Molecules,
Год журнала:
2024,
Номер
29(13), С. 3118 - 3118
Опубликована: Июнь 30, 2024
To
investigate
the
control
mechanisms
of
NOx
precursors
and
synergistic
effects
composite
catalysts
during
proline
pyrolysis,
a
systematic
series
experiments
was
conducted
utilizing
with
varying
Fe-Ca
ratios.
Product
distribution
analysis
employed
to
elucidate
catalysts’
in
reducing
precursor
emissions.
The
interactions
between
Fe
Ca
were
quantitatively
assessed
through
comparative
theoretical
experimental
release
calculations.
results
indicate
that
an
increase
content
catalyst
led
rise
amine
concentrations
from
0.9%
2.95%,
implying
facilitates
generation
amine-N
ring-opening
substitution
reactions.
When
ratio
balanced
at
1:1,
nitrogen
predominantly
participated
formation
purines
via
cyclization
Additionally,
all
exhibited
suppressive
effect
on
precursors,
attributed
their
significant
enhancement
solid
product
retention.
synergistically
inhibits
gaseous
nitrogen.
Notably,
strongest
observed
1:3
ratio,
which
reduced
NH3
by
38.7%
HCN
53.6%
pyrolysis.
This
study
offers
valuable
insights
into
optimization
nitrogen-rich
biomass
pyrolysis
processes.
Wiley Interdisciplinary Reviews Energy and Environment,
Год журнала:
2025,
Номер
14(2)
Опубликована: Апрель 14, 2025
ABSTRACT
The
rapidly
growing
population
is
continuously
putting
pressure
on
available
resources
and
production
processes,
raising
two
significant
global
challenges
viz.
energy
crisis
solid‐waste
management.
Both
issues
are
responsible
for
the
major
challenge
of
environmental
deterioration.
Different
categories
solid
waste,
especially
derived
from
agricultural
industrial
contribute
to
a
large
amount
waste
which
not
only
contaminating
environment,
but
its
improper
management
threat
flora
fauna,
including
human
civilization.
It
an
essential
goal
circular
economy
ensure
sustainable
development
by
designing
strategies
biomass
conversion
into
functional
carbon
materials,
component
modern
nanotechnology‐based
applications.
This
review
article
highlights
current
trends
in
different
synthetic
strategies.
application
biochar‐based
materials
high‐performance
supercapacitors,
rechargeable
lithium‐ion
batteries,
air
serves
as
catalyst
improve
sorption
kinetics
chemical
solid‐state
hydrogen
storage
ORR/OER/HER
electrocatalysts
several
Finally,
regarding
actualization
hierarchical
technology
mentioned.
These
should
be
addressed
researchers
well
policymakers
commercialize
biomass‐derived
material
Environmental Science & Technology,
Год журнала:
2024,
Номер
58(18), С. 7826 - 7837
Опубликована: Апрель 23, 2024
The
interaction
effects
between
the
main
components
(proteins
(P),
carbohydrates
(C),
and
lipids
(L))
of
protein-rich
biomass
during
microwave-assisted
pyrolysis
were
investigated
in
depth
with
an
exploration
individual
copyrolysis
(PC,
PL,
CL)
model
compounds.
average
heating
rate
P
was
higher
than
those
C
L,
interactions
all
groups
reduced
max
instant
rate.
synergistic
extent
(
Molecules,
Год журнала:
2024,
Номер
29(13), С. 3118 - 3118
Опубликована: Июнь 30, 2024
To
investigate
the
control
mechanisms
of
NOx
precursors
and
synergistic
effects
composite
catalysts
during
proline
pyrolysis,
a
systematic
series
experiments
was
conducted
utilizing
with
varying
Fe-Ca
ratios.
Product
distribution
analysis
employed
to
elucidate
catalysts’
in
reducing
precursor
emissions.
The
interactions
between
Fe
Ca
were
quantitatively
assessed
through
comparative
theoretical
experimental
release
calculations.
results
indicate
that
an
increase
content
catalyst
led
rise
amine
concentrations
from
0.9%
2.95%,
implying
facilitates
generation
amine-N
ring-opening
substitution
reactions.
When
ratio
balanced
at
1:1,
nitrogen
predominantly
participated
formation
purines
via
cyclization
Additionally,
all
exhibited
suppressive
effect
on
precursors,
attributed
their
significant
enhancement
solid
product
retention.
synergistically
inhibits
gaseous
nitrogen.
Notably,
strongest
observed
1:3
ratio,
which
reduced
NH3
by
38.7%
HCN
53.6%
pyrolysis.
This
study
offers
valuable
insights
into
optimization
nitrogen-rich
biomass
pyrolysis
processes.
