Dispositivo coletor-detector fabricado aditivamente para análise de explosivos utilizando filamento de PLA reciclado carregado com carbon black e/ou grafite DOI Creative Commons
Maria Souza

Опубликована: Дек. 12, 2024

RESUMOO 2,4,6-trinitrotolueno (TNT) é um explosivo amplamente empregado em atividades militares devido seu baixo custo e baixa sensibilidade a impactos mecânicos.Muito utilizado também ataques terroristas eventos criminosos, seus resíduos subprodutos se tornam vestígios investigações forenses, sendo que alguns dos métodos utilizados por peritos para detecção de TNT são caros, trabalhosos não portáteis.Com isso, tem-se necessidade desenvolver sensíveis, baratos portáteis rápida do

Optimizing the Construction and Activation of 3D-Printed Electrochemical Sensors: An Experimental Design Approach for Simultaneous Electroanalysis of Paracetamol and Caffeine DOI Creative Commons
José Guilherme A. Rodrigues, Tárcila M. N. da Silva, S. Gomes

и другие.

ACS Omega, Год журнала: 2025, Номер 10(1), С. 1131 - 1143

Опубликована: Янв. 6, 2025

This work presents an optimization of the construction, treatment, and activation 3D-printed electrochemical sensors (E-3D). For this, was used a 23-full factorial design examining three key variables at two levels: electrode height, diameter, printing speed. Moreover, it evaluates various physical, chemical, methods to treat activate E-3D surface. The techniques impedance spectroscopy cyclic voltammetry (CV) shows that sequential treatments lead highest treatment efficiency activation. Raman atomic force microscopy characterize untreated treated sensor surfaces. optimal methodology applied electroanalysis paracetamol (PAR) caffeine (CAF) simultaneously using CV differential pulse anodic stripping (DPASV). DPASV measurements reveal limits detection 0.44 0.58 μmol L–1 in 0.5 mol H2SO4 medium for PAR CAF, respectively, with activated sensor. principal achievement this emphasizing critical role surface enhancing performance developed electrodes, thereby advancing technological applications sensors.

Язык: Английский

Процитировано

2

Exploring the Mechanical Durability and Electroanalytical Performance of 3d-Printed Multi-Material Sensors for Rapid On-Site Screening of Nimesulide in Industrial Sewage DOI
Mateusz Cieślik, Magdalena Rucka, Adrian Koterwa

и другие.

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Simultaneous determination of morphine and codeine using additive-manufactured electrodes with conductive filaments based on recycled PLA DOI
Carmen Andrade,

Mariana C. Marra,

Raquel G. Rocha

и другие.

Microchemical Journal, Год журнала: 2025, Номер unknown, С. 113830 - 113830

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Sustainable Validated Methodology for Enzymeless Determination of Tyrosine USING 3D-printed PLA/CB Electrodes in Synthetic Urine DOI Creative Commons
Amanda Morais, Diego P. Rocha, Maria Lurdes Felsner

и другие.

Talanta Open, Год журнала: 2025, Номер 11, С. 100469 - 100469

Опубликована: Май 6, 2025

Язык: Английский

Процитировано

0

Sustainable 3D-printing from coconut waste: conductive PLA-biochar filaments for environmental electrochemical sensing DOI
Raquel G. Rocha, Mariana Marra,

Isabella C. O. F. Silva

и другие.

Microchimica Acta, Год журнала: 2025, Номер 192(6)

Опубликована: Май 9, 2025

Язык: Английский

Процитировано

0

Lab-on-a-Scalpel: Medical Tool Incorporating a Disposable Fully 3D-Printed Electrochemical Cell Promoting Drop-Volume Chemical Analysis in the Operating Theater DOI Creative Commons
Anastasios V. Papavasileiou, Lukáš Děkanovský, Zdeněk Sofer

и другие.

Analytical Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 12, 2025

Surgical operations are intricate and invasive procedures that require continuous monitoring of the patient's biochemical profile. Point-of-care testing would allow healthcare professionals to identify abnormalities make necessary interventions minimize risk complications ensure patient safety. To this end, we report development a disposable compact fully 3D-printed electrochemical cell incorporated into medical scalpel (Lab-on-a-Scalpel), aiming promote on-site (electro)chemical analysis in operating theater. This multifunctional device minimizes number instruments needed during surgery can be fabricated on-demand by using desktop-sized 3D printer at very low cost. The performance Lab-on-a-Scalpel sensing was evaluated over various techniques (cyclic voltammetry, amperometry, differential pulse voltammetry) different setups (stirring, drop-volume analysis, polarization potentials, etc.) for determination epinephrine. Results showed attractive analytical figures-of-merit, with limit detection (LOD) reaching 0.13 μM, high accuracy recovery studies conducted on artificial blood samples. Our findings suggest is valuable tool enables near-patient diagnostics minimum sample volume holds promise become an essential robotic-assisted surgery.

Язык: Английский

Процитировано

0

Microcrystalline Cellulose-Infused Additive Manufactured Filaments: A Sustainable Path to Enhancing Electrochemical Sensors DOI Creative Commons
Bruno Ferreira, Elena Bernalte, Robert D. Crapnell

и другие.

ACS Applied Engineering Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 4, 2025

Язык: Английский

Процитировано

0

3D-Printed Dual-Channel Flow-Through Miniaturized Devices with Dual In-Channel Electrochemical Detection DOI Creative Commons
Miriam Chávez, Alberto Escarpa

Analytical Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 24, 2024

Here, we present three-dimensional-printed dual-channel flow-through miniaturized devices (3Dd) with dual electrochemical detection (EDd) integrating two working electrodes each in an in-channel configuration (3Dd-EDd). Prussian Blue (PB) shell-gold nanoparticles ((PB)AuNP) core-based electrochemistry was chosen for selective hydrogen peroxide determination. 3Dd-EDd exhibited impress stability, identical intrachannel and interchannel performances, excellent interdevice precision values under 9%, revealing the reliability of design fabrication devices. enabled long-term reliable determination at physiological pH Caco-2 cells prooxidant stimulation demonstrating its outstanding electroanalytical performance. The results highlight analytical versatility trustworthiness 3D-printing-based scale advanced potential real-time cell monitoring.

Язык: Английский

Процитировано

1

Dispositivo coletor-detector fabricado aditivamente para análise de explosivos utilizando filamento de PLA reciclado carregado com carbon black e/ou grafite DOI Creative Commons
Maria Souza

Опубликована: Дек. 12, 2024

RESUMOO 2,4,6-trinitrotolueno (TNT) é um explosivo amplamente empregado em atividades militares devido seu baixo custo e baixa sensibilidade a impactos mecânicos.Muito utilizado também ataques terroristas eventos criminosos, seus resíduos subprodutos se tornam vestígios investigações forenses, sendo que alguns dos métodos utilizados por peritos para detecção de TNT são caros, trabalhosos não portáteis.Com isso, tem-se necessidade desenvolver sensíveis, baratos portáteis rápida do

Процитировано

0