Review of Ionic Conductivity Properties of NASICON Type Inorganic Solid Electrolyte LATP

ACS Applied Electronic Materials, Год журнала: 2024, Номер 6(2), С. 641 - 657

Опубликована: Фев. 14, 2024

Solid lithium metal batteries (SLMBs) are an emerging field of advanced battery technology, with immense implications for various sectors. One the key components SLMBs is solid electrolyte, which acts as both separator and ionic conductor between electrodes. Among types electrolytes, NASICON LATP has received considerable attention due to its high mechanical robustness, safety, environmental stability, low cost, wide electrochemical window. These attributes enable improve performance safety SLMBs, create opportunities fabrication high-performance stimulate extensive research efforts. This review provides a contrast typical electrolytes synthesis methods LATP, well recent advances affecting their conductivity properties. It also highlights challenges facing suggests future directions enhancing SLMB technology. To achieve further progress in it essential precisely control crystal structure, electrolyte pellet secondary phase order optimize ion transport efficiency increase stability facilitate development SLMBs.

Язык: Английский

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Matching strategy between sulfide solid electrolyte and various anodes: electrolyte modification, interface engineering and electrode structure design

Energy storage materials, Год журнала: 2024, Номер 69, С. 103422 - 103422

Опубликована: Апрель 21, 2024

Язык: Английский

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Recent Applications of Theoretical Calculations and Artificial Intelligence in Solid-State Electrolyte Research: A Review

Nanomaterials, Год журнала: 2025, Номер 15(3), С. 225 - 225

Опубликована: Янв. 30, 2025

Solid-state electrolytes (SSEs), as key materials for all-solid-state batteries (ASSBs), face challenges such low ionic conductivity and poor interfacial stability. With the rapid advancement of computational science artificial intelligence (AI) technologies, theoretical calculations AI methods are emerging efficient important virtual tools predicting screening high-performance SSEs. To further promote development SSEs, this review outlines recent applications in field. First, current calculation methods, density functional theory (DFT) molecular dynamics (MD), material structure optimization, electronic property analysis, transport introduced, along with an analysis their limitations. Second, innovative including machine learning (ML) deep (DL), properties, analyzing structural features, simulating behaviors elaborated. Subsequently, synergistic application strategies combining high-throughput (HTS), calculations, highlighted, demonstrating unique advantages integrating multiple methodologies discovery performance optimization. Finally, research progress is summarized, future trends forecasted. The integration expected to significantly accelerate SSE materials, thereby driving industrial ASSBs.

Язык: Английский

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Recent Progress and Prospects on Sodium-Ion Battery and All-Solid-State Sodium Battery: A Promising Choice of Future Batteries for Energy Storage

Energy & Fuels, Год журнала: 2024, Номер 38(11), С. 9280 - 9319

Опубликована: Май 13, 2024

At present, in response to the call of green and renewable energy industry, electrical storage systems have been vigorously developed supported. Electrochemical are mostly comprised batteries, which outstanding advantages such as high density conversion efficiency. Among them, secondary batteries like lithium sodium lead-acid received wide attention recent years. Lithium-ion (LIBs) existed for a long time. However, due limited resources worldwide, uneven distribution, worrying safety issues, development LIBs has gradually hindered. Meanwhile, sodium-ion (SIBs), whose working principle is similar that LIBs, emphasized by researchers abundant low cost. Moreover, all-solid-state (ASSBs), higher density, simpler structure, stability safety, also under rapid development. Thus, SIBs ASSBs both expected play important roles applications. This Review focuses mainly on detailed introduction constituent materials ASSBs, analyzing cathode anode solid-state electrolytes (SSEs) past five The direction each SSE suitable listed remarked, nonactive separators collectors briefly mentioned. Finally, reasonable assessment prospects different preparation methods put forward.

Язык: Английский

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In-situ curing poly(N,N'-Methylenebisacrylamide)-based composite electrolyte reinforced with high-strength glass fiber skeleton for solid state lithium ion batteries

Chemical Engineering Journal, Год журнала: 2024, Номер 487, С. 150474 - 150474

Опубликована: Март 16, 2024

Язык: Английский

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A novel LaCl₃-based oxychloride solid-state electrolyte enables fast Li-ion transport and is compatible with lithium metal

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(29), С. 18459 - 18468

Опубликована: Янв. 1, 2024

A novel LaCl 3 -based oxychloride with Zr 4+ and O 2− co-doping provides a smoother 1D channels for Li + within the framework; an optimized sample is compatible metal its critical current density (CCD) up to 7 mA cm −2 .

Язык: Английский

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Surface engineering of nickel-rich single-crystal layered oxide cathode enables high-capacity and long cycle-life sulfide all-solid-state batteries

Advanced Powder Materials, Год журнала: 2024, Номер 3(5), С. 100228 - 100228

Опубликована: Авг. 23, 2024

Язык: Английский

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LiTa₂PO₈-Based Polymer–Ceramic Electrolyte Paved the Way to High-Performance Solid-State Lithium Metal Batteries

Energy & Fuels, Год журнала: 2024, Номер 38(12), С. 11253 - 11261

Опубликована: Июнь 7, 2024

Solid composite electrolytes, leveraging the advantages of both ceramics and polymers, are emerging as a viable alternative to liquid electrolytes in all-solid-state lithium metal batteries. Here, we have developed polymer–ceramic electrolyte with an area-specific resistance ∼94 Ω cm2 at room temperature (RT) by solution casting method. A Li-ion conducting LiTa2PO8 ceramic RT bulk conductivity ∼3.2 × 10–4 S cm–1 was synthesized act active filler PEO/PVDF-HFP polymer matrix complexed LiTFSI salt obtain electrolyte. The symmetric cell optimized exhibited excellent cyclability over 950 cycles areal current density 0.2 mA cm–2. full LiFePO4 cathode anode delivered specific capacity ∼115 mAh g–1 ∼85% retention after 500 1C RT, making it be adopted batteries for applications.

Язык: Английский

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Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives

Advanced Functional Materials, Год журнала: 2024, Номер 35(1)

Опубликована: Окт. 31, 2024

Abstract The use of all‐solid‐state lithium metal batteries (ASSLMBs) has garnered significant attention as a promising solution for advanced energy storage systems. By employing non‐flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the anode allows higher density compared to traditional lithium‐ion batteries. To fully realize potential solid‐state (SSEs) must meet several requirements. These include high ionic conductivity Li + transference number, smooth interfacial contact between SSEs electrodes, low manufacturing cost, excellent electrochemical stability, effective suppression dendrite formation. This paper delves into essential requirements enable successful implementation ASSLMBs. Additionally, representative state‐of‐the‐art examples developed past 5 years, showcasing latest advancements SSE materials highlighting unique properties are discussed. Finally, provides an outlook on achieving balanced improved addressing failure mechanisms solutions, critical challenges such reversibility plating/stripping thermal runaway, characterization techniques, composite SSEs, computational studies, ASS lithium–sulfur lithium–oxygen With this consideration, ASSLMBs can be realized.

Язык: Английский

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Solid-State Batteries: Materials, Technologies, and Future

Опубликована: Янв. 1, 2025

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