Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(11), С. 6376 - 6386
Опубликована: Янв. 1, 2024
Trace nicotinic acid (NA) can not only change the solvation structure of Zn 2+ , but also preferentially adsorbs on anode to reduce side reactions and inhibit dendrites. Zn‖Zn cells with NA operate for 5200 h at 1 mA cm −2 .
Язык: Английский
Advanced Energy Materials, Год журнала: 2024, Номер unknown
Опубликована: Март 4, 2024
Abstract Electrolytes play a crucial role in facilitating the ionic movement between cathode and anode, which is essential for flow of electric current during charging discharging process rechargeable batteries. In particular, electrolyte additives are considered as effective economical approaches into advancements battery technologies both conventional non‐aqueous burgeoning aqueous systems. Herein, systematic comprehensive review reported interfacial engineering Li Zn metal anodes electrolytes, respectively. The types their corresponding functionalities protection these two discussed along with electrochemical features solid interphase (SEI) derived from additives. recent progress on systems also addressed perspectives electrode, electrolyte, associated SEI. Finally, outlook perspective issues future directions field additive presented next‐generation beyond Li‐ion
Язык: Английский
Процитировано
22
Energy storage materials, Год журнала: 2024, Номер 70, С. 103516 - 103516
Опубликована: Май 24, 2024
Язык: Английский
Процитировано
19
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(14)
Опубликована: Фев. 2, 2024
Abstract The design of aqueous zinc (Zn) chemistry energy storage with high rate‐capability and long serving life is a great challenge due to its inhospitable coordination environment dismal interfacial chemistry. To bridge this big gap, herein, we build highly reversible Zn battery by taking advantages the biomass‐derived cellulose nanocrystals (CNCs) electrolyte additive unique physical chemical characteristics simultaneously. CNCs not only serves as fast ion carriers for enhancing 2+ transport kinetics but regulates interface form dynamic self‐repairing protective interphase, resulting in building ultra‐stable anodes under extreme conditions. As result, engineered system achieves superior average coulombic efficiency 97.27 % 140 mA cm −2 , steady charge–discharge 982 h 50 mAh which proposes universal pathway green, sustainable, large‐scale applications.
Язык: Английский
Процитировано
18
Advanced Functional Materials, Год журнала: 2024, Номер 34(34)
Опубликована: Апрель 10, 2024
Abstract Aqueous zinc‐ion batteries (AZIBs) exhibit significant potential for grid energy storage due to their low cost and safety. However, the commercial applications of AZIBs face challenges, particularly in anode, such as zinc dendrites, hydrogen evolution reaction (HER), corrosion. In this study, a protonated triglycine (ggg) multifunctional electrolyte additive is employed. This ggg molecule can dissociate zwitterion (both anion cation) mildly acidic ZnSO 4 electrolytes. The NH 3 + cation adsorb on surface regulating deposition Zn 2+ slowing down side reactions, spontaneously dissociated anions will combine with regulate solvated chemistry electrolyte, establishing electrostatic interaction via strong adsorption ability . Theoretical calculations indicate that demonstrates affinity toward , enabling reconstruction Zn(H 2 O) 6 facilitating subsequent de‐solvation processes. As result, Zn||Zn symmetric cells /0.2 mM exhibited an extended cycling lifetime ≈4500 h. Furthermore, Zn||MnO full battery demonstrated enhanced capacity performance addition molecule. study provides valuable insights into constructing highly reversible AZIBs.
Язык: Английский
Процитировано
17
Advanced Functional Materials, Год журнала: 2024, Номер 34(29)
Опубликована: Фев. 20, 2024
Abstract Rechargeable Zn‐based batteries provide a compelling supplement to subsistent energy storage devices owing their high density, good safety, and low cost. Nevertheless, inherent imperfections such as dendrite growth, side reactions, andante reaction kinetics, severely impede commercialization. As new 0D nanomaterials, carbon dots (CDs) with unique characteristics excellent electrochemical activity, exhibit promising potential exploitation in electrochemistry electrocatalysis areas. Herein, the adhibition of CDs resolving aforementioned drawbacks is introduced. To begin with, concepts, physicochemical properties, synthetic methods are discussed. Next, recent developments advances exploiting respectively ameliorating performance Zn anode, cathode, electrolytes ion bifunctional electrocatalytic activities including oxygen reduction evolution for Zn‐air batteries, roundly reviewed minutely generalized. Finally, current challenges prospects surveyed well, aiming offer reference blossom advanced batteries.
Язык: Английский
Процитировано
16
Advanced Functional Materials, Год журнала: 2024, Номер 34(34)
Опубликована: Март 6, 2024
Abstract By virtue of the intrinsic safety and cost‐effectiveness, aqueous Zn‐ion batteries (AZIBs) have gained increasing attention in realm energy storage. In spite promise Zn anode, challenges like dendrite growth side reactions persist as hurdles to be overcome. Addressing this, rational design anode current collectors (ZACCs) is an effective solution. Recent years witnessed significant strides construction ZACCs, yet precise pathways for ZACC development remain unclear, lacking a set specific criteria guide progress. this comprehensive review, acknowledging concerns surrounding anodes, six criteria—electrical conductivity, zincophilicity, orientational deposition inducibility, chemical stability, mechanical durability, scalability—are innovatively put forward pivotal benchmarks ZACCs. Each criterion accompanied by tailored optimization strategies corresponding challenges. Furthermore, future trend ZACCs envisaged, along with potential application scenarios AZIBs. This review will expedite advancement contribute flourishing landscape
Язык: Английский
Процитировано
16
Energy storage materials, Год журнала: 2024, Номер 70, С. 103449 - 103449
Опубликована: Май 10, 2024
Язык: Английский
Процитировано
16
Energy storage materials, Год журнала: 2025, Номер unknown, С. 104026 - 104026
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
3
Advanced Functional Materials, Год журнала: 2023, Номер 34(13)
Опубликована: Дек. 15, 2023
Abstract Aqueous zinc (Zn) based batteries show great promise as energy storage devices, cost‐effectiveness, and intrinsic safety. However, the development of Zn‐based faces significant challenges, primarily stemming from poor electrochemical reversibility caused by dendrite growth, hydrogen generation, byproduct formation on Zn anode. In this study, valine (Val) is investigated an electrolyte additive to finely tune interface microenvironment, resulting in enhanced stability anode across a wide pH range, marking first time such approach has been explored. Val ions preferably adsorb onto active sites surface, enabling efficient isolation water SO 4 2− desolvated shell layer thus effectively inhibiting growth. The Zn||Zn symmetric cells are demonstrated with additives present remarkable cycling performance 5400 h. Furthermore, Zn||MnO 2 full exhibit stable operation for 5000 cycles at 3 A g −1 . Notably, also functions rechargeable alkaline cells, Zn||Ni 0.8 Co 0.1 Mn O operate durably temperature range. This work offers unique insights into engineering aqueous batteries, especially terms their compatibility
Язык: Английский
Процитировано
28
Energy storage materials, Год журнала: 2023, Номер 62, С. 102940 - 102940
Опубликована: Авг. 23, 2023
Язык: Английский
Процитировано
25