Insights into Probing the Effect of Molecular Weight of Poly(carboxybetaine methacrylate) on the Performance of Forward Osmosis Desalination DOI

Jessika Pazol,

Xiao Tong, Gregory S. Doerk

и другие.

ACS Applied Engineering Materials, Год журнала: 2024, Номер 2(11), С. 2675 - 2688

Опубликована: Окт. 18, 2024

Zwitterionic polymers have proven to be a promising nonfouling material that can applied in the design of selective layers thin film composite (TFC) membranes. Extending permeability and usage TFC membranes attracted increasing interest membrane-based desalination processes since water-flux reduction associated with biofouling nowadays persists as common challenge. By virtue its strong hydration, this polymer category is very useful counteract marine biomedical systems, but benefits from their application membrane technology are still emerging. The efficacy property function polymer's molecular weight remains unknown. In pursuit vision, study fosters new scientific insights via probing different weights poly(carboxybetain methacrylate) (PCBMA) coated on surface layer for prepared zwitterionic (zM) exhibited excellent performance preventing water flux decay bench-scale forward osmosis system. zM revealed enhanced hydrophilic properties retained operational when compared control. Our results suggest using an intermediate-size (PCBMA Mn 50,000) will result best performance. intermediate size resulted lowest decline rate (Rt) 0.01 ± 0.001 (zM-50) unmodified control 0.56 0.071 (M0) after model BSA foulant solution. Furthermore, all similar trends observed reverse salt profiles, well. constructed serve develop further construction

Язык: Английский

Recent advances in tannic acid-based gels: Design, properties, and applications DOI
Zuwu Tang,

Ilnaz Fargul Chowdhury,

Jinbei Yang

и другие.

Advances in Colloid and Interface Science, Год журнала: 2025, Номер 339, С. 103425 - 103425

Опубликована: Фев. 15, 2025

Язык: Английский

Процитировано

5
Multi-Technique assessment of zaleplon for corrosion control in mild steel using 1M HCl media: A study incorporating molecular dynamics, electrochemical testing, and morphological evaluation DOI
Abhinay Thakur, Omar Dagdag, Avni Berisha

и другие.

Journal of the Taiwan Institute of Chemical Engineers, Год журнала: 2025, Номер 170, С. 105995 - 105995

Опубликована: Фев. 5, 2025

Язык: Английский

Процитировано

3
Electrodialysis as a key operating unit in chemical processes: From lab to pilot scale of latest breakthroughs DOI Creative Commons
Guillaume Hopsort, Quentin Cacciuttolo, David Pasquier

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 494, С. 153111 - 153111

Опубликована: Июнь 14, 2024

This review article comprehensively explores the significant advancements in electrodialysis (ED) technology within field of chemical engineering, presenting a holistic overview that spans fundamental principles, membrane materials and fabrication techniques, operational parameters, wide array applications. Unlike previous studies often narrow their focus to specific aspects ED, this work synthesizes global advances, bridging gaps between diverse research themes offer coherent understanding current trends future directions. membrane-based separation process driven by electric potential, is pivotal for its applications water purification, desalination, resource recovery, beyond. delves into evolution ion-exchange membranes, highlighting innovations materials, alongside advances techniques enhance selectivity efficiency. It also scrutinizes impact parameters on performance ED systems, addressing challenges like ion leakage, fouling, balance conductivity. Process intensification system optimization strategies are discussed, revealing how recent developments contribute energy efficiency, scalability, sustainability. The further extends emerging sectors ranging from environmental management hydrometallurgy industries, underscored case demonstrate practical implementations. Conclusively, underlines multidisciplinary approach required advancement technologies, suggesting avenues prioritize impact, economic feasibility, technological innovation. Through perspective, it aims catalyze exploration application some most pressing challenges.

Язык: Английский

Процитировано

12
Surface interaction and inhibition mechanism prediction of Aciclovir molecule on Fe (110) using computational model based on DFT, RDF and MD simulation DOI
Valentine Chikaodili Anadebe, F. E. Abeng, Abhinay Thakur

и другие.

Computational and Theoretical Chemistry, Год журнала: 2024, Номер 1238, С. 114702 - 114702

Опубликована: Июнь 12, 2024

Язык: Английский

Процитировано

11
Amphoteric surfactant of dodecyl dimethyl betaine as an efficient inhibitor for the corrosion of steel in H2SO4 solution: experimental studies and theoretical calculations DOI
Y. Charles Guan, Xianghong Li,

Simei Yang

и другие.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2025, Номер unknown, С. 136894 - 136894

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

1
An Up-to-Date Overview of Liquid Crystals and Liquid Crystal Polymers for Different Applications: A Review DOI Open Access
Jordi Guardià, José Antonio Reina, Marta Giamberini

и другие.

Polymers, Год журнала: 2024, Номер 16(16), С. 2293 - 2293

Опубликована: Авг. 14, 2024

Liquid crystals have been extensively used in various applications, such as optoelectronic devices, biomedical sensors and biosensors, packaging, among others. crystal polymers are one type of liquid material, combining their intrinsic properties with polymeric flexibility for advanced applications displays smart materials. For instance, can serve drug nanocarriers, forming cubic or hexagonal mesophases, which be tailored controlled release. Further include the preparation membranes separation processes, wastewater treatment. Furthermore, these materials ion-conducting fuel cells lithium batteries due to broad types mesophases. This review aims provide an overall explanation classification polymers. great potential relies on range determined by unique properties. Moreover, this study provides latest advances polymer-based focusing especially cells. future directions highlighted.

Язык: Английский

Процитировано

8
Construction of a Porous Zwitterionic Polyimidazole Resin for the Elimination of Technetium in Acidic Environments DOI

Juan Tong,

Y. Liu,

Lipeng Han

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Март 29, 2025

Due to the complex type of coexisting ions, remarkable acidity, and high radioactivity, efficient sustainable methods for removal pertechnetate (99TcO4-) from acidic nuclear waste streams have attracted much attention. Herein, a porous highly polymeric zwitterionic resin (PDVBVIM1.5SO3) was synthesized by installing sulfobetaine units in imidazole achieve purpose balancing hydrophilicity hydrophobicity structure improving reaction kinetics ion selectivity at same time perrhenate (ReO4-)/99TcO4- solutions. The results demonstrate that PDVBVIM1.5SO3 exhibits fast adsorption kinetics, superior capacity, excellent presence variety 1000-fold competing anions. rapid elimination ReO4- can be achieved even 1 mol L-1 HNO3. Importantly, when subject acid soaking, calcination procedure, doses ionizing radiation, maintained its structural integrity outstanding performance. Additionally, displayed efficiency toward simulated Hanford low-activity stream with ReO4-. This work demonstrates achieving balance between an exchange is great significance enhancing selection TcO4-/ReO4-, could waste-adsorbing material candidate.

Язык: Английский

Процитировано

1
Photocatalytic Application of Polymers in Removing Pharmaceuticals from Water: A Comprehensive Review DOI Open Access
Sanja J. Armaković, Stevan Armaković, Maria M. Savanović

и другие.

Catalysts, Год журнала: 2024, Номер 14(7), С. 447 - 447

Опубликована: Июль 12, 2024

This comprehensive review covers recent advancements in utilizing various types of polymers and their modifications as photocatalysts for the removal pharmaceutical contaminants from water. It also considers that enhance photocatalytic properties other materials, highlighting dual role improving water purification efficiency. Over past decades, significant progress has been made understanding polymers, including organic, inorganic, composite efficacy degrading pharmaceuticals. Some most commonly used such polyaniline, poly(p-phenylene vinylene), polyethylene oxide, polypyrole, have reviewed detail. Physical modification techniques (mechanical blending extrusion processing) chemical (nanocomposite formation, plasma techniques, surface functionalization, cross-linking) discussed appropriate modifying order to increase activity. examines latest research findings, development novel polymer-based application compounds, well optimization strategies enhancing performance. Additionally, challenges future directions this field are guide further efforts.

Язык: Английский

Процитировано

5
Computational and experimental study of terpolymers: spectroscopic, thermal, thermochemical, molecular property, and in silico toxicity analysis DOI
Nevin Çankaya, Hanifi Kebiroglu, Cengiz Soykan

и другие.

Drug and Chemical Toxicology, Год журнала: 2025, Номер unknown, С. 1 - 17

Опубликована: Фев. 28, 2025

In this study, a comprehensive analysis of the CMA2OEM-co-DVB-co-AMPS (2-(bis(cyanomethyl)amino)-2-oxoethyl methacrylate-co-divinylbenzene-co-2-acrylamido-2-methyl-1-propanesulfonic acid) and CMA2OEM-co-DVB-co-VIM methacrylate-co-divinylbenzene-co-vinylimidazole) terpolymers was conducted. The structural chemical properties were examined using Fourier transform infrared (FT-IR) spectroscopy, frontier molecular orbital analysis, electrostatic potential (MEP) maps, 1H, 13C NMR thermochemistry surface maps (TCSM), toxicity assessments, physical properties, electron localization function (ELF), total (ESP) analyses. silico analyses, quantitative structure–activity relationship (QSAR) model used for Toxicity Estimation Software Tool (TEST) ProTox 3.0, web-based virtual laboratory, oral prediction. estimates TEST showed that both exhibited low profiles. Oral prediction emphasizes may pose greater risk compared to CMA2OEM-co-DVB-co-AMPS. addition, experimental thermal characterization these also performed. These analyses have provided significant insights into applications functional terpolymers.

Язык: Английский

Процитировано

0
Optimization of ion exchange cryogel functionalization via the epoxy method for protein adsorption from ora‐pro‐nobis (Pereskia aculeata) DOI

Mariana Oliveira Mendes,

Ana Cristina Freitas de Oliveira Meira, Paula Chequer Gouveia Mól

и другие.

The Canadian Journal of Chemical Engineering, Год журнала: 2025, Номер unknown

Опубликована: Фев. 26, 2025

Abstract Ora‐pro‐nobis (OPN) is a plant with high protein content. The development of new adsorbents that enable the separation biomolecules while preserving their bioactivity has attracted interest researchers. This work reports functionalization cryogel via epoxy method and its application in adsorption OPN proteins through ion exchange, using amino acids. Among pH values types exchange ligands evaluated (cysteine, taurine, polyethyleneimine, glutamic acid), highest (54.44 mg g −1 ) was observed at 5.5 for functionalized acid (cryogel‐GA). optimal conditions were obtained 50°C 28 h, an capacity 103.37 ± 4.60 . effective bonding between acid's carboxylic/amine groups cryogel's increases site density. cryogel‐GA retained porosity (0.92%) water retention capacity, crucial purification from crude extracts. Langmuir model fitted to equilibrium isotherms, maximum 76.34 8°C, 172.41 15°C, 252.56 25°C, 400 35°C. on increased temperature. Thermodynamic analysis based Van't Hoff relationship indicated process spontaneous ( = −18.03 kJ mol 35°C) entropically driven, confirming feasibility. These results demonstrate promising matrix capture processes.

Язык: Английский

Процитировано

0