Batteries & Supercaps,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 17, 2024
Abstract
The
rise
of
electronic
societies
is
driving
a
surge
in
the
demand
for
energy
storage
solutions,
particularly
realm
renewable
technologies
like
batteries,
which
rely
heavily
on
efficient
electrode
materials
and
separators.
As
an
answer
to
this
necessity,
Covalent
Organic
Frameworks
(COFs)
are
emerging
highly
intriguing
class
materials,
garnering
increased
attention
recent
years
their
extensive
properties
possible
applications.
This
review
addresses
remarkable
versatility
boundless
potential
COFs
scientific
fields,
mainly
focusing
multivalent
metal
ion
batteries
(MMIBs),
include
AIB
(Aluminium‐ion
batteries),
MIB
(Magnesium‐ion
battery),
CIB
(Calcium‐ion
ZIB
(Zinc‐ion
as
both
separators
across
spectrum
battery
technology.
Inclusive
approaches,
merits,
reaction
mechanisms,
offers
summary
concerning
batteries.
By
providing
rigorous
analysis
COF
attributes,
electrochemical
behaviour,
methodologies,
our
explanation
contributes
deeper
understanding
advancing
Electroreduction
of
CO2
(ECR)
to
CO
or
syngas
is
an
effective
approach
alleviating
greenhouse
gas
emissions.
Herein,
nickel
nanoparticles
coated
with
halogen/nitrogen
codoped
carbon
were
prepared
(X-Ni/NC-a).
Cl-Ni/NC-a
can
obtain
three
important
compositions
(CO:H2)
under
different
voltages,
such
as
0.97,
0.51,
and
0.32,
which
are
the
ratios
for
hydroformylation,
methanol,
ethanol
synthesis,
respectively.
For
Br-Ni/NC-a,
Faraday
efficiency
(FEco)
exceed
96%,
a
partial
current
density
(jco)
48
mA
cm-2.
Additionally,
Br-Ni/NC-a
used
in
Zn-CO2
battery
(ZCB);
power
reach
2.6
mW
cm-2,
charge-discharge
stability
110
h.
DFT
calculations
revealed
that
strong
interaction
between
regulates
electronic
structure
catalyst,
affecting
adsorption/desorption
intermediates.
This
study
provides
feasible
scheme
halogen
doping
modulate
selectivity
ECR
potential
application
catalysts
ZCB.
Batteries & Supercaps,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 17, 2024
Abstract
The
rise
of
electronic
societies
is
driving
a
surge
in
the
demand
for
energy
storage
solutions,
particularly
realm
renewable
technologies
like
batteries,
which
rely
heavily
on
efficient
electrode
materials
and
separators.
As
an
answer
to
this
necessity,
Covalent
Organic
Frameworks
(COFs)
are
emerging
highly
intriguing
class
materials,
garnering
increased
attention
recent
years
their
extensive
properties
possible
applications.
This
review
addresses
remarkable
versatility
boundless
potential
COFs
scientific
fields,
mainly
focusing
multivalent
metal
ion
batteries
(MMIBs),
include
AIB
(Aluminium‐ion
batteries),
MIB
(Magnesium‐ion
battery),
CIB
(Calcium‐ion
ZIB
(Zinc‐ion
as
both
separators
across
spectrum
battery
technology.
Inclusive
approaches,
merits,
reaction
mechanisms,
offers
summary
concerning
batteries.
By
providing
rigorous
analysis
COF
attributes,
electrochemical
behaviour,
methodologies,
our
explanation
contributes
deeper
understanding
advancing
