Comptes Rendus Chimie,
Год журнала:
2025,
Номер
28(G1), С. 423 - 438
Опубликована: Апрель 16, 2025
PFASs
have
become
a
global
pollution
issue.
These
anthropogenic
and
unusually
stable
chemicals
been
in
use
since
the
1940s.
Thousands
of
them,
whether
molecular
or
polymeric,
developed
are
found
innumerable
industrial
processes
consumer
products.
Multiple
air
water
pathways
ensure
their
dissemination
when
released
into
environment.
They
can
adhere
to
rock
sediment,
concrete,
tarmac,
asphalt.
Humans,
animals,
plants
thus
exposed
through
air,
dust,
soil,
diet,
drinking
water,
wastewater.
Some
identified
as
very
persistent
environment,
bioaccumulative,
toxic
by
public
health
authorities.
This
review
emphasizes
that
specific
outstanding
properties
C–F
bond
derive
directly
from
fluorine’s
position
periodic
table.
Fluorinated
surfactants
also
capacity
form
large,
exceptionally
sturdy
supramolecular
self-assemblies
aqueous
solutions,
on
solid
surfaces
at
liquid
interfaces.
behavior
may
impact
fate
PFAS
pollutants
well
remediation
procedures,
fact
has
so
far
barely
recognized.
Finding
alternatives
fluorinated
fluoropolymers
deliver
comparably
high
performances
while
reducing
environmental
biological
be
extremely
challenging.
The
essential
concept
distinguishes
uses
for
which,
current
state,
hardly
find
any
replacement
product
capable
matching
demanded
those
which
lesser
performance
is
sufficient
attainable
otherwise,
not
speak
downright
futile.
need
discerning,
eco-responsible
accentuated
if
we
want
continue
benefit
unmatchable
performances.
Foods,
Год журнала:
2025,
Номер
14(6), С. 980 - 980
Опубликована: Март 13, 2025
As
food
packaging
materials
are
in
direct
contact
with
the
we
eat
and
cook
under
heat
or
pressure,
consumers
apprehensive
of
their
adverse
effects
on
products.
Perfluoroalkyl
polyfluoroalkyl
substances
(PFASs)
often
used
because
hydrophobic
properties;
however,
some
PFASs
carcinogens,
thus
prompting
further
studies
effects.
In
this
study,
a
pretreatment
method
31
coffee
was
established
using
QuEChERS
extraction
analyzed
by
liquid
chromatography-tandem
mass
spectrometry.
We
brewed
32
types
capsule
distributed
Korea,
them
for
PFASs,
evaluated
safety.
The
results
show
that
perfluorooctanoic
acid
8:2
fluorotelomer
sulfonate
levels
higher
machine-brewed
than
coffees
manually
through
paper
filter.
However,
hazard
quotient
excess
cancer
risk
all
samples
lower
World
Health
Organization
standards,
therefore,
these
considered
safe.
study
may
aid
expanding
existing
literature
PFAS
detection
relation
to
human
health.
In
this
study,
dissipative
particle
dynamics
(DPD)
simulations
were
employed
to
determine
the
critical
micelle
concentration
(CMC)
of
perfluoroalkyl
and
polyfluoroalkyl
substances
(PFAS)
in
ionic
aqueous
solutions.
This
approach
provides
precise
CMC
data
for
PFAS
surfactants
presence
various
species,
thereby
addressing
a
gap
current
literature.
Additionally,
study
contributes
development
open-source
molecular
force
fields
charged
perfluorinated
compounds,
which
are
currently
limited.
These
models
incorporate
hydration
free
energy
values
obtained
from
density
functional
theory
(DFT)
account
interactions
through
well-established
linear
relationship.
Hydrophobic
between
surfactant
tail
water
fine-tuned
match
chosen
surfactants.
Then,
DPD
successfully
predicted
diverse
range
surfactants,
including
those
based
on
hydrocarbons
PFAS,
demonstrating
ability
represent
realistic
salinities
encountered
natural
waters.
Experimental
validation
methodology
was
conducted
using
sodium
n-nonyl
sulfate
(SNS)
n-dodecyl
(SDS)
via
interfacial
tension
measurements,
confirming
accurate
representation
changes
with
salinity.
enhances
our
understanding
behavior
solutions
valuable
tool
predicting
complex
environmental
systems.
Comptes Rendus Chimie,
Год журнала:
2025,
Номер
28(G1), С. 423 - 438
Опубликована: Апрель 16, 2025
PFASs
have
become
a
global
pollution
issue.
These
anthropogenic
and
unusually
stable
chemicals
been
in
use
since
the
1940s.
Thousands
of
them,
whether
molecular
or
polymeric,
developed
are
found
innumerable
industrial
processes
consumer
products.
Multiple
air
water
pathways
ensure
their
dissemination
when
released
into
environment.
They
can
adhere
to
rock
sediment,
concrete,
tarmac,
asphalt.
Humans,
animals,
plants
thus
exposed
through
air,
dust,
soil,
diet,
drinking
water,
wastewater.
Some
identified
as
very
persistent
environment,
bioaccumulative,
toxic
by
public
health
authorities.
This
review
emphasizes
that
specific
outstanding
properties
C–F
bond
derive
directly
from
fluorine’s
position
periodic
table.
Fluorinated
surfactants
also
capacity
form
large,
exceptionally
sturdy
supramolecular
self-assemblies
aqueous
solutions,
on
solid
surfaces
at
liquid
interfaces.
behavior
may
impact
fate
PFAS
pollutants
well
remediation
procedures,
fact
has
so
far
barely
recognized.
Finding
alternatives
fluorinated
fluoropolymers
deliver
comparably
high
performances
while
reducing
environmental
biological
be
extremely
challenging.
The
essential
concept
distinguishes
uses
for
which,
current
state,
hardly
find
any
replacement
product
capable
matching
demanded
those
which
lesser
performance
is
sufficient
attainable
otherwise,
not
speak
downright
futile.
need
discerning,
eco-responsible
accentuated
if
we
want
continue
benefit
unmatchable
performances.
