Intermetallic Synergy in PdCuCo Catalysts Boosts C─C Bond Cleavage of Polyalcohol Electrooxidation

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 9, 2025

Abstract Multi‐metallic catalysts with specific structures play a crucial role in enhancing the selectivity and activity of chemical reactions. However, challenges such as unfavorable alcohol adsorption on catalysts, CO poisoning, high free energy barriers during oxidation processes pose significant obstacles to catalysts' ability cleave C─C bonds for complete oxidation. Here, series PdCuCo metalene electrocatalysts is reported, wherein varying intermetallic interactions among Pd, Cu, Co effectively modulate pathway. Notably, catalyst Pd 0.15 Cu 0.35 2 , synthesized by galvanic replacement metallic surface, delivers remarkably electrocatalytic ethylene glycol glycerol alkaline electrolytes (9.7 10.9 A mg −1 respectively), both which are much better than reported broadly applicable various alcohols. High performance assigned structural advantages material synergistic effects multiple metals. This synergy not merely enhances surface electronics, fostering creation exclusive active sites, but also facilitates oxidative cleavage stable bond efficient

Язык: Английский

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Tree-like hierarchical porous anode catalyst layer for efficient proton exchange membrane water electrolyzer by optimization of transportation

International Journal of Hydrogen Energy, Год журнала: 2025, Номер 123, С. 231 - 237

Опубликована: Апрель 1, 2025

Язык: Английский

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Best Practices in Membrane Electrode Assembly for Water Electrolysis

ACS Materials Letters, Год журнала: 2024, Номер 6(7), С. 2757 - 2786

Опубликована: Июнь 5, 2024

As the demand for sustainable energy sources increases, water electrolysis has attracted huge attention in research fields due to its cleanliness and high purity of hydrogen generation. Electrolysis technology involves splitting molecules into oxygen using electricity. The combined with renewable electricity makes it a key method producing sustainably. Herein, we present comprehe1nsive review systems efficient production. First, representative components membrane electrode assembly (MEA) investigations respect configurations MEAs, which are categorized as catalyst-coated substrates (CCSs) membranes (CCMs), will be discussed. Then, introduce state-of-the-art practices on electrolyzers classified alkaline (AWEs), proton exchange (PEMWEs), anion (AEMWEs). Finally, critical outlooks realize full potential highlighted.

Язык: Английский

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Recent advances and modulation tactics in Ru- and Ir-based electrocatalysts for PEMWE anodes at large current densities

eScience, Год журнала: 2024, Номер unknown, С. 100323 - 100323

Опубликована: Окт. 1, 2024

Язык: Английский

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Na-doped cobalt spinel electrocatalysts prepared by programmed electrostatic spraying for improving OER activity and durability in acidic media

Chemical Engineering Journal, Год журнала: 2024, Номер 500, С. 156846 - 156846

Опубликована: Окт. 23, 2024

Язык: Английский

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Fabrication of self‐supported catalysts via electrodeposition for proton exchange membrane water electrolysis: Emphasizing on the porous transport layers

EcoEnergy, Год журнала: 2024, Номер 2(3), С. 381 - 399

Опубликована: Авг. 2, 2024

Abstract The potential of proton exchange membrane water electrolysis (PEMWE) is enormous in tackling worldwide environmental and energy issues the face increasing risks associated with climate change scarcity. Nevertheless, economic competitiveness hydrogen production hindered by challenging operating conditions acidic environments, resulting a lower unit cost compared to alternative sources. Hence, numerous global research endeavors persist enhancing efficiency essential components PEMWE systems, specifically porous transport layer (PTL). Additionally, investigating interface between catalyst (CL) PTL, which directly system performance, imperative for future sustainability reduction. This review focuses on analysis fabrication techniques, materials, structural configurations enhance performance PTLs. we suggest use self‐supported catalysts as solutions mass charge transfer at CLs PTLs, hence facilitating wide scale. In last section provide an overview trajectory next‐generation context efficient production.

Язык: Английский

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Ionomer-free Co-Ru based electrode for efficient proton exchange membrane water electrolysis via synergistic catalysis

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161979 - 161979

Опубликована: Март 1, 2025

Язык: Английский

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Towards Next-Generation proton exchange membrane fuel Cells: The role of nanostructured catalyst layers

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163196 - 163196

Опубликована: Май 1, 2025

Язык: Английский

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Nano-Pd loaded composite membrane for reduced hydrogen crossover in proton exchange membrane water electrolysis via recasting method

Renewable Energy, Год журнала: 2024, Номер 235, С. 121285 - 121285

Опубликована: Сен. 2, 2024

Язык: Английский

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In-situ Construction of Ionic Liquid Salt-derived Graphene-like Dual-heteroatoms doping Engineering as Efficient Metal-free Electrocatalyst for Oxygen Reduction Reaction

Journal of Alloys and Compounds, Год журнала: 2024, Номер 1003, С. 175688 - 175688

Опубликована: Июль 23, 2024

Язык: Английский

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