ChemistrySelect, Год журнала: 2024, Номер 10(1)
Опубликована: Дек. 30, 2024
Abstract As one of the most stable metal‐organic frame materials (MOFs), UiO‐66 has attracted extensive attention in adsorption field. However, application is still constrained by weak electron‐hole charge separation capability and low accessibility micropores. In this study, mesoporous defects were constructed with acetic acid doped Fe 3 O 4 to prepare magnetically recyclable @UiO‐66. The doping resulted formation denatured UiO‐66, which was conducive oxytetracycline (OTC) water. crystal structure physicochemical characteristics @UiO‐66 examined. By using static technique, mechanism OTC on investigated. results reveal that an capacity 210 mg g −1 removal ratio 84.0%. pseudo‐second‐order kinetics, Elovich, Langmuir isothermal models all applicable process. process increased entropy endothermic reaction. Solution pH a little effect performance. This study provides possibility one‐step synthesis MOFs can efficiently adsorb tetracycline antibiotics water cost excellent recyclability reusablity.
Язык: Английский