Steric Hindrance Manipulation in Polymer Electrolytes toward Wide-Temperature Solid-State Lithium Metal Batteries DOI
Jie Huang, Bin Qiu,

Feng Xu

и другие.

ACS Energy Letters, Год журнала: 2025, Номер unknown, С. 1921 - 1930

Опубликована: Март 27, 2025

Язык: Английский

Enhancing ionic conductivity and suppressing Li dendrite formation in lithium batteries using a vinylene-linked covalent organic framework solid polymer electrolyte DOI Creative Commons
Jin Yang, Chenxiao Lin, Yong‐Lei Wang

и другие.

Journal of Materials Chemistry A, Год журнала: 2023, Номер 12(3), С. 1694 - 1702

Опубликована: Дек. 5, 2023

A novel solid polymer electrolyte based on chemically stable vinylene-linked covalent organic framework was developed, demonstrating enhanced Li + conductivity and improved battery performance.

Язык: Английский

Процитировано

14

Fe-MIL-101 metal organic framework integrated solid polymer electrolytes for high-performance solid-state lithium metal batteries DOI
Ramesh Subramani, Su‐Yang Hsu, Yu‐Chun Chuang

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(12), С. 7132 - 7141

Опубликована: Янв. 1, 2024

This work reports Fe-MIL-101 MOF integrated SPE for improved LMBs. The presence of Fe 3+ metal centers enhances Li + transfer and boosts the electrochemical properties SPE, enabling stable cycling at room temperature in solid-state

Язык: Английский

Процитировано

6

Robust and Adhesive Laminar Solid Electrolyte with Homogenous and Fast Li‐Ion Conduction for High‐Performance All‐Solid‐State Lithium Metal Battery DOI Creative Commons
Shiyuan Guo,

Yuefeng Su,

Kang Yan

и другие.

Advanced Science, Год журнала: 2024, Номер 11(30)

Опубликована: Июнь 14, 2024

Constructing composite solid electrolytes (CSEs) integrating the merits of inorganic and organic components is a promising approach to developing high-performance all-solid-state lithium metal batteries (ASSLMBs). CSEs are now capable achieving homogeneous fast Li-ion flux, but how escape trade-off between mechanical modulus adhesion still challenge. Herein, strategy address this issue proposed, that is, intercalating highly conductive, homogeneous, viscous-fluid ionic conductors into robust coordination laminar framework construct electrolyte with conduction (LSE-HFC). A 9 µm-thick LSH-HFC, in which poly(ethylene oxide)/succinonitrile adsorbed by metal-organic nanosheets as building blocks, used here an example determine validity. The transfer mechanism verified works across entire LSE-HFC, facilitates flux low migration energy barriers, endowing LSE-HFC high conductivity 5.62 × 10

Язык: Английский

Процитировано

6

Integration of a composite polymer electrolyte and Se/C cathodes toward high-performance all-solid-state Li–Se batteries DOI Creative Commons
Tae Hwa Hong,

Jea Duk Kim,

Jung‐Seok Lee

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(4), С. 1998 - 2003

Опубликована: Янв. 1, 2024

The coupling of composite polymer electrolytes with Se/C cathodes was achieved in this study to address the needs modern solid-state batteries, including high-energy density, low temperature operation, cycle stability, and ease manufacture.

Язык: Английский

Процитировано

5

Engineering Ion Conduction Nanodomain Spacing and Interface Environment for Ultrastable All‐Solid‐State Lithium Metal Batteries DOI
Sucheng Liu, Mingdong Liu, Li Du

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер 34(33)

Опубликована: Апрель 21, 2024

Abstract Block copolymer electrolytes are of great interest due to the combination merits ion conduction and mechanical strength. However, there lacks a comprehensive understanding on role nanodomain spacing in ion‐dipole coordinating environment interface environment. Herein, lithium salts with varied binding energy chosen tune Polyether‐block‐Polyamide (PEO‐PA) polymer. Spectra characterizations molecular dynamic simulations systematically demonstrate adding LiFSI lower contributes forming larger PEO clarifies relationship between as well The doping PEO‐PA (AEOF) creates loosely Li + ‐EO group improves pristine contact. In addition, formation solid‐electrolyte interphase rich LiF 3 N enhances interfacial stability. Therefore, ionic conductivity AEOF is significantly improved. Furthermore, Li||AEOF||Li cells exhibit extraordinary cycling life over 10000 h (416 days) at 0.1 mA cm −2 capacity mAh . This study provides new insight into environment, which benefits theory‐guided design all‐solid‐state polymer electrolytes.

Язык: Английский

Процитировано

5

Ferroelectric BiFeO3 modified PVDF-based electrolytes for high-performance lithium metal batteries DOI

Yanmei Wu,

Hong Zhang,

Yilin Xu

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(31), С. 20403 - 20413

Опубликована: Янв. 1, 2024

PVDF-based electrolytes are promising candidates for solid-state lithium batteries (SSLBs) due to their high safety, interface compatibility and electrochemical stability.

Язык: Английский

Процитировано

5

Enhancing Li+ transport efficiency in solid-state Li-ion batteries with a ceramic-array-based composite electrolyte DOI

Shu-Ming Yeh,

Chia‐Chen Li

Journal of Materials Chemistry A, Год журнала: 2023, Номер 11(44), С. 24390 - 24402

Опубликована: Янв. 1, 2023

An innovative composite solid electrolyte (CSE) enhances Li + transport efficiency by integrating an array of ceramic pillars into a polymer matrix, as compared to conventional CSEs with dispersed particles.

Язык: Английский

Процитировано

11

Tailoring the interface of lithium metal batteries with in situ formed gel polymer electrolyte DOI

Si‐Xin Jia,

Jinxin Xue,

Hong Huo

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(25), С. 15430 - 15439

Опубликована: Янв. 1, 2024

In situ formed gel polymer electrolyte with wide electrochemial stability window is obtained an amide group covalently cross-linked matrix. It can stabilize lithium metal anode and inhibit liquid decomposition on the cathode.

Язык: Английский

Процитировано

4

Perspective on Recent Advances of Functional Electrolytes for Lithium Metal Batteries DOI

Lishun Bai,

Benqiang Chen,

Danni Zhang

и другие.

Energy & Fuels, Год журнала: 2024, Номер 38(12), С. 10634 - 10652

Опубликована: Июнь 10, 2024

Lithium metal batteries (LMBs) have attracted extensive research interest because of their unparalleled electrochemical performances. Electrolytes, a critical component batteries, play pivotal role in promoting ionic and charge transport forming solid–electrolyte interphase (SEI). The solvation chemistry electrolytes is closely related to the performance LMBs can be effectively manipulated by adjusting components structures. However, with undesirable properties lead fast capacity decay even pose severe safety hazards LMBs. Therefore, development high-performance for advancement Typical electrolyte strategies include high-concentration (HCEs) localized (LHCEs). In this review, we primarily focus on recent advancements functional design strategies. We provide brief overview characteristics commonalities different formulations. Additionally, prepared basis novel solvents are also summarized, which key method achieving high Finally, inspiring methods further optimize compositions structures practical proposed.

Язык: Английский

Процитировано

4

A functional silicon composite polymer electrolyte with hydrofluoric acid scavenging for quasi-solid-state lithium metal batteries DOI
Zhao Li,

Li Yang,

Yu Cheng

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(31), С. 20337 - 20347

Опубликована: Янв. 1, 2024

A functional composite polymer electrolyte (FCPE) containing Si nanoparticles can prevent the growth of lithium dendrites in quasi-solid-state batteries by reacting with HF and H 2 O to form a protective LiF-rich layer on metal surface.

Язык: Английский

Процитировано

4