Recent Progress and Prospects on Sodium-Ion Battery and All-Solid-State Sodium Battery: A Promising Choice of Future Batteries for Energy Storage

Energy & Fuels, Год журнала: 2024, Номер 38(11), С. 9280 - 9319

Опубликована: Май 13, 2024

At present, in response to the call of green and renewable energy industry, electrical storage systems have been vigorously developed supported. Electrochemical are mostly comprised batteries, which outstanding advantages such as high density conversion efficiency. Among them, secondary batteries like lithium sodium lead-acid received wide attention recent years. Lithium-ion (LIBs) existed for a long time. However, due limited resources worldwide, uneven distribution, worrying safety issues, development LIBs has gradually hindered. Meanwhile, sodium-ion (SIBs), whose working principle is similar that LIBs, emphasized by researchers abundant low cost. Moreover, all-solid-state (ASSBs), higher density, simpler structure, stability safety, also under rapid development. Thus, SIBs ASSBs both expected play important roles applications. This Review focuses mainly on detailed introduction constituent materials ASSBs, analyzing cathode anode solid-state electrolytes (SSEs) past five The direction each SSE suitable listed remarked, nonactive separators collectors briefly mentioned. Finally, reasonable assessment prospects different preparation methods put forward.

Язык: Английский

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Quasi-Solid Gel Electrolytes for Alkali Metal Battery Applications

Nano-Micro Letters, Год журнала: 2025, Номер 17(1)

Опубликована: Март 19, 2025

Abstract Alkali metal batteries (AMBs) have undergone substantial development in portable devices due to their high energy density and durable cycle performance. However, with the rising demand for smart wearable electronic devices, a growing focus on safety durability becomes increasingly apparent. An effective strategy address these increased requirements involves employing quasi-solid gel electrolytes (QSGEs). This review focuses application of QSGEs AMBs, emphasizing four types influence battery performance stability. First, self-healing gels are discussed prolong life enhance through self-repair mechanisms. Then, flexible explored mechanical flexibility, making them suitable electronics. In addition, biomimetic inspired by natural designs introduced high-performance AMBs. Furthermore, biomass materials presented, derived from biomaterials, offering environmental friendliness biocompatibility. Finally, perspectives challenges future developments terms enhancing ionic conductivity, strength, stability novel materials. The underscores significant contributions AMBs performance, including lifespan, safety, adaptability, providing new insights directions research applications field.

Язык: Английский

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Effects of Sodium Sources on Nonaqueous Precipitation Synthesis of β″-Al₂O₃ and Formation Mechanism of Uniform Ionic Channels

Langmuir, Год журнала: 2025, Номер unknown

Опубликована: Янв. 16, 2025

High-temperature and long-term sintering of β″-Al2O3 solid electrolyte (Beta″ Alumina Solid Electrolyte, BASE) can easily cause Na2O volatilization. It reduces the (SE) quality, resulting in low ion conductivity electrolyte. is also difficult to form uniform ionic channels. This work designs a simple nonaqueous precipitation through de-etherification heterogeneous polymerization reaction between optimal sodium source ethoxide aluminum isopropoxide synthesize highly active precursor powders with Na-O-Al as skeleton, effectively reducing synthesis temperatures minimizing Importantly, residual organic groups temperature 1150 °C promote formation situ carbon uniformly. In-situ mass fraction about 3.98% will uniformly distributed transport channels diameter 1-3 μm when at 1580 °C. These ensure migration rate ions 0.028 S/cm 300

Язык: Английский

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Ultrafast UV Curing Enabling A Stable Interphase and Interface for Solid-State Sodium–Metal Batteries

ACS Energy Letters, Год журнала: 2024, Номер unknown, С. 195 - 204

Опубликована: Дек. 16, 2024

Designing advanced solid-state sodium batteries (SSBs) demands simultaneously overcoming the low ionic conductivity of electrolytes (SSEs) and poor interfacial compatibility between electrodes SSEs. Herein, a composite electrolyte (CSE) with high was prepared by using an efficient UV polymerization in 45 s. A stable interphase interface were achieved through solvent structure tuning situ curing. By introduction fluoroethylene carbonate (FEC) to form competitive solvation CSE-F, lowest unoccupied molecular orbital (LUMO) allowed preferential reduction FEC shell. dense uniform NaF-rich constructed inhibit growth dendrites. Simultaneously, integrated cathode tight-contact interface, enabling ion transport. The Na||CSE-F@Na3V2(PO4)3 (NVP) cell showed capacity retention 91.78% after 2100 cycles. This work provides solution achieve rational electrode/electrolyte design for SSBs.

Язык: Английский

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Composite Polymer Solid Electrolytes for All‐Solid‐State Sodium Batteries

Small Methods, Год журнала: 2025, Номер unknown

Опубликована: Фев. 5, 2025

Abstract Sodium‐ion batteries (SIBs) are emerging as a promising alternative to lithium‐ion batteries, primarily due their plentiful raw materials and cost‐effectiveness. However, the use of traditional organic liquid electrolytes in sodium battery applications presents significant safety risks, prompting investigation solid more viable solution. Despite advantages, single encounter challenges, including low conductivity ions at room temperature incompatibility with electrode materials. To overcome these limitations, researchers develop composite polymer (CPSEs), which merge strengths high ionic inorganic flexibility electrolytes. CPSEs usually composed dispersed matrix. The final performance can be further improved by optimizing particle size, relative content, form fillers. show great advantages improving interface compatibility, making them an important direction for future solid‐state research. Therefore, this paper summarizes recent advancements electrolytes, discusses impact preparation processes on performance, outlines potential developments sodium‐ion batteries.

Язык: Английский

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Advances in Developing Inorganic Calcium Solid-State Electrolytes: A Minireview

Energy & Fuels, Год журнала: 2025, Номер unknown

Опубликована: Март 16, 2025

Язык: Английский

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Impact of Composite Cathode Architecture Engineering on the Performance of All-Solid-State Sodium Batteries

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Май 14, 2025

The electrode/electrolyte interfacial contact, ionic percolation pathways, and charge transfer resistance within the cathode significantly impact performance lifespan of all-solid-state sodium batteries (AS3Bs). Addressing these issues requires optimization composite architecture interface in AS3Bs. One major challenge developing cathodes with oxide solid electrolytes is selecting appropriate thermal processing temperature to ensure intimate contact between active material electrolyte while ensuring a sufficient pathway inside cathode. In this study, we present an approach for fabricating by cofiring vanadium fluorophosphate (Na3V2(PO4)2F3, NVPF) superionic conductor (Na3Zr2Si2PO12, NZSP) at 700 °C using optimized weight ratio. This method ensures reduced NVPF NZSP establishing efficient pathway. To further enhance cathode, residual voids are filled polymer composed PEO/NaClO4. Benefits dense structure, stable NVPF/NZSP interface, negligible pores three-dimensional electronic network facilitate greater utilization almost no capacity degradation upon long-term cycling. full cell, delivers initial discharge 114 mA h g-1 0.1 C, retaining 85% its after 500 cycles 99% Coulombic efficiency excellent rate capability 1 C.

Язык: Английский

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Interface Engineering Strategies for Realizing Anode‐Free Sodium Batteries: A Review

Advanced Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 1, 2025

Abstract Sodium‐ion batteries (NIBs) emerge as promising alternatives to lithium‐ion due sodium's abundance, low cost, and sustainability. However, NIBs face challenges such lower energy density, electrode material compatibility, long‐term stability. Anode‐free sodium (AFNBs) address these limitations by eliminating the pretreatment anode, using a current collector for plating stripping, thus increasing density simplifying manufacturing. Several types of AFNBs, including anode‐free Na‐metal, Na‐solid‐state, Na‐air/CO 2 batteries, are under development, each targeting specific electrochemical challenges. Na‐metal offer high but suffer from dendrite formation unstable solid‐electrolyte interphase (SEI). Na‐solid‐state enhance safety issues with interfacial resistance limited ionic conductivity. promise exceptional densities still in early stages, struggle Na lose stability concerns. Interface engineering plays crucial role overcoming challenges, particularly controlling deposition, stabilizing SEI, minimizing side reactions. Research focuses on optimizing interface through surface modifications, electrolyte composition, protective coatings suppress cycling This review highlights latest advancements explores future directions aiming develop high‐energy‐density, durable, safe sodium‐based storage systems.

Язык: Английский

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Rapid Na+ Transport Pathway and Stable Interface Design Enabling Ultralong Life Solid‐State Sodium Metal Batteries

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Дек. 30, 2024

Abstract Sodium‐metal batteries (SMBs) using solid‐state polymer electrolytes (SPEs) show impressive superiority in energy density and safety. As promising candidates for SPEs, plastic crystal (SPCE) based on succinonitrile (SN) could achieve high ion conductivity wide voltage window. Nonetheless, the notorious SN decomposition reaction electrode/electrolyte interface seriously challenges stable operation of battery. To address this drawback, we commence with structural engineering chain segments SPCE employ intermolecular interactions to optimize composition solid electrolyte (SEI). Moreover, study emphasizes importance network design optimizing migration behavior sodium ions SPCE. The assembled symmetric cells display a critical current up 2.7 mA cm −2 cycling performance 700 hours at 0.5 . Furthermore, Na/SPCE‐9/Na 3 V 2 (PO 4 ) maintains discharge specific capacity 76.8 mAh g −1 10 C shows long‐cycle stability, retaining 86.2 % initial over 5000 cycles an average coulombic efficiency 99.9 %. Our work presents high‐performance intrinsic safety, providing valuable insights future SMBs.

Язык: Английский

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Chlorine-Rich Na6−xPS5−xCl1+x: A Promising Sodium Solid Electrolyte for All-Solid-State Sodium Batteries

Materials, Год журнала: 2024, Номер 17(9), С. 1980 - 1980

Опубликована: Апрель 24, 2024

Developing argyrodite-type, chlorine-rich, sodium-ion, solid-state electrolytes with high conductivity is a long-term challenge that crucial for the advancement of all-solid-state batteries (ASSBs). In this study, argyrodite-type Na6−xPS5−xCl1+x solid solutions were successfully developed solution formation range 0 ≤ x 0.5. Na5.5PS4.5Cl1.5 (x = 0.5), displaying highest ionic 1.2 × 10−3 S/cm at 25 °C, which more than hundred times higher Na6PS5Cl. Cyclic voltammetry and electrochemical impedance spectroscopy results demonstrated rich chlorine significantly enhanced stability, in addition to causing reduction activation energy. The composite also showed characteristics pure conductor without electronic conductivity. Finally, viability as sodium electrolyte was checked lab-scale ASSB, showing stable battery performance. This study not only demonstrates new composites sodium-ionic, relatively but provides an anion-modulation strategy enhance conductors.

Язык: Английский

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