Inorganic Chemistry,
Год журнала:
2024,
Номер
63(37), С. 17032 - 17042
Опубликована: Сен. 2, 2024
Rare
earth
(RE)
dopants
can
modulate
the
bandgap
of
oxides
indium
and
gallium
provide
extra
upconversion
luminescence
(UCL)
abilities.
However,
relevant
UCL
fine-tuning
strategies
energy
mechanisms
have
been
less
studied.
In
this
research,
InGaO,
Ho
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 27, 2025
β-Ga2O3,
as
a
semiconductor
material
with
an
ultrawide
band
gap
(Eg
>
4.8
eV),
emerges
promising
candidate
for
ultraviolet
(UV)-transparent
semiconductors.
Its
distinctive
property
of
high
transparency
from
visible
light
to
the
region
gives
it
broad
application
prospects
in
fields
deep
UV
light-emitting
diodes
(LEDs),
lasers,
and
electronic
devices.
This
study
employed
first-principles
calculations
utilizing
generalized
gradient
approximation+
U
(GGA+U)
method
investigate
impact
doping
β-Ga2O3
transition
metals
including
copper
(Cu),
silver
(Ag),
gold
(Au)
on
its
structure
optical
properties.
The
findings
reveal
that
under
oxygen
(O)-rich
conditions,
formation
energy
doped
system
is
lower
compared
gallium
(Ga)-rich
conditions.
And
Cu-doped
demonstrated
possess
lowest
energy,
indicating
enhanced
stability
β-Ga2O3.
Additionally,
intrinsic
calculated
be
4.853
eV,
whereas
gaps
metal
(TM)-doped
are
significantly
reduced.
Specifically,
Cu-doped,
Ag-doped,
Au-doped
1.228,
0.982,
1.648
respectively.
reduction
can
attributed
introduction
impurity
levels
by
metals,
which
modify
electron
distribution
atoms
vicinity
Fermi
level.
Remarkably,
exhibits
superior
absorption
performance,
incorporation
such
Cu,
Ag,
Au
facilitates
expansion
range.
transformation
not
only
enhances
material's
light-harvesting
capability
but
also
improves
providing
crucial
theoretical
foundation
development
novel
β-Ga2O3-based
optoelectronic
The
fourth-generation
semiconductor
material,
gallium
oxide
(Ga2O3)
has
received
extensive
attention
for
its
wide
bandgap,
ultra-high
breakdown
electric
field,
high
temperature
resistance,
and
better
radiation
resistance.
Ga2O3
nanomaterials
are
primarily
synthesized
through
the
thermal
treatment
of
oxyhydroxide
(GaOOH),
but
synthesis
methods
GaOOH
depend
on
complex
reaction
process,
pressure,
precision
equipment
other
conditions,
resulting
applicability
is
significantly
limited.
Herein,
a
straightforward,
flexible,
environmentally
friendly,
maneuverable
method
synthesizing
presented.
Under
ambient
when
liquid
metals
(LMs)
were
immersed
in
deionized
water
(DI
water),
Ga
atoms
their
surface
can
spontaneously
capture
oxygen
oxygen-containing
groups,
thereby
transforming
into
nano-GaOOH.
Moreover,
LMs
exhibit
tension
fluidity,
which
facilitates
easy
detachment
from
under
mechanical
agitation.
Furthermore,
annealed
nanomaterials.
This
strategy
grounded
principles
sustainability
efficiency,
mitigates
unsafe
factors,
reduces
energy
consumption,
be
implemented
large
scale.
approach
plays
crucial
role
advancing
modern
technology
holds
significant
practical
implications
as
well
promising
development
prospects.
Advanced Electronic Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 10, 2025
Abstract
In
recent
years,
gallium
oxide
(Ga
2
O
3
)
has
drawn
considerable
research
interest
as
an
ultrawide‐bandgap
semiconductor
due
to
its
promising
applications
in
the
power
electronics,
photodetection,
and
gas
sensing.
Moreover,
Ga
heterojunctions
have
emerged
a
approach
address
key
limitations
of
standalone
material—most
notably,
lack
p‐type
doping
capability.
One
application
areas
for
is
ultraviolet
(UV)
which
gained
significant
attention
yet
remains
relatively
nascent
field
with
vast
potential
further
exploration
optimization.
This
review
provides
detailed
overview
current
state‐of‐the‐art
technology,
highlighting
advancements,
challenges,
emerging
strategies
aimed
at
overcoming
these
challenges.
Specifically,
it
examines
deep‐UV
analysing
compatible
electrode
materials
assessing
various
substrates
suitable
growth
enhance
device
performance.
comprehensive
designed
serve
essential
resource
researchers
engineers
working
‐based
heterojunctions,
especially
UV
photodetection.
Written
needs
new
entrants
mind,
aims
build
robust
foundational
understanding
supporting
ongoing
innovation
expansion
this
field.
Advanced Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 26, 2025
Abstract
Underwater
imaging
technologies
are
increasingly
crucial
for
environmental
monitoring
and
resource
exploration.
However,
the
development
of
advanced
photodetectors
such
applications
faces
significant
challenges,
including
interference
from
ambient
visible
infrared
light,
adaptation
to
underwater
environments,
cost‐effectiveness.
Photoelectrochemical‐type
solar‐blind
(PEC‐SBPDs)
based
on
wide
bandgap
semiconductors
have
shown
great
promise
in
overcoming
these
challenges.
Here,
a
novel
approach
enhance
performance
α‐Ga
2
O
3
‐based
PEC‐SBPDs
is
presented
through
Mg‐doping.
By
employing
low‐cost
hydrothermal
synthesis
technique,
Mg‐doped
nanorod
arrays
fabricated,
which
induces
formation
V
‐Mg
Ga
complexes
that
enhances
interfacial
catalytic
activity
improves
transport
photogenerated
carriers.
The
optimized
exhibits
remarkable
435%
increase
photocurrent
response
compared
undoped
,
with
peak
responsivity
34.54
mA
W
−1
.
A
5
×
PEC‐SBPD
array
nanorods
successfully
demonstrated
imaging,
achieving
clear
efficient
challenging
conditions.
This
study
not
only
highlights
superior
environments
but
also
opens
new
avenues
high‐performance
self‐powered
sensing,
other
related
applications.
Horticulturae,
Год журнала:
2025,
Номер
11(4), С. 387 - 387
Опубликована: Апрель 5, 2025
Houpoea
officinalis
(H.
officinalis)
flowers
are
rich
in
a
spectrum
of
bioactive
compounds
and
mineral
nutrients.
The
availability
balance
elements
directly
impact
the
morphogenesis
flower
organs,
which
play
pivotal
roles
various
physiological
biochemical
processes
that
drive
development.
However,
relatively
little
is
known
about
changes
composition
occur
during
development
H.
officinalis.
objective
this
study
to
analyze
variations
22
contents
pistil,
stamens,
petals
at
four
stages.
amount
(Na,
Mg,
K,
Ca,
V,
Cr,
Mn,
Fe,
Co,
Ni,
Cu,
Zn,
Sr,
Sn,
Al,
Ti,
Ga,
Cd,
Ba,
Tl,
Pb,
Bi)
these
samples
was
determined
using
atomic
absorption
spectroscopy
inductively
coupled
plasma
mass
spectrometry.
Results
showed
macroelements
such
as
potassium
(K,
25.80–48.06
mg/g)
calcium
(Ca,
17.27–31.00
mg/g),
well
microelements
like
zinc
(Zn,
445.17–1553.16
μg/g)
iron
(Fe,
324.27–622.31
μg/g).
Notably,
pistil
part
found
harbor
more
significant
concentration
early
developmental
stages
flowers.
Correlation
analysis
PCA
have
effectively
exposed
pronounced
association
between
accumulation
patterns
their
corresponding
organs.
These
findings
will
provide
detailed
information
distribution
different
help
encourage
researchers
enhance
quality
for
human
consumption.