Strong Metal–Support Interaction Facilitates the Separation of Electron–Hole Pairs at Au₁₃/BiOCl Interface: Insight from Quantum Dynamics

The Journal of Physical Chemistry Letters, Год журнала: 2025, Номер unknown, С. 611 - 617

Опубликована: Янв. 8, 2025

Focusing on Au13/BiOCl, we investigated the effects of metal–support interaction (MSI) photogenerated charge carrier separation using nonadiabatic molecular dynamic simulations combined with time-domain density functional theory. Our results show that time scales electron transfer from Au13 cluster to BiOCl are distinct depending intensity MSI. Oxygen vacancy (OV) can enhance between and BiOCl, leading a stronger (NA) coupling in Au13/BiOCl an OV system compared pristine system. The scale is reduced by factor 1.65 study suggests be facilitated enhancing MSI provides valuable principles for design high-performance photocatalysts.

Язык: Английский

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In-situ growth of flower-like CdIn2S4 on three-dimensional microspheres SnIn4S8 to form S-scheme heterojunction for efficient detection of tert-butylhydroquinone in edible oils

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161413 - 161413

Опубликована: Март 1, 2025

Язык: Английский

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Activity Rationalization and Mechanism Tracking of CO2 Photoreduction over 2D-based Layered-Bismuth-Oxyhalides

EnergyChem, Год журнала: 2025, Номер unknown, С. 100143 - 100143

Опубликована: Янв. 1, 2025

Язык: Английский

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Improvement of efficiency and selectivity of CO2 photoreduction over Bi2O2SO4 catalysts with Cu-Bi alloys

Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 106192 - 106192

Опубликована: Март 1, 2025

Язык: Английский

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Co species modulating of BiOBr-based Z-scheme heterojunction for the transform photoreduction CO2 products from CO to CH4

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161754 - 161754

Опубликована: Март 1, 2025

Язык: Английский

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Effective separation of ciprofloxacin from aqueous solutions using BiOCl/Bi2S3/biochar hybrid structure fabricated via ultrafast solid-state reaction

Applied Water Science, Год журнала: 2025, Номер 15(4)

Опубликована: Март 24, 2025

Abstract Developing a product that serves dual purpose as an adsorbent/photocatalyst for ecological applications is compelling study area. This article discusses facile ultrafast synthesis of BiOCl/Bi 2 S 3 /biochar (BiOCl/Bi /BC) by solid-state reaction with coupled roles photocatalyst during sunlight exposure and adsorbent when there no light. /BC was characterized XRD, SEM, EDX, HR-TEM, XPS, FTIR, Raman, DR/UV–Vis spectroscopy techniques. The adsorption efficiency its parameters were explored using ciprofloxacin (CPF) contaminant model drug in the absence light irradiation. role considered under direct 30 achieved removal 81.25% dark reached 90% within 1 h. exhibited triplet initial rate, doubled rate constant photocatalysis (11.34 mg g −1 min , 0.642 ) compared to (3.88 0.256 ), respectively, indicating adsorptive, catalytic, cocatalytic BC. Mechanism studies indicated separated CPF via electrostatic interaction, π – conjunction, hydrogen bonding while occurred through S-scheme mechanism where • O − h + play predominant photocatalytic degradation. Besides, hybrid stable revealed acceptable recyclability after four consecutive cycles from their aqueous solutions. work provided ultrafast, simple, economical, efficient strategy application structure has function elimination water.

Язык: Английский

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Interlayer engineering to Construct MoS2 nanoflowers with large interlayer spacing for High-Performance capacitive deionization

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132698 - 132698

Опубликована: Март 1, 2025

Язык: Английский

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Core-shell CuO@In2O3 with close contact interface enhances interfacial charge transfer for highly selective CO2 photoreduction in pure water

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132817 - 132817

Опубликована: Апрель 1, 2025

Язык: Английский

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S-scheme charge transfer pathway in a hierarchical BiOCl0.7I0.3-P/TiO2 heterojunction for bifunctional bacterial inactivation and antibiotic degradation

Ceramics International, Год журнала: 2024, Номер unknown

Опубликована: Окт. 1, 2024

Язык: Английский

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Needle growth of Nb2O5 nanoparticles on BiOCl nanosheets to fabricate S-scheme heterojunction with oxygen vacancies for enhanced photooxidation of cyclohexane

Applied Surface Science, Год журнала: 2024, Номер 680, С. 161447 - 161447

Опубликована: Окт. 6, 2024

Язык: Английский

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