Materials Today Communications, Год журнала: 2024, Номер unknown, С. 111333 - 111333
Опубликована: Дек. 1, 2024
Язык: Английский
Materials Today Communications, Год журнала: 2024, Номер unknown, С. 111333 - 111333
Опубликована: Дек. 1, 2024
Язык: Английский
Applied Physics A, Год журнала: 2024, Номер 130(8)
Опубликована: Июль 30, 2024
Язык: Английский
Процитировано
17Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 5, 2025
Abstract The interaction between the electrolyte and working electrode surface affects cascade of reactions involving Li deposition, N 2 , proton carriers consequently NH 3 production from Li‐mediated nitrogen reduction reaction (Li‐NRR). Efficient Li‐NRR at low concentrations is particularly challenging because current density uneven metal lithium nitride plating. Here, enhanced electrochemical for a concentration 0.5 m are demonstrated by employing 3D porous polymer fibers featuring + ‐affinity on Cu electrodes. Raman IR spectroscopic analyses exhibit that polymeric composed carboxyl hydroxyl groups can form Li‐binding complexes decrease interactions with solvents anions in electrolyte. support this structure serves to retain near electrode, expanding active area increasing density. Li‐affinitive effective even salt improve yield Faradaic efficiency. This study underscores importance morphology, affinity, its analytical methods understanding Li‐NRR.
Язык: Английский
Процитировано
2Electrochimica Acta, Год журнала: 2025, Номер unknown, С. 145842 - 145842
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
1Coordination Chemistry Reviews, Год журнала: 2025, Номер 530, С. 216472 - 216472
Опубликована: Фев. 3, 2025
Язык: Английский
Процитировано
0Arabian Journal for Science and Engineering, Год журнала: 2025, Номер unknown
Опубликована: Фев. 5, 2025
Язык: Английский
Процитировано
0Arabian Journal for Science and Engineering, Год журнала: 2025, Номер unknown
Опубликована: Март 6, 2025
Язык: Английский
Процитировано
0The Chemical Record, Год журнала: 2025, Номер unknown
Опубликована: Апрель 10, 2025
Abstract Green energy, including metal‐air batteries and fuel cells, is the key solution to climate change. The efficiency of these energy technologies depends on oxygen reduction reaction (ORR) at cathode, which a slow process requiring expensive noble metal catalysts, like platinum, for improvement. high cost this catalyst restricts its widespread use in producing cells. An alternative approach utilize non‐noble metals, such as transition rare earth are more cost‐effective demonstrate comparable durability effectiveness metals. With their affordability distinct electronic structure, metals have potential revolutionize industry. Transition can enhance ORR catalysts by manipulating surface molecular makeup through ′doping′ ′synergistic effects′. This article discusses roles various process, covering fundamental advanced levels, well progression from mono high‐entropy systems (systems with increasing complexity improved performance), bi‐, tri‐, tetra‐metallic comprehensive manner, emphasizes opportunities researchers propose innovative strategies optimizing process.
Язык: Английский
Процитировано
0Journal of Hazardous Materials, Год журнала: 2025, Номер 492, С. 138266 - 138266
Опубликована: Апрель 15, 2025
Язык: Английский
Процитировано
0Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(50)
Опубликована: Авг. 26, 2024
The lithium-mediated nitrogen reduction reaction (Li-NRR) offers a viable alternative to the Haber-Bosch process for ammonia production. However, ethanol, common proton carrier in Li-NRR, exhibits electrochemical instability, leading oxidation at anode or byproduct formation cathode. This study replaces alcoholic carriers with ionic liquids (ILs), specifically tetrabutylphosphonium chloride (TBPCl) and tetrabutylammonium (TBACl), examine how electronegativity differences between central atom adjacent carbon of cation affect catalytic performance. results show that switching tetraalkyl-type ILs markedly enhances performance, resulting 1.45-fold increase Faradaic efficiency (FE) transition from phosphonium ammonium ILs. Additionally, optimal IL concentrations electrolyte are identified maximize yield. TBACl, particular, demonstrates enhanced production operational stability, achieving an yield rate 13.60 nmol/cm
Язык: Английский
Процитировано
1Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2024, Номер 703, С. 135322 - 135322
Опубликована: Сен. 10, 2024
Язык: Английский
Процитировано
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