
Case Studies in Chemical and Environmental Engineering, Год журнала: 2024, Номер unknown, С. 100985 - 100985
Опубликована: Окт. 1, 2024
Язык: Английский
Case Studies in Chemical and Environmental Engineering, Год журнала: 2024, Номер unknown, С. 100985 - 100985
Опубликована: Окт. 1, 2024
Язык: Английский
Arabian Journal for Science and Engineering, Год журнала: 2025, Номер unknown
Опубликована: Янв. 8, 2025
Abstract Metal–organic frameworks (MOFs) are considered promising candidates for organic pollutant remediation due to their adaptable topology, large surface area, porous structure and unsaturated metal sites. This study presents a novel, safe, environmentally friendly energy-efficient method synthesizing copper terephthalate metal–organic (Cu-BDC). The synthesis utilizes choline chloride/sorbitol deep eutectic solvent (DES), green solvent, which allows milder conditions. use of DES in Cu-BDC was calculated provide up 99% energy savings compared traditional method, showcasing the efficiency this approach. Methylene blue (MB) adsorption using synthesized samples investigated. MB selected as model molecule because its toxicity persistence aquatic environment. Compared Cu-BDC, Cu-BDC-D (synthesized form DES) showed greater effectiveness with 98.7% removal at 10 g/L catalyst dosage, pH 7, 100 mg/L initial concentration 25 °C. effects various parameters, including adsorbent temperature, on capacity were examined. kinetic data analyzed both pseudo-first-order pseudo-second-order models. results indicated that kinetics followed model, Weber Morris intraparticle diffusion Chrastil models employed further investigate processes involved adsorption. Additionally, Langmuir, Freundlich Sips isotherm analyzed, Langmuir providing best fit. Desorption experiments demonstrated could be reused three times. highlights potential MOF obtained an effective sustainable dye water treatment applications.
Язык: Английский
Процитировано
1Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141968 - 141968
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1Microporous and Mesoporous Materials, Год журнала: 2025, Номер unknown, С. 113533 - 113533
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0Crystals, Год журнала: 2025, Номер 15(3), С. 277 - 277
Опубликована: Март 17, 2025
A facile solvo-hydrothermal method was used to synthesize sub-100 nm diameter TiO2/α-Fe2O3@SiO2 nanorods (TiO2/HNRs@SiO2). Thermal annealing of TiO2/HNRs@SiO2 activated the photosensitizing crystalline TiO2 domains containing mixed anatase and rutile phases. The photocatalytic degradation methylene blue (MB), conducted using thermally annealed photocatalysts, successfully demonstrated with ~95% MB removal efficiency under mild conditions pH = ~7 room temperature ~150 min solar irradiation. enhanced attributed rapid adsorption onto surface via favorable electrostatic interactions synergistic integration α-Fe2O3 into nanorod heterostructures bandgaps 1.99–2.03 eV, allowing them absorb visible light for efficient decomposition. This study provides insights designing photocatalysts improved selectivity sustainable water treatment environmental remediation.
Язык: Английский
Процитировано
0Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163491 - 163491
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0South African Journal of Chemical Engineering, Год журнала: 2025, Номер unknown
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0Materials Today Chemistry, Год журнала: 2024, Номер 43, С. 102489 - 102489
Опубликована: Дек. 27, 2024
Язык: Английский
Процитировано
1Case Studies in Chemical and Environmental Engineering, Год журнала: 2024, Номер unknown, С. 100985 - 100985
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
0