Synergistic Effect Enables Aqueous Zinc‐Ion Batteries to Operate at High Temperatures DOI Open Access

Changlei Zhuang,

Siwen Zhang, Zhi Gen Yu

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 26, 2024

Abstract The performance of aqueous zinc‐ion batteries (AZIBs) at high temperatures (HT) is severely compromised by active water corrosion, parasitic reactions, and dendrite growth. Herein, zinc trifluoroacetate introduced a low concentration (0.2 m ), dissolved in triethyl phosphate (TEP)and H 2 O. suppressed due to the reconstructed original hydrogen bond network, which helps inhibit reactions severe corrosion. Meanwhile, solid electrolyte interphase (SEI) formed on anode decomposition salt. high‐tolerance SEI physically separates anode, reducing corrosion caused water. Moreover, TEP, as prevalent fire‐retardant cosolvent, can preferentially anchor sheet, serving shielding buffer layer. TEP not only reconstructing structure electric double layer (EDL), decreasing content water, but also accelerating prompt formation further. As proof this synergistic effect, assembled symmetric Zn.

Язык: Английский

From Fundamentals to Practice: Electrolyte Strategies for Zinc‐Ion Batteries in Extreme Temperature DOI Creative Commons
Tao Xue, Yongbiao Mu, Xian Yong Wei

и другие.

Carbon Neutralization, Год журнала: 2024, Номер 4(1)

Опубликована: Ноя. 24, 2024

ABSTRACT In the pursuit of advanced energy storage technologies that promote sustainable solutions, zinc‐ion batteries (ZIBs) have emerged as a promising alternative to lithium‐ion due their abundance, safety, and environmental advantages. However, failure mechanisms ZIBs under extreme temperatures are still not fully understood, presenting significant challenges development commercialization. Therefore, innovative strategies essential enhance adaptability temperature extremes. this review, we first explore thermodynamic kinetic aspects performance degradation temperatures, focusing on key factors such ion diffusion redox processes at electrode interfaces. We then comprehensively summarize discuss existing approaches for various electrolyte types, including aqueous, nonaqueous, solid state. Finally, highlight future prospects operating conditions. The insights presented in review expected accelerate advancement facilitate practical implementation large‐scale systems.

Язык: Английский

Процитировано

14

Conductive Hydrogels: Bioelectronics and Environmental Applications DOI

Seyedeh‐Arefeh Safavi‐Mirmahalleh,

Mohsen Khodadadi Yazdi, Mohammad Reza Saeb

и другие.

Current Opinion in Solid State and Materials Science, Год журнала: 2025, Номер 34, С. 101213 - 101213

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1

Toward Green and Sustainable Zinc‐Ion Batteries: The Potential of Natural Solvent‐Based Electrolytes DOI Creative Commons
G. Yaman, Recep Yüksel

Small, Год журнала: 2025, Номер unknown

Опубликована: Янв. 21, 2025

Abstract Zinc‐ion batteries (ZIBs) are emerged as a promising alternative for sustainable energy storage, offering advantages such safety, low cost, and environmental friendliness. However, conventional aqueous electrolytes in ZIBs face significant challenges, including hydrogen evolution reaction (HER) zinc dendrite formation, compromising their cycling stability safety. These limitations necessitate innovative electrolyte solutions to enhance ZIB performance while maintaining sustainability. This review explores the potential of natural solvent‐based derived from renewable biodegradable resources. Natural deep eutectic solvents (DES), bio‐ionic liquids, biomass‐derived organic compounds present unique advantages, wider electrochemical window, reduced HER activity, controlled deposition. Examples include DESs based on choline chloride (ChCl), glycerol‐based systems, γ‐valerolactone (GVL) aloe vera, demonstrating improved suppression. Despite promise, challenges high viscosity, scalability remain critical barriers commercialization. underscores need further research optimize solvent formulations, Zn anode compatibility, integrate these systems into practical applications. By addressing can pave way safer, high‐performance, environmentally ZIBs, particularly large‐scale storage systems.

Язык: Английский

Процитировано

1

Zinc-ion batteries at elevated temperatures: linking material design to wearable/biocompatible applications DOI Creative Commons
Yutong Wu,

Qiong He,

Yunlei Zhou

и другие.

Advanced Composites and Hybrid Materials, Год журнала: 2025, Номер 8(1)

Опубликована: Янв. 17, 2025

Язык: Английский

Процитировано

1

Artificial aluminum-doped SiO2 aerogel coating layer regulating zinc ions flow for highly reversible dendrite-free zinc anodes DOI

Xiangsi Wu,

Fang Chai, Juan Yang

и другие.

Electrochimica Acta, Год журнала: 2024, Номер 501, С. 144799 - 144799

Опубликована: Июль 31, 2024

Язык: Английский

Процитировано

4

Molecular Crowding Agent Modified Polyanionic Gel Electrolyte for Zinc Ion Batteries Operating at 100 °C DOI

Shimin Huang,

Shenggong He,

Shilin Huang

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 27, 2024

Abstract Aqueous zinc‐ion batteries (AZIBs) attract attention due to their safety and high specific capacity. However, practical applications are constrained by Zn anode corrosion, dendritic growth, poor high‐temperature adaptability induced a strong hydrogen‐bond network in aqueous electrolytes. In this work, dual polyanionic gel electrolyte (denoted as PAM‐PAMPS‐10PD) is developed capable of withstanding temperatures (100 °C) situ polymerization. The abundant anionic groups the greatly improve 2+ transport inducing uniform deposition . Then addition high‐boiling molecular crowding agent 1,5‐pentanediol (PD) can inhibit water activity enhancing hydrogen bonding with H 2 O changing solvation structure corrosion. As result, symmetric battery using PAM‐PAMPS‐10PD be stably cycled for at least 500 h 100 °C 0.5 mA cm −2 /0.5 mAh , realizing dendrite‐free zinc anodes temperatures. Moreover, Zn–AC full has capacity retention 47.8% after 3000 cycles 4 This study provides beneficial reference design high‐performance electrolytes establishes solid foundation application AZIBs.

Язык: Английский

Процитировано

4

Partially crystalline Co3(HITP)2 modified Si anode endowing Si-air batteries with long discharge duration at high temperatures DOI

Fengjun Deng,

Ze Liu, Yuhang Zhang

и другие.

Composites Part B Engineering, Год журнала: 2025, Номер unknown, С. 112270 - 112270

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

Anchoring polyiodide with flexible interlayer for high-performance aqueous zinc-iodine batteries DOI
Yu Zhang, Usman Ali,

Yuehan Hao

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 688, С. 132 - 139

Опубликована: Фев. 20, 2025

Язык: Английский

Процитировано

0

Gel Electrolyte Interdigitation Enables Stable High Areal Capacity Cycling of the 3D Zn Electrode DOI Creative Commons
Yuan Shang,

Ravindra Kokate,

Patrick Kin Man Tung

и другие.

Journal of Materials Chemistry A, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Hydrogel electrolyte interdigitation is introduced as an effective strategy for stable 3D zinc metal anode design, allowing fast mass transport into the tortuous framework and uniform deposition/dissolution across entire structure.

Язык: Английский

Процитировано

0

An anti-freezing flexible polymer electrolyte for high-performance zinc-ion batteries DOI

Hyocheol Lee,

P. Rangaswamy, Anh Le Mong

и другие.

Journal of Materials Chemistry A, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

An optimized 1.0 M Zn–eutectic SPE offers high ionic conductivity, mechanical strength, and stability. The Zn|SPE|V 10 O 24 · n H 2 O@rGO cell delivers excellent performance durability, ensuring stable operation over a wide temperature range.

Язык: Английский

Процитировано

0