Efficient removal of a pharmaceutical compound on organoclay: batch experiment, DFT calculation, statistical physics, and modeling DOI

Fatiha Bessaha,

Gania Bessaha,

Assia Benhouria

и другие.

Chemical Engineering Communications, Год журнала: 2024, Номер unknown, С. 1 - 18

Опубликована: Ноя. 18, 2024

This study was performed to evaluate the adsorptive properties of bentonite. Natural bentonite found adsorb considerable amounts Salicylic acid (SA) after modification by hexadecyltrimethylammonium bromide (HDTMA). Batch studies investigated modified natural (organobentonite). The characterization results show increase in d001 spacing from 1.13 1.53 nm for raw and organobentonite, respectively. FTIR analysis indicates asymmetric vs. (CH2) symmetric stretching modes clay loaded with surfactant molecules are 2919 2845 cm−1, We investigate parameters such as contact time, pH, temperature, initial concentration. Desorption regeneration were also studied. kinetic shows that adsorption equilibrium salicylic onto organoclay reached 120 min fits well a pseudo-second-order model contribution intraparticular diffusion. In addition, adjustment isothermal models indicated Langmuir-Freundlich best fit isotherms data unmodified Langmuir maximum capacity organobentonite is 128 mg g−1 at 25 °C. According statistical physics model, SA could be adsorbed on surface non-parallel orientation. desorption-regeneration investigation revealed material successfully reused three cycles adsorption. Mechanistic sorption have highlighted several mechanisms: hydrogen bonding, electrostatic attraction, hydrophobic interaction.

Язык: Английский

Strong adsorption of tetracycline on carbon blacks: An in-depth study of the adsorption mechanism DOI
Xiang Li,

Lingling Zeng,

Liya Zhu

и другие.

Journal of Water Process Engineering, Год журнала: 2025, Номер 70, С. 106784 - 106784

Опубликована: Янв. 5, 2025

Язык: Английский

Процитировано

5

Exploring the state-of-the-art in metal-organic Frameworks for antibiotic adsorption: A review of performance, mechanisms, and regeneration DOI Creative Commons
Clint Sutherland

Environmental Toxicology and Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 9, 2025

The application of metal-organic frameworks (MOFs) towards the adsorption antibiotics is a new and emerging area study. rise in use or misuse antibiotic products has exacerbated their ongoing presence persistence natural environment. Even at low concentrations, residues exert pressure on bacterial populations, eventually leading to emergence resistant bacteria. Metal-organic frameworks, known for high porosity, vast specific surface area, ease modification, have emerged be promising sustainable adsorbent. In an effort advance development this adsorbent, study provides state-of-the-art review recent research published from 2020 present, specifically examining MOFs removing aqueous solutions. Multiple MOF adsorbents were analyzed, with approximately 59% demonstrating significant capacity within pH range 6.0-8.0. 75% instances, system reached equilibrium under 2 hr. Adsorption capacities compared well other works literature exceeded conventional many instances. Notable cases performance MIL-53(Al) amoxicillin (AMX) SA-g-P3AP@MOF(Fe)/Ag neomycin where 758.5 625.0 mg/g attained, respectively. reusability was extensively reported laboratory batch scale. Analysis studies revealed most effective eluents acetone, ethanol, methanol, mostly 3-5 cycles attainable without appreciable loss efficiency. confirmed that are highly efficient antibiotics; however, there some areas warrant further development. It intended work will bring trends forefront, identify knowledge gaps, help guide future proposals.

Язык: Английский

Процитировано

2

Sustainable remediation of an anionic dye in aqueous solutions using modified aluminosilicate as a highly efficient and reusable adsorbent DOI

Hadjer Bousemat,

Samira Ziane-Hezil,

Fatiha Bessaha

и другие.

Reaction Kinetics Mechanisms and Catalysis, Год журнала: 2025, Номер unknown

Опубликована: Янв. 13, 2025

Язык: Английский

Процитировано

0

Constructing metal-phenolic network (MPN) microspheres as efficient adsorbent for pollutants removal DOI
Qiang Liu, Lin Han,

Tiantian Feng

и другие.

Particuology, Год журнала: 2025, Номер unknown

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

Modulation of polymorphic structure of Ag/Ce–MOFs materials and its adsorption mechanism of Minocycline in water DOI
Lei Zhang, Lei Zhang,

Nan Zhang

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132832 - 132832

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Recent review on porous adsorbents for water decontamination: strategies for enhanced removal of tetracycline DOI
Alvin Lim Teik Zheng, Ellie Yi Lih Teo, S. Sivasangar

и другие.

Journal of Porous Materials, Год журнала: 2024, Номер 32(1), С. 1 - 25

Опубликована: Ноя. 2, 2024

Язык: Английский

Процитировано

3

Exploring Statistical Physics Principles for Superior Pefloxacin Extraction from Water via Halloysite Nanotubes: Stereographic and Topographic Evaluation DOI

A. Naifar,

Kods Oueslati, Fatma Aouaini

и другие.

Microporous and Mesoporous Materials, Год журнала: 2024, Номер 383, С. 113427 - 113427

Опубликована: Ноя. 16, 2024

Язык: Английский

Процитировано

2

Efficient removal of a pharmaceutical compound on organoclay: batch experiment, DFT calculation, statistical physics, and modeling DOI

Fatiha Bessaha,

Gania Bessaha,

Assia Benhouria

и другие.

Chemical Engineering Communications, Год журнала: 2024, Номер unknown, С. 1 - 18

Опубликована: Ноя. 18, 2024

This study was performed to evaluate the adsorptive properties of bentonite. Natural bentonite found adsorb considerable amounts Salicylic acid (SA) after modification by hexadecyltrimethylammonium bromide (HDTMA). Batch studies investigated modified natural (organobentonite). The characterization results show increase in d001 spacing from 1.13 1.53 nm for raw and organobentonite, respectively. FTIR analysis indicates asymmetric vs. (CH2) symmetric stretching modes clay loaded with surfactant molecules are 2919 2845 cm−1, We investigate parameters such as contact time, pH, temperature, initial concentration. Desorption regeneration were also studied. kinetic shows that adsorption equilibrium salicylic onto organoclay reached 120 min fits well a pseudo-second-order model contribution intraparticular diffusion. In addition, adjustment isothermal models indicated Langmuir-Freundlich best fit isotherms data unmodified Langmuir maximum capacity organobentonite is 128 mg g−1 at 25 °C. According statistical physics model, SA could be adsorbed on surface non-parallel orientation. desorption-regeneration investigation revealed material successfully reused three cycles adsorption. Mechanistic sorption have highlighted several mechanisms: hydrogen bonding, electrostatic attraction, hydrophobic interaction.

Язык: Английский

Процитировано

0