Dual electron transfer path and LSPR photothermal enhancement in BiOCl@ZnIn₂S₄ heterojunction for enhanced photocatalytic H₂ evolution, H₂O₂ production and tetracycline removal

Inorganic Chemistry Frontiers, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

The well-designed catalyst structure can significantly enhance the efficiency of photocatalytic H 2 , O and degradation TC. This study offers novel insights into constructing a visible photothermal assisted reaction system.

Язык: Английский

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Reinforced Hole Trapping in S‐Scheme Photoharvesters for Markedly Enhanced Photocatalytic Hydrogen Evolution and Nitrogen Fixation

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 7, 2025

Abstract The S‐scheme heterojunction exerts a profoundly positive influence on enhancing carrier separation efficiency and redox capability. However, there are few reports accelerating the reaction rate of photogenerated charge carriers, particularly consumption holes in heterojunction. Herein, an situ construction strategy is employed to construct ultra‐small nonprecious metal NiO (≈2 nm) By incorporating into heterojunctions, photocatalytic hydrogen production performance significantly improved by 380 times, nitrogen fixation enhanced 20 times. Density function theoretical (DFT) calculations, X‐ray photoelectron spectroscopy (in XPS), Diffuse Reflectance Infrared Fourier Transform Spectroscopy DRIFTS) characterization results indicate that incorporation heterojunctions can not only enhance photo‐generated carriers ability but also further promote sacrificial agents, thereby achieving secondary enhancement efficiency. Therefore, (H 2 ) (N markedly improved. successful execution this work provides novel approach material structure design, offering valuable insights for development improvement high‐performance materials.

Язык: Английский

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One-Step Environment-friendly Synthesized Semiconductor ZnS/OE-PE: Solar Light Assisted Evaluation of Antibiotic Degradation, Pt-Free Hydrogen Production, and Antibacterial Assessment

Materials Today Sustainability, Год журнала: 2025, Номер unknown, С. 101071 - 101071

Опубликована: Янв. 1, 2025

Язык: Английский

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Co Nanoparticles on MnO: Electron Transfer through Ohmic and S-Scheme Heterojunction for Photocatalytic Hydrogen Evolution

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Фев. 4, 2025

The photocatalytic hydrolysis method represents a significant potential solution to the dual challenges of energy security and environmental sustainability. selection suitable materials systems is paramount importance for successful implementation hydrogen production technology. In this study, in situ reduction Co nanoparticles on MnO was successfully performed by calcining MnCo-PBA. Furthermore, graphdiyne (GDY) introduced physical agitation. introduction GDY reduced Co/MnO agglomeration made Co/MnO/GDY catalyst exhibit high activity production, with an optimum rate 2117.33 μmol·g-1·h-1, which 4.88 2.67 times higher than that Co/MnO, respectively. results photoelectrochemical test indicate composite has better photogenerated carrier separation efficiency. X-ray photoelectron spectroscopy, density functional theory calculations, electron paramagnetic resonance were used investigate transfer mechanism during process, confirming presence S-scheme heterojunction ohmic junction, enhance carriers. GDY-based constructed study significantly bimetallic catalysts.

Язык: Английский

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Efficient visible light photocatalytic green hydrogen production from Dy2O3 combined with nitrogen-deficient g-C3N4

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(3), С. 113040 - 113040

Опубликована: Май 12, 2024

Язык: Английский

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Modification strategies of TiO2-based nanocatalysts for CO2 reduction through photocatalysis: A mini review

Applied Catalysis A General, Год журнала: 2024, Номер unknown, С. 120054 - 120054

Опубликована: Дек. 1, 2024

Язык: Английский

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Regulating crystal phase of TiO2 to enhance catalytic activity of Ni/TiO2 for solar-driven dry reforming of methane

Journal of Fuel Chemistry and Technology, Год журнала: 2024, Номер 52(9), С. 1203 - 1213

Опубликована: Сен. 1, 2024

Язык: Английский

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Unveiling the Roles of Lattice Strain by Ni Exsolution on Photothermal Reduction of CO₂ Activity in BaTiO₃ Catalyst

Small, Год журнала: 2025, Номер unknown

Опубликована: Фев. 5, 2025

Abstract The lattice strain influences crystal orientation, facets exposed to external light, and atom rearrangement strongly affect catalytic activity. However, how rationally design a metal‐oxide heterojunction catalyst with featuring is great challenge. Herein, facile method adopted induce upon in situ exsolution of Ni nanoparticles from Ba 0.9 Ti 0.1 O 3‐δ (BTNO) perovskite oxide, hereby enhancing the photothermal reduction CO 2 . Lattice Ni‐exsolution dual regulation ensure that Ni‐anchored BTNO displays superb activity It shows yield 40.50 mmol g cat −1 h CH 4 19.62 , which are 14 73 times higher than those BaTiO 3 In addition, DRIFTS density functional theory (DFT) calculations reveal pathways modulates interfacial band structure enhances transfer photogenerated charge. Consequently, this study provides new approach for achieving highly efficient through engineering.

Язык: Английский

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Directed Regulation of Charge Transport Pathways in Fabricating Co9s8/Cd8.05zn1.95s10/Pt Heterojunction for High-Efficiency Photocatalytic Water Splitting

Опубликована: Янв. 1, 2025

Язык: Английский

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Photocatalytic hydrogen evolution: Recent advances in materials, modifications, and photothermal synergy

International Journal of Hydrogen Energy, Год журнала: 2025, Номер 115, С. 113 - 130

Опубликована: Март 10, 2025

Язык: Английский

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