Metal-Free Nitrogen-Doped Porous Carbons for Nitriles and Amides Synthesis from 1,2-Diols via Oxidative Cleavage of C–C Bonds

ACS Catalysis, Год журнала: 2023, Номер 13(22), С. 14996 - 15006

Опубликована: Ноя. 6, 2023

The oxidative cleavage and functionalization of C–C bonds in 1,2-diols have become a rapidly growing field chemical transformations. However, achieving it direct selective manner, especially using metal-free-based catalysts, remains challenging because the inherent kinetic inertness thermodynamic stability bonds. Herein, we describe general efficient metal-free N-doped porous carbon material that enables synthesis nitriles from 1,2-diols. A broad array structurally distinct mono- multisubstituted can smoothly undergo to obtain O2 as oxidant aq. NH3 nitrogen source. Notably, amidation deliver amides also be achieved with NH4OAc series control experiments verify preference selectivity for stems synergistic effect carboxylic acid group catalysts carboxylate anions. This protocol exhibits easy scalability, substrate scope, remarkable functional tolerability, recyclable catalyst. Characterization analysis experimental data reveal high catalytic activity materials is mainly attributed graphitic-N species large specific surface area.

Язык: Английский

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State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 14436 - 14474

Опубликована: Сен. 15, 2024

Язык: Английский

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Carbon-supported Co/Co₃O₄ hybrid catalyst: an efficient non-noble metal catalyst for the hydrodeoxygenation of vanillin

Catalysis Science & Technology, Год журнала: 2023, Номер 13(21), С. 6233 - 6237

Опубликована: Янв. 1, 2023

Developing Co-based catalysts with high efficiency and low cost is significant for the efficient hydrodeoxygenation of biomass-derived vanillin to 2-methoxy-4-methylphenol (MMP).

Язык: Английский

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The Oxidative C−C Bond Cleavage for the Valorization of Lignin

ChemistrySelect, Год журнала: 2024, Номер 9(17)

Опубликована: Апрель 25, 2024

Abstract Selective and efficient transformation of lignin to the value‐added chemicals is importance realize industrial application renewable biomass resources. The oxidative cleavage carbon‐carbon (C−C) bond a promising technique for depolymerization refining lignin. Herein, catalyst system valorization models summarized, which includes thermocatalytic, photocatalytic electrocatalytic approaches. In thermocatalytic system, homogeneous catalysis heterogeneous introduced discussed, respectively. For or used photocatalyst electrocatalyst emphasized. At last, insights main challenges future perspectives on have been presented.

Язык: Английский

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Aerobic oxidative C–C bond cleavage and functionalization for the synthesis of value-added chemicals

Chemical Communications, Год журнала: 2023, Номер 59(80), С. 11923 - 11931

Опубликована: Янв. 1, 2023

Aerobic oxidative cleavage of the C–C bond is summarized, focusing on reactions catalyzed by sustainable non-noble metal catalysts and carried out under mild conditions.

Язык: Английский

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