Research Trends and Future Perspectives on Zn-Ion Batteries Using Ga-Based Liquid Metal Coatings on Zn Anodes

ACS Energy Letters, Год журнала: 2024, Номер 9(11), С. 5421 - 5433

Опубликована: Окт. 16, 2024

Zn-ion batteries (ZIBs) are considered promising alternatives to conventional Li-ion secondary due their high safety, environmental friendliness, and cost-effectiveness. Despite these advantages, uneven metal plating stripping, dendrite formation, passivation corrosion owing the hydrogen evolution reaction (HER) have hindered practical implementation of ZIBs. A route for overcoming problems involves coating Zn anode with eutectic gallium indium (EGaIn)-based liquid (LM) a strong affinity growth direction tenability. considerable research on EGaIn-coated anodes ZIBs, this topic has not been comprehensively reviewed. Hence, Review introduces application LMs ZIBs particularly discusses mitigation stability issues using LM fundamental processes related anodes. We summarize progress in field suggest future directions advance

Язык: Английский

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Mixed-dimensional van der Waals heterostructure of Bi2S3 nanorods and SnS2 nanosheets bridged with N-doped carbon interlayer for enhanced sodium-ion batteries

Energy storage materials, Год журнала: 2024, Номер 73, С. 103880 - 103880

Опубликована: Ноя. 1, 2024

Язык: Английский

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Spatial and anchoring effects of zirconia-doped 3D scaffolds for stable zinc anodes

Chemical Engineering Journal, Год журнала: 2025, Номер 505, С. 159397 - 159397

Опубликована: Янв. 10, 2025

Язык: Английский

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A layered basic zinc acetate coating for dendrite-free Zn anodes by interface environment regulation in aqueous zinc-ion batteries

Inorganic Chemistry Frontiers, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

The artificially constructed porous layered basic zinc acetate nanosheets can effectively reduce the electric field's tip effect and hydrogen evolution reaction, leading to uniform Zn nucleation deposition.

Язык: Английский

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Maximizing Functional Diversity of Electrolyte Additives through Modular Molecular Engineering to Stabilize Zinc Metal Anodes

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 25, 2025

Abstract Molecule design is significant for achieving the functional diversity of electrolyte additives in aqueous zinc‐ion batteries, yet strategy underutilized. Here modular molecular engineering proposed to segregate and recombine hydrophilic (hydrophobic) zincophobic (zincophilic) modules within maximize efficacy electrolytes promoting Zn stability reversibility. By using an with a polyoxometalate (POM) additive, (NH 4 ) 3 [PMo 12 O 40 ], which contains zincophilic‐hydrophobic polyoxoanion ] 3− zincophobic‐hydrophilic cation NH + , promising system developed. Experimental theoretical analyses unravel that consisting weak [Mo 36 shell encapsulating zincophilic intensifier PO core, can alter 2+ ‐solvation sheath Zn‐electrolyte interface. Meanwhile, disrupts hydrogen bond networks water, synergistically realizing high electrochemical anode at both room low temperatures. As result, Zn//NaV 8 ∙1.5H 2 batteries additive exhibit outstanding cycling stability, over 10 000 cycles 5 A g −1 25 °C 800 0.2 −30 °C. This work highlights significance molecule expands research scope POM chemistry.

Язык: Английский

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Research Progress on the Mechanisms of MOF/COF and Their Derivatives in Zinc−Ion Batteries

Energy storage materials, Год журнала: 2025, Номер unknown, С. 104220 - 104220

Опубликована: Март 1, 2025

Язык: Английский

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Design of Porous Organic Polymer ASEIs for Zn Anode Protection and Ion Migration Regulation

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 10, 2024

Abstract Rechargeable aqueous Zn metal batteries (RAZMBs) are considered as a competitive alternative to the next generation of energy storage system. However, stripping/plating reversibility is greatly limited by dendrite growth and side reactions on anode. In virtue excellent protection ion migration regulation effects, porous organic polymer artificial solid electrolyte interphases (POPASEIs) have attracted widespread attention in stabilizing This article summarizes progress anode POPASEIs recent years, divided into two categories according matrix: polymer‐based nonporous POPASEIs. The can be coordination (PCOOP)‐based covalent polymers (PCVOP)‐based ASEIs chemical structure, while four types pore‐forming strategies, including phase separation‐induced POPASEIs, template‐assisted fiber‐formed filler‐modified addition, structural advantages, challenges, perspectives for also discussed provide guidance further research development ASEIs.

Язык: Английский

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Navigating highly reversible Zn metal anodes via a multifunctional corrosion inhibitor-inspired electrolyte additive

Chemical Engineering Journal, Год журнала: 2024, Номер 500, С. 157307 - 157307

Опубликована: Ноя. 1, 2024

Язык: Английский

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Cathode-less zinc-manganese fiber batteries with reinforced-concrete structured composite hydrogel electrolytes

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 158509 - 158509

Опубликована: Дек. 1, 2024

Язык: Английский

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Nanosheet-like arrays with more Moδ+ on nickel foams as self-supporting electrodes for hydrogen evolution reactions

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 113974 - 113974

Опубликована: Янв. 1, 2025

Язык: Английский

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