Fabrication of robust and efficient boronic acid-functionalized porphyrin-based metal–organic framework for selective adsorption of adenosine

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160919 - 160919

Опубликована: Фев. 1, 2025

Язык: Английский

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Deep eutectic solvent-modified polyvinyl alcohol/chitosan thin film membrane for dye adsorption: Machine learning modeling, experimental, and density functional theory calculations

International Journal of Biological Macromolecules, Год журнала: 2025, Номер 294, С. 139479 - 139479

Опубликована: Янв. 5, 2025

Язык: Английский

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Cationic Metal–Organic Framework Nanoparticles Based on UiO-66 for Effective ReO₄^– Capture

ACS Applied Nano Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 9, 2025

ReO4– as a hazardous waste severely threatens environmental safety and human health. The high-efficiency adsorbent for the removal of is immense interest but still faces challenges. Herein, we established cationic metal–organic framework nanoparticles by an amino protonation strategy. Based on facile green method, first introduced dense groups (6.59 mmol/g) in UiO-66 situ to prepare UiO-66-(NH2)2, during which acetic acid modulator was applied construct defects. Subsequently, UiO-66-(NH2)2 acidified UiO-66-(NH3+Cl–)2. Notably, this exhibits high adsorption capacity 590.2 mg g–1 short equilibrium time 240 min ReO4–. Besides, excellent chemical stability reusability endow UiO-66-(NH3+Cl–)2 with promising potential practical applications. Experimental characterization density functional theory (DFT) calculations suggest that electrostatic interaction, ion exchange, coordination interaction jointly contribute effective Thus, work provides highly efficient nanoparticle and, importantly, proposes feasible strategy constructing adsorbents.

Язык: Английский

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Adsorption of Ni(II) from Aqueous Solution by Wheat Straw Modified with Mercaptopropionyl Functional Groups

Langmuir, Год журнала: 2025, Номер unknown

Опубликована: Фев. 19, 2025

Mercaptopropionyl wheat straw (MPWS) was prepared as an adsorbent by modifying with mercaptopropionyl groups, and the ability of MPWS for removal Ni(II) from aqueous solution examined. The using identified through investigating impacts dosage, adsorption temperature, time. Different models isotherm kinetics were utilized to fit experimental results elucidate mechanism Ni(II). Environmental interference factors, including initial concentration, pH value, inorganic matters, organic matters in wastewater, examined evaluate antienvironmental disturbance capability during adsorption. A rate high 99.02% achieved at 6.0 temperature 30 °C a contact time 100 min. exhibited excellent alignment both pseudo-second-order kinetic model, Freundlich isothermal Redlich–Peterson Hill model. Furthermore, coexisting substances environment could inhibit process MPWS; however, this inhibition be mitigated or eliminated increasing amount absorbent MPWS. Overall, displays remarkable resistance against environmental its application removing wastewater.

Язык: Английский

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Synthesis and characterization of carbonaceous materials for lead adsorption

Resources Chemicals and Materials, Год журнала: 2025, Номер unknown, С. 100103 - 100103

Опубликована: Март 1, 2025

Язык: Английский

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From precious metal recovery to value-added MOF synthesis: Stable ZIF-8-hydrogel beads for sustainable multistage pollutant treatment

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132900 - 132900

Опубликована: Апрель 1, 2025

Язык: Английский

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Fixation behavior of oceanic manganese nodule-sodium alginate composite microspheres for heavy metal release during manganese nodule mining

Environmental Pollution, Год журнала: 2024, Номер 363, С. 125120 - 125120

Опубликована: Окт. 15, 2024

Язык: Английский

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New insights into sustainable in-situ fixation of heavy metals in disturbed seafloor sediments

Journal of Hazardous Materials, Год журнала: 2024, Номер 480, С. 136411 - 136411

Опубликована: Ноя. 7, 2024

Язык: Английский

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Efficiency of heat-treated sepiolite in the adsorption of Cd, Zn, and Co from aqueous solutions: A low-cost approach for wastewater treatment

Deleted Journal, Год журнала: 2024, Номер 2(2), С. 1562 - 1562

Опубликована: Сен. 30, 2024

This study investigated the adsorption of Cd, Co, and Zn ions onto unmodified heat-treated sepiolite, focusing on effect contact time, initial pH, heat pretreatments. Kinetic experiments were conducted in triplicate, equilibrium indicated that Co2+ had highest preference, followed by Zn2+ Cd2+. The efficiency for significantly increased with higher whereas Cd2+ showed optimal at lower pH levels. Heat-treated sepiolite 250 ℃ exhibited a surface area capacity comparison 150 ℃-treated which importance pretreatment. pseudo-second-order kinetic model better described process, it was confirmed chemisorption as rate-limiting step. By increasing rates enhanced, achieved within 480 min all systems. Higher solute concentrations led to an increase processes, Co consistently showing competitive multi-ionic solutions. Adsorption percentages varied thermal treatment, indicating these parameters optimizing sepiolite’s heavy metal removal.

Язык: Английский

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Unlocking the potential of environmentally friendly adsorbent derived from industrial wastes: A review

Chemosphere, Год журнала: 2024, Номер 367, С. 143662 - 143662

Опубликована: Ноя. 1, 2024

Язык: Английский

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