

Опубликована: Дек. 3, 2023

Marble dust is a low-cost, robust, and environmentally friendly natural material for integrated carbon capture utilization (ICCU). This study demonstrates the effect of oxygen water in flue gas on ICCU performance marble when it with reverse shift reaction (RWGS), which could potentially be scaled up application dust. The inclusion vapor augmented ability calcined (CM) to eliminate 12.8 mmol g−1 CO2 from achieved highest CO yield 10.2 almost 100 % selectivity. introduction O2, despite lowering efficiency, retained pore structure CM, boosting lasting producing. With inert MgO as stabilizer segregation between two-layered CaO crystalline alleviated sintering deposition, enhanced diffusion superior structural stability over consecutive cycles than raw CaO.

Язык: Английский

Процитировано

17
Bifunctional materials for integrated CO2 capture and conversion: review on adsorbent and catalyst types, recent advances, and challenges DOI

Xing Gang Zhang,

Archina Buthiyappan, Jegalakshimi Jewaratnam

и другие.

Journal of environmental chemical engineering, Год журнала: 2023, Номер 12(1), С. 111799 - 111799

Опубликована: Дек. 29, 2023

Язык: Английский

Процитировано

17
Progress in reaction mechanisms and catalyst development of carbon dioxide methanation DOI Creative Commons
Liang Han,

C.Y. Zhao,

Rui Wang

и другие.

Journal of CO2 Utilization, Год журнала: 2024, Номер 84, С. 102845 - 102845

Опубликована: Июнь 1, 2024

The overuse of fossil fuels has created a dual challenge for humanity, namely energy and environmental concerns. Excessive carbon emissions have resulted in range global climate issues. It's great practical significance to capture the excessive dioxide convert them into high value-added chemicals or fuels. Methane is an important carrier chemical bond storage due its mass calorific value. Carbon methanation promising process reducing emissions. This review introduces recent research progress on using thermal catalytic, bioconversion, photocatalytic, electrocatalytic technologies. A dual-function integrated design integrating proposed, which not only realizes on-site utilization, but also improves manufacturability economic benefits entire process.

Язык: Английский

Процитировано

6
Suppressing cyclic deactivation of magnesium-calcium dual-functional materials via dispersed metal-carbonate interfaces for integrated CO2 capture and conversion DOI Creative Commons

Rongchang Cao,

Lei Liu, Hanzi Liu

и другие.

Carbon Capture Science & Technology, Год журнала: 2024, Номер 13, С. 100275 - 100275

Опубликована: Авг. 14, 2024

The integrated CO 2 capture and utilization employs chemical looping approach for suppressing the equilibrium limitations of traditional gas-solid catalytic reactions, enabling efficient conversion dilute into high-value fuels with minimal energy consumption. However, diminishing cyclic activity dual-functional materials poses significant challenges to their industrial application. Herein, we tailored a series magnesium-calcium materials, influence coordinated metals on performance were quantitatively investigated. Notably, Fe Ni Ce Mg 5 Ca 20 3 achieves cumulative yield 121.0 mmol/g over 15 cycles at 650°C, maximum 8.3 per cycle 99.0% selectivity, its capacity remains stable 10.6 37 adsorption/desorption cycles. Experimental results indicate that lattice phase separation is fundamental mechanism underlying decline in activity. strategic incorporation transition metal intermediates promotes formation dispersed metal-carbonate interfaces, providing surface hydrogenation sites accelerating decomposition reconstruction * within lattice. This modification mitigates adsorption/catalytic separation, boosts migration deoxygenation nanoparticle construction. findings offer valuable strategies designing highly DFMs utilization.

Язык: Английский

Процитировано

4