New Cu(II), Cu(I) and Ag(I) Complexes of Phenoxy-Ketimine Schiff Base Ligands: Synthesis, Structures and Antibacterial Activity DOI Creative Commons

Miriam Caviglia,

Zhenzhen Li,

Carlo Santini

и другие.

Molecules, Год журнала: 2025, Номер 30(9), С. 1893 - 1893

Опубликована: Апрель 24, 2025

Two phenoxy-ketimines ligands, 2-(1-(benzylimino)ethyl)phenol (HLBSMe) and 2-((benzylimino)(phenyl)methyl)phenol (HLBSPh), were synthesized used as supporting ligands of new copper(II), copper(I), silver(I) complexes. In order to confer different solubility properties the metal complexes stabilize Cu Ag in their +1 oxidation state, lipophilic triphenylphosphine (PPh3) hydrophilic 1,3,5-triaza-7-phosphaadamantane (PTA) selected co-ligands syntheses Cu(I) Ag(I) All compounds characterized by CHN analysis, NMR, FT-IR spectroscopy, electrospray ionization mass spectrometry (ESI-MS); molecular structure copper(II) complex [Cu(LBSPh)2] was also determined single-crystal X-ray diffraction. Finally, antibacterial activity complexes, Schiff base phosphane co-ligands, assessed determining minimum inhibitory concentration (MIC) bactericidal (MBC) against Gram-negative (Escherichia coli) Gram-positive bacteria (Staphylococcus aureus).

Язык: Английский

Cu(II) complexes with unsymmetrical N3O-type Schiff base ligands: Synthesis, crystal structures, in vitro antiproliferative studies against the human breast (MCF-7), colon (HCT-116) and lung (A549) cancer cell lines, and molecular docking studies DOI
Mahdi Behzad, Liana Ghasemi,

S. Bahareh Hossieni

и другие.

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114367 - 114367

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
New Cu(II), Cu(I) and Ag(I) Complexes of Phenoxy-Ketimine Schiff Base Ligands: Synthesis, Structures and Antibacterial Activity DOI Creative Commons

Miriam Caviglia,

Zhenzhen Li,

Carlo Santini

и другие.

Molecules, Год журнала: 2025, Номер 30(9), С. 1893 - 1893

Опубликована: Апрель 24, 2025

Two phenoxy-ketimines ligands, 2-(1-(benzylimino)ethyl)phenol (HLBSMe) and 2-((benzylimino)(phenyl)methyl)phenol (HLBSPh), were synthesized used as supporting ligands of new copper(II), copper(I), silver(I) complexes. In order to confer different solubility properties the metal complexes stabilize Cu Ag in their +1 oxidation state, lipophilic triphenylphosphine (PPh3) hydrophilic 1,3,5-triaza-7-phosphaadamantane (PTA) selected co-ligands syntheses Cu(I) Ag(I) All compounds characterized by CHN analysis, NMR, FT-IR spectroscopy, electrospray ionization mass spectrometry (ESI-MS); molecular structure copper(II) complex [Cu(LBSPh)2] was also determined single-crystal X-ray diffraction. Finally, antibacterial activity complexes, Schiff base phosphane co-ligands, assessed determining minimum inhibitory concentration (MIC) bactericidal (MBC) against Gram-negative (Escherichia coli) Gram-positive bacteria (Staphylococcus aureus).

Язык: Английский

Процитировано

0