Palladium-catalyzed N-arylation of (hetero)aryl chlorides with pyrroles and their analogues DOI

Ying Yin,

Yuxuan Xiao,

Xun Yang

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

A practical method for N -arylation of N–H heteroarenes with aryl chlorides through Pd/keYPhos catalyzed selective cleavage the Ar–Cl bond under mild conditions has been developed.

Язык: Английский

Palladium-Catalyzed Coupling of Aryl Chlorides with Secondary Phosphines to Construct Unsymmetrical Tertiary Phosphines DOI
Yuxuan Xiao, Xun Yang, Haiyan Li

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 29, 2024

The functionalization of the C-Cl bond in unactivated aryl chlorides under mild conditions presents a significant challenge. We disclose general protocol for constructing both partially and entirely unsymmetrical tertiary phosphines through Pd/keYPhos-catalyzed coupling with secondary conditions. reaction exhibits excellent functional group tolerance broad substrate scopes. Furthermore, rapid synthesis ligands luminescent compound sTPPs, alongside gram-scale systhesis, demonstrates practical applicability this method.

Язык: Английский

Процитировано

2
Photouranium-catalyzed hydroxylation of aryl chlorides via water splitting DOI
Kai Chen, Hang Shi

Chem Catalysis, Год журнала: 2024, Номер 4(7), С. 101062 - 101062

Опубликована: Июль 1, 2024

Язык: Английский

Процитировано

0
Protocol for hydroxylating aryl chlorides catalyzed by photouranium with water under ambient conditions DOI Creative Commons
Chengliang Li, Leiyang Bai, Xuefeng Jiang

и другие.

STAR Protocols, Год журнала: 2024, Номер 5(4), С. 103279 - 103279

Опубликована: Сен. 27, 2024

Язык: Английский

Процитировано

0
Formal Transformation of Benzylic Carboxylic Acids to Phenols DOI

Chenhao Lou,

Qiuwei Huang,

Yangyang Ma

и другие.

Chemistry - A European Journal, Год журнала: 2024, Номер unknown

Опубликована: Окт. 14, 2024

Abstract Phenols play a crucial role as core structural motifs in natural products and also serve fundamental building blocks synthetic chemistry. Apart from the known protocols for conversion of aryl precursors to phenols (i. e., decarboxylative oxygenation), we report here efficient synthesis stable readily available benzylic carboxylic acids under mild reaction conditions. The photocatalytic peroxides is step this strategy, allowing subsequent C−O bond formation via Hock rearrangement.

Язык: Английский

Процитировано

0
Palladium-catalyzed N-arylation of (hetero)aryl chlorides with pyrroles and their analogues DOI

Ying Yin,

Yuxuan Xiao,

Xun Yang

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

A practical method for N -arylation of N–H heteroarenes with aryl chlorides through Pd/keYPhos catalyzed selective cleavage the Ar–Cl bond under mild conditions has been developed.

Язык: Английский

Процитировано

0