Chemical Engineering Journal, Год журнала: 2025, Номер 505, С. 159323 - 159323
Опубликована: Янв. 6, 2025
Язык: Английский
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 23, 2025
Abstract Rechargeable aqueous zinc‐ion batteries (ZIBs) are expected to be the next generation of low‐cost, safe, and high‐energy‐density energy storage systems. However, undesirable electrode/electrolyte interfacial (EEI) side reactions anode dissolution cathode materials during cycling ZIBs have led drastic degradation battery performance. Here, a phosphated electrolyte is developed facilitate simultaneous formation Zn 3 (PO 4 ) 2 ‐rich solid interphase (SEI) cathode/electrolyte interface (CEI) as well improved solvent chemistry. The in situ generated robust EEI induce uniform deposition zinc inhibit solvation material achieve high performance ZIBs. chemistry promises stable at low temperatures with an ultra‐long life 600 h −10 °C. Moreover, pouch cell exhibits excellent no significant capacity after 150 cycles. In addition, anode‐free performances long lifetime 200 This study provides simple effective strategy for construction
Язык: Английский
Процитировано
6
Energy Materials, Год журнала: 2025, Номер 5(2)
Опубликована: Янв. 13, 2025
Aqueous zinc-based batteries (ZIBs), characterized by their low cost, inherent safety, and environmental sustainability, represent a promising alternative for energy storage solutions in sustainable systems. Significant advancements have been made developing high-performance cathode materials aqueous ZIBs, which exhibit enhanced lifespan density. However, challenges associated with zinc anodes, such as dendrite formation side reactions, impede the practical application of ZIBs. This manuscript discusses role electrolyte additives Zn electrodeposition process comprehensively describes strategies to enhance anode stability through additive incorporation. It specifically focuses on underlying mechanisms that regulate solvation structure electrical double layer. Finally, concludes future perspectives advancing technology, aiming provide guidelines more robust Zn-based
Язык: Английский
Процитировано
4
Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(13), С. 7799 - 7806
Опубликована: Янв. 1, 2024
Herein, a functional vinylene-linked COF with zincophilic fluorinated sites is well designed and applied as an interface layer to simultaneously manipulate the Zn plating/stripping behavior interfacial side reactions.
Язык: Английский
Процитировано
17
Energy & Environmental Science, Год журнала: 2024, Номер 17(13), С. 4794 - 4802
Опубликована: Янв. 1, 2024
The high-valence metal cation Ce 4+ is used to compress the electric double layer on Zn electrode surface, which improves 2+ deposition overpotential and reduces corrosion rate.
Язык: Английский
Процитировано
17
Energy & Environmental Science, Год журнала: 2024, Номер 17(13), С. 4758 - 4769
Опубликована: Янв. 1, 2024
CB[6] not only forms complexes with SO 4 2− anions to enhance its solubility, but also adsorbs horizontally on the Zn surface form an H 2 O/SO shielding layer and induces epitaxial deposition of 2+ along (002) lattice plane.
Язык: Английский
Процитировано
13
Chemical Society Reviews, Год журнала: 2024, Номер 53(18), С. 8980 - 9028
Опубликована: Янв. 1, 2024
As one of the most promising electrochemical energy storage systems, aqueous batteries are attracting great interest due to their advantages high safety, sustainability, and low costs when compared with commercial lithium-ion batteries, showing promise for grid-scale storage. This invited tutorial review aims provide universal design principles address critical challenges at electrode-electrolyte interfaces faced by various multivalent battery systems. Specifically, deposition regulation, ion flux homogenization, solvation chemistry modulation proposed as key tune inter-component interactions in corresponding interfacial strategies underlying working mechanisms illustrated. In end, we present a analysis on remaining obstacles necessitated overcome use under different practical conditions future prospects towards further advancement sustainable systems long durability.
Язык: Английский
Процитировано
13
Advanced Materials, Год журнала: 2024, Номер unknown
Опубликована: Сен. 2, 2024
Abstract Large‐scale application of low‐cost, high‐safety and environment‐compatible aqueous Zn metal batteries (ZMBs) is hindered by dendrite failure side reactions. Herein, highly reversible ZMBs are obtained addition trace D‐pantothenate calcium additives to engineer a dual‐functional interfacial layer, which enabled bioinspired gating effect for excluding competitive free water near surface due the trapping immobilization hydroxyl groups, guiding target 2+ transport across interface through carboxyl groups pantothenate anions, as well dynamic electrostatic shielding around protuberances from Ca cations ensure uniform deposition. In consequence, reactions perfectly inhibited owing reduced molecules reaching surface, compact deposition achieved promoted kinetics. The ultra‐stable symmetric cells with beyond 9000 h at 0.5 mA cm −2 mAh over 5000 5 1 , an average Coulombic efficiency 99.8% amazingly realized. regulated‐electrolyte demonstrates high compatibility verified cathodes stable full cells. This work opens brand‐new pathway regulate Zn/electrolyte promise ZMBs.
Язык: Английский
Процитировано
12
Energy & Environmental Science, Год журнала: 2024, Номер 17(19), С. 7281 - 7293
Опубликована: Янв. 1, 2024
Ultrastable (>3500 h) electrolyte at high current density by high-entropy solvation for AZIBs. With increasing configuration entropy, O–H bond order in active H 2 O and ionic conductivity are increased, realizing highly reversible Zn anode.
Язык: Английский
Процитировано
11
Energy storage materials, Год журнала: 2024, Номер 68, С. 103361 - 103361
Опубликована: Март 21, 2024
Язык: Английский
Процитировано
10
Materials Today Chemistry, Год журнала: 2024, Номер 38, С. 102059 - 102059
Опубликована: Апрель 21, 2024
Язык: Английский
Процитировано
10