Hacettepe Journal of Biology and Chemistry,
Год журнала:
2024,
Номер
52(4), С. 217 - 236
Опубликована: Июль 19, 2024
The
aim
of
this
study
is
to
selectively
remove
As(V)
ions,
the
most
common
type
arsenic
in
drinking
water
and
especially
surface
water.
For
purpose,
a
super
macroporous
polymeric
cryogel
column
was
prepared
using
molecular
imprinting
technique.
MAC
chosen
as
functional
monomer
due
high
affinity
sulfhydryl
(-SH)
groups.
synthesized
from
amino
acid
cysteine.
Physicochemical
properties
HEMA-based
poly(HEMA-MAC)
were
determined
by
SEM
FTIR
area
swelling.
Adsorption
studies
carried
out
continuous
system.
Different
parameters
such
pH,
flow
rate,
temperature,
ionic
strength
time
studied
determine
optimum
conditions
for
removal
ion
maximum
189.4µg/g
polymer
at
pH:
5.0
15ppm
concentration.
In
selectivity
conducted
presence
PO43-,
SO42-
NO3-
ions.
According
relative
k
values
obtained
experiments,
As
IIP
shows
1.52
times
more
than
PO43-
ion,
2.61
1.53
NIP
cryogel.
From
theoretical
calculations,
it
found
that
(V)
adsorption
fit
with
Langmuir
isotherm
process
obeyed
pseudo-second
order
kinetics.
Materials,
Год журнала:
2023,
Номер
16(6), С. 2207 - 2207
Опубликована: Март 9, 2023
Climate
change
and
water
are
inseparably
connected.
Extreme
weather
events
cause
to
become
more
scarce,
polluted,
erratic
than
ever.
Therefore,
we
urgently
need
develop
solutions
reduce
contamination.
This
review
intends
demonstrate
that
pectin-based
materials
an
excellent
route
detect
mitigate
pollutants
from
water,
with
several
benefits.
Pectin
is
a
biodegradable
polymer,
extractable
vegetables,
contains
hydroxyl
carboxyl
groups
can
easily
interact
the
contaminant
ions.
In
addition,
be
prepared
in
different
forms
(films,
hydrogels,
or
beads)
cross-linked
agents
their
molecular
structure.
Consequently,
adsorbents
tuned
remove
diverse
pollutants.
Here,
will
summarize
existing
remediation
technologies
highlighting
adsorption
as
ideal
method.
Then,
focus
on
chemical
structure
of
pectin
and,
historical
perspective,
its
after
applying
cross-linking
methods.
Finally,
application
adsorbent
considering
low
degree
methoxylation.
Polymers,
Год журнала:
2023,
Номер
15(3), С. 741 - 741
Опубликована: Янв. 31, 2023
In
the
field
of
water
purification,
membrane
separation
technology
plays
a
significant
role.
Electrospinning
has
emerged
as
primary
method
to
produce
nanofiber
membranes
due
its
straightforward,
low
cost,
functional
diversity,
and
process
controllability.
It
is
possible
flexibly
control
structural
characteristics
electrospun
well
carry
out
various
material
combinations
make
full
use
their
properties,
including
high
porosity,
selectivity,
microporous
permeability
obtain
high-performance
treatment
membranes.
These
can
satisfy
fast
efficient
purification
requirements
in
different
applications
filtration
efficiency.
The
current
research
on
still
focused
creating
high-permeability
with
outstanding
remarkable
antifouling
performance,
superior
physical
chemical
long-term
stability.
This
paper
reviewed
preparation
methods
properties
for
fields,
microfiltration,
ultrafiltration,
nanofiltration,
reverse
osmosis,
forward
other
special
applications.
Lastly,
technologies
progress
were
discussed,
future
development
direction
was
also
presented.
Polymers,
Год журнала:
2023,
Номер
15(5), С. 1311 - 1311
Опубликована: Март 6, 2023
The
efficiency
in
the
capabilities
to
store
and
release
antioxidants
depends
on
film
morphology
its
manufacturing
process,
as
well
type
methodology
used
obtain
polyphenol
extracts.
Here,
hydroalcoholic
extracts
of
black
tea
polyphenols
(BT)
were
obtained
dropped
onto
different
polyvinyl
alcohol
(PVA)
aqueous
solutions
(water
or
BT
extract
with
without
citric
acid,
CA)
three
unusual
PVA
electrospun
mats
containing
nanoparticles
within
their
nanofibers.
It
was
shown
that
mat
through
precipitated
solution
presented
highest
total
content
antioxidant
activity,
addition
CA
an
esterifier
crosslinker
interfered
polyphenols.
kinetics
food
simulants
(hydrophilic,
lipophilic
acidic)
fitted
using
Fick’s
diffusion
law
Peppas’
Weibull’s
models,
showing
polymer
chain
relaxation
is
main
mechanism
all
except
for
acidic,
which
abrupt
by
about
60%
before
being
controlled.
This
research
provides
a
strategy
development
promising
controlled-release
materials
active
packaging,
mainly
hydrophilic
acidic
products.
Chemical Engineering Journal,
Год журнала:
2022,
Номер
454, С. 140168 - 140168
Опубликована: Ноя. 3, 2022
The
problem
of
arsenic
contamination
in
water
demands
sustainable,
scalable,
and
easy-to-implement
solutions.Various
nano-adsorbents
flourished
the
last
decade,
but
their
use
alone
requires
additional
filtering
processes
to
avoid
environmental
contamination.This
work
presents
a
simple,
efficient,
green
approach
overcome
this
inconvenience
while
maximizing
adsorption
capacity.We
show
for
first
time
novel
synthesizing
ultra-small
nanoparticles
(IONPs)
within
electrospun
hydrophilic
poly(vinyl
alcohol)
(PVA)
nanofibers,
avoiding
NPs
release
into
environment
when
submerged
water.The
in-situ
synthesis
favor
enhanced
capacity
due
excellent
dispersion,
tiny
size,
surface
availability
IONPs,
reaching
3.5
mg/g
at
10
μg/L.We
that
IONPs
alter
polymeric
matrix
properties,
such
as
glass
transition
temperature
crystallinity,
by
preventing
formation
strong
hydrogen
bond
inter/intramolecular
interactions
PVA.Insolubility
swelling
are
essential
characteristics
membrane,
which
allow
solution
interchange
onto
IONPs.Isotherm
studies
increase
from
1
wt%
3
content
decreases
active
sites
per
mass
IONPs.Still,
it
does
not
reusability
reaches
least
cycles
with
80
%
efficiency.We
discuss
mechanisms
phosphate
anions
partially
inhibit
As(V)
membranes
also
highly
capable
removing
Cr(VI),
independently
presence
Ni(II).
Polysaccharides,
Год журнала:
2023,
Номер
4(3), С. 219 - 255
Опубликована: Авг. 20, 2023
Adsorption
processes,
due
to
their
technical
simplicity
and
cost-effectiveness,
have
arisen
as
one
of
the
most
well-known,
straightforward
solutions
water
pollution.
In
this
context,
polysaccharides,
abundance,
biodegradability,
biocompatibility,
are
appealing
raw
materials
for
design
adsorbents.
Moreover,
some
them,
such
chitosan,
can
be
obtained
from
organic
waste
products,
use
additionally
contributes
solving
another
concerning
problem:
accumulation.
Unfortunately,
low
adsorption
capacities
and/or
physicochemical
properties,
native
polysaccharides
not
suitable
purpose.
However,
there
alternatives
that
overcome
these
physical
or
chemical
limitations,
often
taking
advantage
versatility
polyhydroxylated
structure.
review
aims
present
an
overview
advances
2019
onwards
in
new
adsorbents
treatment
cellulose,
alginate,
starch,
addressing
two
main
strategies
reported
literature:
preparation
either
polysaccharide-based
composites
polysaccharide
derivatives.
It
is
important
point
out
that,
herein,
special
emphasis
placed
on
relationship
between
structure
efficiency
analyzed
materials,
attempt
contribute
rational
polysaccharides.
Analytical Methods,
Год журнала:
2024,
Номер
16(15), С. 2386 - 2399
Опубликована: Янв. 1, 2024
l
-Cys/PCN-222
as
a
novel
and
dual-functional
fluorescent
sensor
was
developed.
It
not
only
showed
higher
chiral
recognition
of
-histidine
but
also
performed
visual
for
Hg
2+
in
actual
surface
water.