Solid–Solid Interface Design for Hydrogen Production by Direct Seawater Electrolysis: Progress and Challenges DOI Creative Commons

Bowei Zhou,

Tong Wu, Yilin Dong

и другие.

Inorganics, Год журнала: 2025, Номер 13(6), С. 183 - 183

Опубликована: Июнь 4, 2025

Using direct seawater electrolysis (DSE) for hydrogen production has garnered increasing scientific attention as a promising pathway toward sustainable energy solutions. Given the complex ionic environment of seawater, researchers have proposed diverse range strategies aimed at addressing issue enhancing corrosion resistance anodes, yet no optimal solution been found so far. Among emerging approaches, design using multilayer electrode architecture offers notable advantages by introducing abundant active sites, chemical environments, and robust physical structures. Crucially, these configurations enable synergistic integration distinct material properties across different layers, thereby both electrochemical activity structural stability in harsh environments. Despite benefits, limited understanding role played solid–solid interfaces hindered rational practical application such electrodes. This review focuses on principles functional roles anodes oxygen evolution reaction (OER) under DSE conditions. In addition, we systematically summarize discuss representative fabrication methods constructing hierarchically structured By screening recent advances techniques, further highlight how engineered influence interfacial bonding, electron transfer, mass transport during processes, intrinsic catalytic activity, well protecting metallic from corrosion. Finally, current challenges future research directions to deepen mechanistic interface phenomena are discussed, with aim accelerating development scalable electrodes electrolysis.

Язык: Английский

Comprehensive Chlorine Suppression: Advances in Materials and System Technologies for Direct Seawater Electrolysis DOI Creative Commons

Cenkai Zhao,

Zheyuan Ding,

Kunye Zhang

и другие.

Nano-Micro Letters, Год журнала: 2025, Номер 17(1)

Опубликована: Янв. 22, 2025

Abstract Seawater electrolysis offers a promising pathway to generate green hydrogen, which is crucial for the net-zero emission targets. Indirect seawater severely limited by high energy demands and system complexity, while direct bypasses pre-treatment, offering simpler more cost-effective solution. However, chlorine evolution reaction impurities in lead severe corrosion hinder electrolysis’s efficiency. Herein, we review recent advances rational design of chlorine-suppressive catalysts integrated systems architectures chloride-induced corrosion, with simultaneous enhancement Faradaic efficiency reduction cost. Furthermore, directions are proposed durable efficient systems. This provides perspectives toward sustainable conversion environmental protection.

Язык: Английский

Процитировано

3
Recent Advancement in Electrocatalytic Water Splitting Facilitated by the Sulfide Oxidation Reaction DOI
Lang Zhang,

Mingying Chen,

Lingfeng Xiao

и другие.

ACS Applied Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 27, 2025

Язык: Английский

Процитировано

0
Cell preservation strategies in direct seawater electrolysis based on cost-effective anion exchange membrane technology DOI Creative Commons
Sabrina Campagna Zignani,

Angela Salanitro,

M. P. De Pascale

и другие.

Electrochimica Acta, Год журнала: 2025, Номер unknown, С. 146406 - 146406

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Alkaline Seawater as an Electrolyte for Hydrogen Production: A Feasibility and Performance Study DOI
Nadia B. Ysea,

Melisa J. Gómez,

Teresita E. Humana

и другие.

Journal of Alloys and Compounds, Год журнала: 2025, Номер 1032, С. 181110 - 181110

Опубликована: Май 20, 2025

Язык: Английский

Процитировано

0
The Regulation Mechanism of Oxygen Vacancies in Ruddlesden–Popper Perovskite Ln2NiO4 (Ln = La, Pr, Nd) Air Electrode for Reversible Protonic Solid Oxide Cells DOI
Kai Kang,

Xu Liu,

Chao Wang

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Май 28, 2025

Abstract Reversible protonic solid oxide cells (R‐PSOCs) are promising green energy storage devices for efficient hydrogen/electricity conversion. Due to the complex environment of air electrode, microscopic influence mechanism oxygen vacancies in perovskites on reduction reaction (ORR) and evolution (OER) is unclear. In this study, layered Ruddlesden–Popper perovskite Ln 2 NiO 4 (Ln = La, Pr, Nd) electrodes constructed investigate effect water/oxygen coupling dual mode. The Pr 4+δ full cell exhibits highest peak power density 0.692 W cm −2 fuel mode a maximum current −1.2 A electrolysis at 700 °C. changes electrochemical impedance spectroscopy show that can absorb small amount interfacial water SOFC promote triple‐conductivity. Meanwhile, it have good electrolytic performance an atmosphere 10% H O SOEC enriched Pr₂NiO provide broad platform both ORR OER, while appropriate hydrophilicity achieve better balance state by competitive adsorption water/oxygen. These comprehensive characteristics make suitable be potential electrode material RSOCs.

Язык: Английский

Процитировано

0
Solid–Solid Interface Design for Hydrogen Production by Direct Seawater Electrolysis: Progress and Challenges DOI Creative Commons

Bowei Zhou,

Tong Wu, Yilin Dong

и другие.

Inorganics, Год журнала: 2025, Номер 13(6), С. 183 - 183

Опубликована: Июнь 4, 2025

Using direct seawater electrolysis (DSE) for hydrogen production has garnered increasing scientific attention as a promising pathway toward sustainable energy solutions. Given the complex ionic environment of seawater, researchers have proposed diverse range strategies aimed at addressing issue enhancing corrosion resistance anodes, yet no optimal solution been found so far. Among emerging approaches, design using multilayer electrode architecture offers notable advantages by introducing abundant active sites, chemical environments, and robust physical structures. Crucially, these configurations enable synergistic integration distinct material properties across different layers, thereby both electrochemical activity structural stability in harsh environments. Despite benefits, limited understanding role played solid–solid interfaces hindered rational practical application such electrodes. This review focuses on principles functional roles anodes oxygen evolution reaction (OER) under DSE conditions. In addition, we systematically summarize discuss representative fabrication methods constructing hierarchically structured By screening recent advances techniques, further highlight how engineered influence interfacial bonding, electron transfer, mass transport during processes, intrinsic catalytic activity, well protecting metallic from corrosion. Finally, current challenges future research directions to deepen mechanistic interface phenomena are discussed, with aim accelerating development scalable electrodes electrolysis.

Язык: Английский

Процитировано

0